| Issue |
A&A
Volume 710, June 2026
|
|
|---|---|---|
| Article Number | A23 | |
| Number of page(s) | 14 | |
| Section | Planets, planetary systems, and small bodies | |
| DOI | https://doi.org/10.1051/0004-6361/202452666 | |
| Published online | 28 May 2026 | |
The effect of atmospheric chemistry on the optical geometric albedos of hot Jupiters
1
Center for Space and Habitability, University of Bern,
Gesellschaftsstrasse 6,
3012
Bern,
Switzerland
2
Space Telescope Science Institute,
3700 San Martin Dr,
Baltimore,
MD
21218,
USA
3
Ludwig Maximilian University, University Observatory Munich,
Scheinerstrasse 1,
Munich
81679,
Germany
4
University of Warwick, Department of Physics, Astronomy & Astrophysics Group,
Coventry
CV4 7AL,
UK
5
University of Bern, ARTORG Center for Biomedical Engineering Research,
Murtenstrasse 50,
3008
Bern,
Switzerland
★ Corresponding author: This email address is being protected from spambots. You need JavaScript enabled to view it.
Received:
18
October
2025
Accepted:
12
February
2026
Abstract
We investigate the geometric albedos of hot Jupiters by comparing observational data from space telescopes TESS, Kepler, CoRoT, and CHEOPS against theoretical models. The study aims to understand the distribution of observed geometric albedos across different bandpasses and how these observations align with or deviate from model predictions. We curated a comprehensive sample of observed geometric albedos, using either existing Spitzer secondary eclipse measurements or a scaling law between the equilibrium and dayside temperature to remove any contaminating thermal planetary emission. We then utilised hierarchical Bayesian modelling to identify trends with planetary properties such as equilibrium temperature, gravity, and stellar metallicity. On a population level, we found no statistical difference in the distributions of geometric albedos measured by TESS compared to those measured by Kepler, CoRoT, and CHEOPS. We confront the geometric albedo sample with a simple but first-principles model that includes Rayleigh scattering by molecular hydrogen and absorption by sodium, water, titanium oxide, and vanadium oxide. We find that the abundance of sodium and water are the key absorbers that influence the geometric albedos of hot Jupiters, whilst the addition of titanium oxide and vanadium oxide (in the absence of condensation) results in vanishing geometric albedos that are inconsistent with the observed distributions.
Key words: methods: statistical / planets and satellites: atmospheres / planets and satellites: composition / planets and satellites: gaseous planets
© The Authors 2026
Open Access article, published by EDP Sciences, under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/4.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
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1 Introduction
The geometric albedo of a planet, moon, or exoplanet is the fraction of light reflected at full illumination with respect to the observer (at superior conjunction). Geometric albedo is a wavelength-dependent quantity and may be larger than unity if the incoming light is preferentially reflected back in the direction of the observer. In the Solar System, there is a long and rich history of measuring the geometric albedos of moons and planets using data measured from Voyager (see, e.g. Hanel et al. 1981) and Cassini (see, e.g. Pitman et al. 2010; Buratti et al. 2022). For Jupiter, geometric albedo spectra have been measured (e.g. Li et al. 2018).
For exoplanets, the geometric albedo may be inferred from measurements of the eclipse depth (D), planetary radius (Rp), and semi-major axis (a) (Seager 2010),
(1)
where it is assumed that the light is being measured at a wavelength at which thermal emission from the exoplanet is negligible and only reflected starlight is present (Heng & Demory 2013).
In practice, the geometric albedos of exoplanets are measured over broad photometric bandpasses, rather than at specific wavelengths, by the CoRoT (e.g. Auvergne et al. 2009; Dang et al. 2018), Kepler (e.g. Borucki et al. 2010; Morris et al. 2024; Heng & Demory 2013; Heng et al. 2021), CHEOPS (e.g. Benz et al. 2021; Brandeker et al. 2022; Krenn et al. 2023), and TESS (e.g. Ricker et al. 2015; Wong et al. 2021) space telescopes. Almost all of these measurements are of hot Jupiters, due to their large eclipse depths and short periods leading to more significant eclipse depth measurements. Many hot Jupiters have been found to have low albedos, such as HD 189733b (0.076 ± 0.016, Krenn et al. 2023) and HD 209458b (0.096 ± 0.016, Brandeker et al. 2022), while some show higher albedos, most likely due to reflective clouds, such as Kepler-7 b (
, Demory et al. 2011; Heng et al. 2021; Morris et al. 2024).
Atmospheric processes affect the reflectivity of exoplanet atmospheres. Sudarsky et al. (2000) predicted that hot Jupiters would have small geometric albedos because their high atmospheric temperatures may activate strong absorption of visible light by lines of sodium and potassium. Burrows et al. (2008) calculated albedo models for HD 209458b and HD 189733b and found a model without scattering clouds was able to reproduce the MOST observations (Rowe et al. 2008). Cahoy et al. (2010) modelled the albedos of Jupiter and Neptune analogues and found that clouds influenced the albedo spectra and temperature drove the effects of clouds more than metallicity. Madhusudhan et al. (2012) developed an analytic geometric albedo model framework including three different types of scattering phase functions to investigate the dependence of polarisation of Rayleigh scattering in the atmosphere on the planetary orbital inclination. In Mallonn et al. (2019), they obtained geometric albedo limits for a number of ultra-hot Jupiters and found values consistent with low reflectivity in the optical to nearinfrared. Heng et al. (2021) derived a general analytic formula for the geometric albedo, which Brandeker et al. (2022) used to demonstrate that the ∼10% geometric albedo of HD 209458b may be explained by scattering from molecular hydrogen and absorption from water and sodium.
The trends between different hot Jupiter properties and their geometric albedos have been a topic of study since the first occultation measurement of TrES-1b in 2005 (Charbonneau et al. 2005). Previous studies have included the set of hot Jupiters observed with Kepler (see, e.g. Heng & Demory 2013; Angerhausen et al. 2015; Esteves et al. 2015), and with TESS (Wong et al. 2021). They found a tentative positive correlation between dayside temperature and geometric albedo for the planets with 1500 < Tday < 3000 K.
The growing but heterogeneous body of albedo measurements constrains the atmospheric physics of these planets. In this work, we investigate the distribution of observed geometric albedos from the TESS, CHEOPS, Kepler, and CoRoT missions. We divide the four missions into two groups, since CHEOPS, Kepler, and CoRoT (hereafter, CKC) have bandpasses with similar transmittance-weighted mean wavelengths (λ̄ = 674,664,695 nm, respectively), and the TESS bandpass has more transmittance in the red (Â = 797 nm). The full transmission functions for the instruments can be seen in Figure 1. We compare the observed albedos with the results from a simplified geometric albedo model (derived from Heng et al. 2021) to answer the following questions:
Whether we should expect geometric albedo measurements in different filter bandpasses to have the same underlying distribution;
Whether geometric albedos correlate with equilibrium temperature, planetary surface gravity, stellar metallicity, or effective stellar temperature;
Whether correlations between albedo and planet properties are dependent on the photometric bandpass of the measurements (e.g. Kepler, TESS);
Whether the scatter in albedo observations sets constraints on the atmospheric properties of hot Jupiters.
In Section 2.1 we describe our data curation methods and the procedure we followed to thermally decontaminate the albedos of targets where that had not been done previously. The curated albedo measurements are shown in Table A.1. Section 2.2 details our theoretical geometric albedo model and the prior assumptions used to produce the albedo distributions we investigate in Section 4. In Section 3 we investigate whether the observational data is correlated with other system or atmospheric parameters, and to what significance. We also look at the variations between the TESS and CKC datasets. In Section 5.2, we synthesise our findings from both the observations and the modelling and present a flowchart to show what information can be determined from measuring the geometric albedo of a planet.
![]() |
Fig. 1 Transmission functions for CHEOPS, Kepler, CoRoT, and TESS instruments as a function of wavelength. In this study we group CHEOPS, Kepler, and CoRoT together due to their similarity in transmission functions. TESS is kept separate as it transmits more into the red. |
2 Methods
2.1 Data curation and thermal decontamination
To determine if the measured geometric albedos displayed any trends with the stellar or exoplanetary properties, we first needed to curate and collect them. We divided geometric albedo measurements into two categories: those from the CoRoT, Kepler, or CHEOPS missions, which have similar optical filters; and those from the TESS mission, with measurements at slightly longer optical wavelengths.
The observed flux coming from the planet can be a combination of reflected starlight and thermal emission from the planet itself. The process of removing thermal emission to compute the albedo is called thermal decontamination (see, e.g. Heng & Demory 2013). Thermal decontamination was already performed by Wong et al. (2021) for the TESS observations. There were a few objects for which only an upper limit was reported. For these planets, we reapplied the thermal decontamination (with the same method as in Wong et al. 2021), given the eclipse depth and dayside temperature, and kept the full error bars, even if they went below zero, to reduce the statistical bias towards Ag > 0. We excluded KELT-1b from consideration, as it is a brown dwarf. We also excluded Kepler-13Ab, as Wong et al. (2021) have shown that the inferred TESS geometric albedo depends heavily on the assumed infrared absorbers.
Many of the CoRoT and Kepler albedos in the literature have not been thermally decontaminated. For these albedos, we decontaminated with
(2)
where Fλ is the planetary thermal dayside flux as a function of wavelength, F*,λ is the stellar flux as a function of wavelength, and T is the telescope transmission function. Since these albedos are measured in wide bandpasses, we assumed a blackbody for the thermal emission of the planet (Fλ = πBλ(Tday)), with an integrated dayside hemisphere temperature. Where available, we used dayside temperatures derived from previous Spitzer observations. Many of the CoRoT and Kepler objects have no Spitzer measurements, so we estimated the dayside temperatures with the scaling relationship between Tday and the equilibrium temperature (Teq) calibrated by Beatty et al. (2019). We accounted only for uncertainties on the measured eclipse depths and ignored the uncertainties on T*, a/R*, and Tday, because the joint posterior distributions of these quantities are generally unavailable in the literature. The list of decontaminated geometric albedo values is reported in Table A.1.
2.2 Modelling the bandpass-integrated geometric albedo
The geometric albedo may be calculated from first principles, if the single-scattering albedo (ω) is known, using the analytical formula derived by Heng et al. (2021),
(3)
where ε = (1 – γ)/(1 + γ) and γ =
. P0 is a constant that describes the amount of single-scattering. This formula was derived for a semi-infinite atmosphere (Chandrasekhar 1960), where the optical depth (but not the spatial distance) transitions from zero to infinity. We constructed the single-scattering albedo, ω, with
(4)
where XM is the volume mixing ratio (relative abundance by number) of a chemical species, M (e.g. water, sodium), and σM is the opacity of M. We assumed a hydrogen-dominated atmosphere consistent with the cosmic abundance of hydrogen and helium, but ignored the scattering and absorption by helium. We assumed that the other species have a total mixing ratio well below 1%. We computed mixing ratios, XM, with FastChem (Stock et al. 2018, 2022; Kitzmann et al. 2024) for several hundred species in chemical equilibrium given the temperature, pressure, and metallicity. We retrieved atomic and molecular opacities, σM, from DACE1, which were computed with HELIOS-K (Grimm & Heng 2015; Grimm et al. 2021). We accessed opacities and mixing ratios from DACE and FastChem using the radiative transfer package shone (Morris et al., in prep.)2.
To compute the bandpass-integrated geometric albedo, one needs to integrate the geometric albedo over the bandpass filter, weighted by the stellar spectral flux,
(5)
We note here that this equation is correct using the TESS transmission filter due to it being an energy counter; however, for CoRoT, Kepler and CHEOPS, an additional factor of λ must be applied to both the numerator and denominator as they are photon counters (Rodrigo & Solano 2020). In our model, for a given stellar effective temperature, we used a PHOENIX spectrum to model the stellar spectral flux, F*,λ (Husser et al. 2013).
We began with a range of metallicities, temperatures, and pressures given the measured properties of the planets in Table A.1, and assumed chemical equilibrium to calculate the volume mixing ratios of each species. Planets at high temperatures are more likely to be near chemical equilibrium, but the threshold effective temperature at which this approximation breaks down is not easily specified. We parameterised the gasphase chemistry by a metallicity, which assumes that the ratios of elemental abundances are locked to their solar values. In practice, chemical equilibrium results ratios of water to sodium that depend only on the assumed temperature and pressure. We also ran a second model with water and sodium abundances that are allowed to deviate from chemical equilibrium.
In this investigation, we included species that are: (a) expected to be present in hot Jupiters within the range of equilibrium temperatures in Table A.1; and (b) have significant absorption bands in the optical. We included H2O and Na, along with Rayleigh scattering from H2, and tested the effects of TiO and VO.
The range of stellar effective temperatures, T*, was guided by the minimum and maximum values corresponding to the objects of our sample: 4550-8000 K. We needed both the stellar temperature, and also the temperature of the planet at optical depth τ ~ 1 in the atmosphere. The relationship between these temperatures is complex and not known in general, so we sampled these two temperatures independently. We used a range of values of the temperatures equal to the range of equilibrium temperatures in our sample (between 1300 and 2700 K), where equilibrium temperature is defined as
(6)
where R* is the stellar radius and a is the semi-major axis. Equilibrium temperature is not the same as the dayside temperature of the planet; however, in our simple model, it is enough to guide our chosen temperature range.
We set a prior on metallicity log U(−1,1) based on an empirical scaling relation between metallicity and planetary mass (Swain et al. 2024; Wakeford et al. 2017). The range of pressures used follows the estimated photospheric pressures of hot Jupiters.
![]() |
Fig. 2 Distribution of observed geometric albedos for both bandpasses (CoRoT-Kepler-CHEOPS (CKC) in blue and TESS in orange), where each observation (from Table A.1) is treated as a Gaussian distribution with a width given by the 1-sigma uncertainty reported. This histogram plot is made from 10000 samples of each observation and then normalised. The CKC sample peaks around Ag = 0.1, whereas the TESS sample has a wider peak and has a maximum at Ag = 0. However, this could be a result of the much wider error bars in the TESS data, smoothing out any peaks. |
3 Geometric albedo observations
3.1 Observed geometric albedo trends
The set of observed geometric albedos is reported in Table A.1. In total there are 17 targets in the CKC band and 19 in the TESS band. We divided the objects into two sections: those in the top section have their albedos taken directly from previous analyses (in which thermal decontamination has been carried out); and in the bottom half, we used eclipse depths and dayside temperatures from the enumerated references to decontaminate the geometric albedos (see method in Section 2.1). All of the targets are within the hot to ultra-hot Jupiter regime, with equilibrium temperatures ranging from 1179 ± 11 K to 2764 ± 37 K.
The set of geometric albedos in each bandpass group is shown in Figure 2. We drew 10 000 samples from the geometric albedo posterior distribution, assuming a Gaussian distribution with means and standard deviations defined by the observations and their uncertainty. Since the observations have large uncertainties that may extend to negative albedos, we took the absolute value before comparing to the model posteriors. The TESS albedo posterior samples peak at zero and the CKC samples peak around Ag = 0.1. The CKC samples also have a narrower peak than the TESS samples; however, this width will be very dependent on the uncertainties of the observations. This more positive peak of the bluer bandpasses is, however, in line with expectations, because scattering affects the blue end of the spectrum.
Following a similar approach as Sagear & Ballard (2023), we compared these observed albedo distributions with three empirical albedo distribution models within a hierarchical Bayesian framework. The hypothetical, empirical albedo distributions are Rayleigh, half-Gaussian, and Beta distributions, chosen for their simplicity, and to test whether the albedo distributions go to zero counts at zero albedo or not. The Rayleigh and half-Gaussian functions have only one free parameter, σ, and the Beta function has two parameters, a and b. The likelihood functions for each distribution can be found in Appendix B. The best-fit models are shown in Figure 3 and Table 1 details the best-fit parameter values for the CKC and TESS dataset.
We compared the Bayesian information criterion (BIC) of each albedo distribution model and found that no model is strongly preferred. The Rayleigh function has the smallest BIC, for both CKC and TESS data, and the Beta function has the highest. Looking at the difference between the CKC and TESS distributions, we see that the best-fit parameters are consistent with each other. Again following Sagear & Ballard (2023), we used the probability ratio
(7)
to evaluate whether a joint fit to the CKC and TESS datasets is preferred over individual fits. Here D1 and D2 represent the CKC and TESS geometric albedos and hypothesis H1 states that a joint fit is best to fit these datasets, whilst H0 states that individual fits to the datasets is best. P(D1|H0) and P(D2|H0) are the likelihoods of the best-fit models to the individual datasets and P(D1D2|H1) is the likelihood of the best-fit joint model. If a joint fit is preferred, this gives us evidence that the samples are from the same underlying distribution. For the Rayleigh model, we obtain ln(R) = 9.27, for the half-Gaussian one ln(R) = 9.41, and for Beta ln(R) = –19.1. The two best-fitting models have positive values for ln(R), which implies that the joint fit likelihood is higher than the combined individual fits. We conclude there is no evidence of a difference in the underlying distributions of the TESS versus CKC-measured geometric albedos.
Next, we took the set of thermally decontaminated albedos and investigated whether they show any correlation with other system parameters. We show the albedos plotted against these parameters in Figure 4. We fitted both a constant and a linear model to the geometric albedos as a function of a range of parameters, taking into account the uncertainties in both the system parameters and the albedos, with emcee (Hogg et al. 2010; Foreman-Mackey et al. 2013). The albedo uncertainties are likely underestimated in this decontamination process, so we include an error bar scaling factor as a free parameter. These fits are intended for finding first-order trends - we note that the linear fits allow non-physical, negative albedos. We show the BIC results of these model comparisons in Table 2.
The uncertainties of the geometric albedos are large compared to the range of possible values (between 0 and 1). In general, the uncertainties for the TESS measurements have larger error bars than the CKC measurements. This is partially due to the error on the reported eclipse depth. Most of the Kepler objects have very tight constraints on their eclipse depths, due to the high number of eclipses per object. The slopes of these linear fits are sensitive to the measurements at the extremes. Typically ΔBIC<10 between constant and linear models, suggesting no preference for correlations. There is a weak preference for the linear model with log(g) and [Fe/H] in the CKC band.
Whilst the albedo measurements show little or no correlations with system parameters, the geometric albedo measurements are very uncertain. Another reason for this uncertainty comes from the thermal decontamination procedure, which often involves multiple assumptions (e.g. blackbody planets) and very uncertain dayside temperature measurements due to limited infrared observations. Emitted flux scales with T4 (within a specific bandpass this relation is not as straightforward), so these uncertainties propagate through to the geometric albedo. A more correct thermal decontamination approach would use the full planetary emission spectrum, but almost none of these planets, to date, have full SED measurements from, for example, JWST.
![]() |
Fig. 3 Three panels show the best-fit models (Rayleigh, half-Gaussian, and Beta distributions) plotted over the observed geometric albedos, with the shading showing the 1σ uncertainties in the fits. In orange is the TESS band and in the blue the CKC band. We find that the best-fit models from the two bandpasses are consistent. We also find that, by calculating the BIC of each fit, the Rayleigh distribution is the best-fitting model for this data (although not very significantly) and the Beta distribution the worst. |
![]() |
Fig. 4 Geometric albedos and physical parameters for targets observed with CoRoT-Kepler-CHEOPS (blue points) and TESS (orange points). The trend results can be found in Table 2. We have restricted the y axis to physical values of the geometric albedo; however, it should be noted that some targets (WASP-18b and WASP-33b) have median posterior values below 0. |
Result of the trend analysis of the observed geometric albedos versus various stellar and planetary parameters (‘Independent Variable’ in this table).
Priors distributions for the input to our geometric albedo model assuming chemical equilibrium.
4 Theoretical model results
4.1 Geometric albedos in chemical equilibrium
We began our modelling efforts by assuming chemical equilibrium in the planet’s atmosphere (see Section 2.2 for model details). Table 3 details the priors used for the sampling distributions. We sampled over T*, Tplanet, pressure, and metallicity (i.e. the observed atmospheric metallicity).
Figure 5 shows the results in the CHEOPS and TESS bandpass. Abundances of the species are not free parameters themselves, but are calculated from the M/H ratio, pressure, and temperature. As we have already mentioned, the use of a single number (the metallicity) to describe the gas-phase chemical abundances is a simple assumption. The metallicity is correlated with the geometric albedo due to larger abundances of absorbing molecules increasing the opacity in the atmosphere. From our results it is clear that water and sodium have strong and similar effects on suppressing the albedo. For the same chemical abundances, we generally measure a lower Ag in the TESS bandpass than the CHEOPS bandpass. Interestingly, the albedo distributions from the different bandpasses have little overlap. The most reflective planet in the TESS bandpass almost always has a lower albedo than the least reflective planet in CHEOPS bandpass. This is not borne out by the observations. We do not show the albedos as a function of T*, Tplanet and pressure, as these show no discernible correlation.
4.2 Geometric albedos out of equilibrium
Next, we relaxed the assumption that the planet’s atmosphere is in chemical equilibrium, using the priors in Table 4. To parameterise the disequilibrium, we used a scaling factor to perturb the mixing ratios of each species relative to the equilibrium value. We independently sampled over a distribution of ‘scaling factors’ that has the form of log U[–1,1] in log space for both sodium and water. Our results are shown in Figure 6. We find similar trends as in Section 4.1; however, with a larger scatter of Ag for a fixed chemical abundance.
Due to the increased scatter, the values of Ag in the TESS and CHEOPS bandpass are permitted to overlap. However it is still clear that, on average, the albedos from CHEOPS are higher than from TESS. From the width of the posterior distributions, we observe that water has a stronger influence than sodium in the TESS bandpass and they both have similar-strength correlations in the CHEOPS band.
![]() |
Fig. 5 Geometric albedo model results, produced by sampling over the input parameter prior distributions (see Table 3) and assuming chemical equilibrium. The wavelength-dependent albedos were then bandpass-integrated to produce the expected albedos in the TESS (orange) and CKC (blue) band. Not shown are the albedos as a function of T*, Tplanet and pressure, as these show no discernible correlation. We find that the metallicity (log [M/H]) has the largest impact on the geometric albedo and that, from this, the water abundance produces slightly tighter constraints on Ag than sodium. We also see very distinct differences between the CHEOPS and TESS bandpasses. |
![]() |
Fig. 6 Geometric albedo model results, produced by sampling over the input parameter prior distributions (see Table 4) and using a scaling factor distribution to move the model away from chemical equilibrium. The wavelength-dependent albedos were then bandpass-integrated to produce the expected albedos in the TESS (orange) and CKC (blue) band. We find similar results to the chemical equilibrium model: temperature and pressure had no effect on the geometric albedo (so they are not shown here), and metallicity is the main driver. Due to increased parameter space from the relaxation of the chemical equilibrium constraint, the posteriors of TESS and CKC albedos are now wider and begin to overlap slightly. It is clear that the higher the metallicity, the lower the geometric albedo. |
Prior distributions for the input to our geometric albedo model with chemical abundances scaling factors to shift the model away from chemical equilibrium.
4.3 Theoretical model compared to the observations
We reproduced the range of albedos observed with TESS and CKC using a model with only H2, water, and sodium. In our model simulations, the very low-metallicity planets produce high albedos, in both the CHEOPS and TESS band, because there are too few absorbers to stop the Rayleigh scattering from dominating. This strong correlation between albedo and metallicity is not mirrored in the observations, if we assume that the stellar metallicity is equal or correlated to the planet’s metallicity. However there are huge uncertainties on the stellar metallicity measurements, making it very difficult to detect any trends. From planet formation, stellar metallicity and planetary metallicity share no simple linear relation, especially if there is condensation involved that acts to remove metals from the gas phase. We also find no significant correlation with the stellar temperature, planetary temperature, or pressure. Over the range considered, these parameters only have a very small effect on the cross-section of the chemical species and so it is expected that they should not have a significant influence on Ag.
The comparison between the theoretical and observed distributions is very informative. We find both similarities and differences between the shapes of the distributions; for example, the peak of the modelled CKC results is at a higher albedo than the TESS distribution. Although this matches what we find in the data, we believe the observed sample size is too small to trust this as a result. More observations would be needed to confirm this hypothesis. We also find that, due to the metallicity constraints, the CKC modelled distribution does not reach zero. In Figure 7, we show how the distributions depend on the assumed metallicity prior. The higher the metallicities probed, the greater a pile-up of albedos at zero. In Figure 8, we show how increasing the distance the model can probe away from chemical equilibrium changes the shape of the modelled distributions. This is mostly due to the fact that larger metallicities can be explored with a larger scaling prior.
4.4 Theoretical models with more absorbers
Based on the analogy to brown dwarfs, Fortney et al. (2008) predicted the existence of two classes of hot Jupiters based on the absence or presence of TiO and VO. Since then, there have been a select number of confirmed detections of TiO or VO in hot Jupiters (see, e.g. Nugroho et al. 2017; Chen et al. 2021). It is known that TiO and VO are prominent absorbers in hot atmospheres when observed in emission and are also detectable at high resolution via cross-correlation. Additionally, TiO and VO have been the proposed absorbers responsible for detected thermal inversions (see, e.g. Coulombe et al. 2023; Cont et al. 2021). However, these species have not been detected directly in reflection spectroscopy, which would be the only way to conclusively determine that the albedos are affected directly by TiO and/or VO in an atmosphere. One possible reason is the sequestration of titanium and vanadium into condensates by a ‘cold trap’ on the nightside of hot Jupiters (see, e.g. Parmentier et al. 2013). If they are condensed, then they would not contribute to the stellar absorption and scattering in the atmosphere.
This is to say that even if the initial abundances of TiO and VO are correctly predicted by gas-phase equilibrium chemistry, their final abundances are controlled by atmospheric dynamics and condensation. Therefore, we know that these species could be present, but we do not know exactly where or in what abundance, and consequently how much they contribute to the geometric albedo we observe. This motivated us to test atmospheres with and without these species in this study, using a scaling factor relative to chemical equilibrium. We also tested adding condensation into our model to see what effect this would have. When we used the model without condensation, we did not let the scaling factors of TiO or VO be greater than 1 (or 0 in log-space), to maintain physical conditions. For the other species and parameters, we used similar priors to the other models (see Tables 5 and 6). Our results are shown in Figures 9 and 10. We see that in the absence of a condensation model, including these strong-optical absorbers at even small abundances, drastically reduces the observed geometric albedo. However, when the condensation is switched on, we find higher geometric albedos are again reachable. We find that these distributions are very different from the observed distribution, in both the CHEOPS and TESS bandpass.
![]() |
Fig. 7 The influence of the assumed priors for the underlying abundances of water and sodium on the modelled geometric albedo. In the left panel we show the distributions in the CHEOPS bandpass, and in the right one we show the distributions in the TESS bandpass. We overlay the observed distribution to suggest that perhaps the underlying effective metallicity distribution is within these ranges; however, we are also very aware that the uncertainties of the observations highly influence this shape (due to the low number of observations). |
![]() |
Fig. 8 The influence of the permitted distance from equilibrium of the abundances of water and sodium on the modelled geometric albedo. This is mostly due to the fact that larger metallicities can be explored with a larger scaling prior. In the left panel we show the distributions in the CHEOPS bandpass, and in the right one we show the distributions in the TESS bandpass. Here we keep the metallicity distribution fixed to log U[–1,1]. We overlay the observed distribution. |
Prior distributions for the input to our geometric albedo model with chemical abundance scaling factors to shift the model away from chemical equilibrium.
Prior distributions for the input to our geometric albedo model with condensation enabled and chemical abundance scaling factors to shift the model away from chemical equilibrium.
5 Discussion
5.1 Geometric albedos are primarily determined by the abundance of absorbers
Using our geometric albedo model (Section 2.2), we have shown evidence that the abundances of absorbing chemical species in the atmosphere (or ‘effective’ metallicity) is one of the main drivers for determining the geometric albedo of a planet. We have also seen that when heavier metals such as TiO and VO are present the efficiency of condensation together with the abundances are the main drivers. From Figure 9, we see that when (optical) absorbers are abundant in the atmosphere, the (optical) geometric albedo is low. The exact correlation depends on which absorbers are present and whether the atmosphere is near chemical equilibrium or not.
The other potential correlates that we considered were atmospheric temperature, pressure, and stellar temperature. We found no significant correlation between these parameters and the geometric albedo, within the ranges set by our observations. This is because the opacities of the atmospheric species do not vary significantly within this temperature and pressure range. Temperature has more of an impact on the volume-mixing ratio, but the change is insufficient to affect the bandpass-integrated albedo. One caveat here is that the model does not assume a correlation between stellar temperature and planet temperature, as this is beyond the scope of the model. Another caveat is that our model does not feature clouds, which, if present, may be more dependent on temperature and pressure and therefore influence the geometric albedo more significantly.
![]() |
Fig. 9 Geometric albedo model results without condensation, produced by sampling over the input parameter prior distributions (see Table 5) and using a scaling factor distribution to move the model away from chemical equilibrium. The wavelength-dependent albedos were then bandpass-integrated to produce the expected albedos in the TESS (orange) and CKC (blue) band. We find that the presence of additional optical absorbers forces the albedo to stay near zero, even when the metallicity is low. |
![]() |
Fig. 10 Geometric albedo model results including condensation, produced by sampling over the input parameter prior distributions (see Table 5) and using a scaling factor distribution to move the model away from chemical equilibrium. The wavelength-dependent albedos were then bandpass-integrated to produce the expected albedos in the TESS (orange) and CKC (blue) band. We find that high albedos are reachable with high metallicites, due to condensation removing the effect of metals from the upper atmosphere. |
5.2 What this means for atmospheric characterisation
We have summarised our model results into a simple framework for interpreting albedo measurements in terms of atmospheric properties. In broad terms:
First, measure the optical geometric albedo of the planet.
If the albedo is high (Ag ≳ 0.2), then the planetary atmosphere likely produces significant scattering (to scatter the starlight back into space), or it has few absorbers (allowing Rayleigh scattering to dominate).
If the albedo is low (Ag ≲ 0.05), then this could imply that the atmosphere has little scattering, or that it is abundant in absorbers.
If the albedo is high and the metallicity is high, significant additional scattering in the atmosphere is required to produce the observed albedo. None of our models (with different absorbers or abundance combinations) have been able to produce high geometric albedos when the metallicity is high. Reflective clouds would be an obvious solution to produce the additional scattering required.
High albedos can be produced by planets with low metallicity if they have only only water and sodium present. Adding more absorbers such as TiO and VO causes the albedo to decline rapidly without the addition of clouds. This scenario is sensitive to the absorbers in the atmosphere.
Alternatively, if the albedo is low and the metallicity is high, abundant absorbers must dominate over the Rayleigh scattering in the atmosphere. This scenario may also imply that clouds are not present in this atmosphere, since clouds tend to boost the geometric albedo.
The final combination is a low geometric albedo and low metallicity, which, we have shown in our water and sodium models, is impossible unless the chemistry strays far from equilibrium.
5.3 Parameters that control the spread in Ag
Figure 5 shows that the model albedo distributions with equilibrium chemistry have a higher probability density near Ag = 0 than the CKC observations, which peak at Ag = 0.2. The observed TESS albedos may lack this peak because the albedo uncertainties are much larger.
The model geometric albedo distributions increase towards Ag → 0 mostly due to high metallicities. Perhaps the highest metallicities in this prior are excluded by the observations, and may not occur in nature. Looking at the stellar metallicities associated with the observations, they are all below [Fe/H] ~ 0.4.
At present, devising any further parametrisation to relate stellar metallicity and planet metallicity might be premature.
We note that the spread in geometric albedos is larger with disequilibrium chemistry. In equilibrium, the geometric albedos observed in the two bandpasses do not overlap. This is not something that is seen in the observations.
5.4 Albedo differences between bandpasses
For the model in chemical equilibrium with only water and sodium, we see large discrepancies between the TESS and the CHEOPS bandpass, despite a significant wavelength overlap between the bandpasses. Even with our generous priors allowing mixing ratios to range from 0.1-10 times the equilibrium abundance (and more, see Figure 8), the posteriors are clearly still distinct.
However, we found that observed albedos from TESS and CKC are very similar. In Section 3, we curated geometric albedos in the literature and concluded the CKC and TESS observed albedo datasets come from the same underlying distribution. There are two likely reasons why the observed albedo distributions are mutually consistent, but the model albedo distributions are inconsistent. The first is that the observational uncertainties are too large to identify small differences. The second is that the model is quite simplified. At planetary temperatures near 2000 K, we expect condensation of clouds to play an important role in the observed albedos, which may obscure any differences between the albedo distributions from CKC and TESS.
5.5 Future work
With the help of CHEOPS and Kepler, we have very precise eclipse depth measurements, giving us the total planetary flux in a specific bandpass. The problem is how to decouple the reflected light from the thermal emission of the planet. From measurements of the solar spectrum (e.g. Fraunhofer 1918), we know that approximating stars and planets as black bodies is a bad approximation. The step up from this is to fit a planetary model spectrum to both Spitzer infrared eclipse depths and then extrapolate this model into the optical. Of course, two data points are not ideal for fitting a full atmospheric spectrum. The most ’correct’ method would be to take a full emission spectrum of the planet and jointly fit a reflected light component and a thermal emission component to obtain the true Ag. With the James Webb Space Telescope (JWST) optical-to-IR modes such as NIRSpec prism, we can begin to effectively decontaminate secondary eclipses. The Nancy Grace Roman Space Telescope is set for launch in 2027, which may increase the number of know planets by over an order of magnitude (Wilson et al. 2023; Tamburo et al. 2023), and enable direct imaging in reflected light (see, e.g. Carrión-González et al. 2021), giving us a more direct method of separating the thermal and reflected light.
Furthermore, the community has been working for over a decade to understand cloud formation in these planets, and this work will be crucial for creating more accurate atmospheric models. As we see on Earth, clouds reflect significant amounts of solar light and so it is reasonable to assume they would have an impact on the scattering in a hot Jupiter’s atmosphere. In Section 5.2, we discussed cases where clouds were and were not necessary to explain the derived geometric albedo, given a certain metallicity. Future work should now include trying to integrate a cloud model within a normal atmospheric model to estimate geometric albedos of planets. However this also depends on knowing the chemical compositions of a planet’s atmosphere, something that is now becoming possible for these larger planets with JWST.
6 Conclusion
In this paper, we have conducted an investigation into the geometric albedos of hot Jupiters, comparing observational data from several space telescopes - TESS, Kepler, CoRoT, and CHEOPS - with theoretical models. Our findings demonstrate that the geometric albedo of these exoplanets is primarily influenced by the abundance of atmospheric absorbers, with metallicity playing a crucial role. The observed albedo distributions across different bandpasses do not exhibit significant differences. This differs from the models for which, if chemical equilibrium is assumed, there is a clear separation between the geometric albedos in the TESS bandpass compared to the CHEOPS bandpass. However, there are large uncertainties on the observed datapoints that could be masking real structure in the distributions that is predicted by the models.
Our modelling efforts highlight the challenges in accurately predicting geometric albedos, especially when deviating from chemical equilibrium. The inclusion of additional absorbers such as TiO and VO in our models consistently results in lower albedos, emphasising the complexity of these atmospheres and how much the specific absorbers influence the reflectivity of the planet.
Looking forward, the introduction of more precise instruments, particularly JWST and the Nancy Grace Roman Space Telescope, will be influential in refining our understanding of these albedo measurements by providing more accurate spectral data. This will allow for better separation of reflected and thermal emission components and precision atmospheric composition measurements of hot Jupiter atmospheres. Our work lays the groundwork for future studies to further explore the connection between atmospheric composition and reflectivity in exoplanet atmospheres.
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Appendix A Geometric albedos of hot Jupiters
Collection of hot Jupiter exoplanets with their reported geometric albedo (Ag) and other stellar and planetary parameters.
Appendix B Likelihood distributions
Here we detail the likelihood distributions used to fit the Rayleigh, half-Gaussian and Beta distribution to the distribution of the observed geometric albedo data. K is the total number of Ag observations and N is the number of samples of each observation distribution.
(B.1)
(B.2)
(B.3)
Appendix C Testing the effect of additional absorption in Spitzer
Brightness temperatures vary across bandpasses, so using the thermal decontamination approach from Spitzer to TESS may neglect real differences in temperature with altitude. We tested the sensitivity of the model albedos with respect to changes in the near-infrared brightness temperature, as in Piette et al. (2020). We added 250 K to the Spitzer brightness temperature for all planets with Teq > 1800 K to investigate the impact of the Spitzer decontamination approach on the albedos. In Figure C.1, we show a version of Figure 2 that has the added temperature offset, and in Figure C.2, we show Figure 4 with the same offset.
![]() |
Fig. C.1 Distribution of observed geometric albedos for both bandpasses (CoRoT-Kepler-CHEOPS (CKC) in blue and TESS in orange), similar to Figure 2, but with some results modified to account for potential absorption in the Spitzer band (as explained in Section C. This histogram plot is made from 10,000 samples of each observation and then normalised. |
![]() |
Fig. C.2 Geometric albedos and physical parameters for targets observed with CoRoT-Kepler-CHEOPS (blue points) and TESS (orange points), but with some results modified to account for potential absorption in the Spitzer band (as explained in Section C. We have restricted the y axis to physical values of the geometric albedo, however it should be noted that some targets have median posterior values below 0. |
All Tables
Result of the trend analysis of the observed geometric albedos versus various stellar and planetary parameters (‘Independent Variable’ in this table).
Priors distributions for the input to our geometric albedo model assuming chemical equilibrium.
Prior distributions for the input to our geometric albedo model with chemical abundances scaling factors to shift the model away from chemical equilibrium.
Prior distributions for the input to our geometric albedo model with chemical abundance scaling factors to shift the model away from chemical equilibrium.
Prior distributions for the input to our geometric albedo model with condensation enabled and chemical abundance scaling factors to shift the model away from chemical equilibrium.
Collection of hot Jupiter exoplanets with their reported geometric albedo (Ag) and other stellar and planetary parameters.
All Figures
![]() |
Fig. 1 Transmission functions for CHEOPS, Kepler, CoRoT, and TESS instruments as a function of wavelength. In this study we group CHEOPS, Kepler, and CoRoT together due to their similarity in transmission functions. TESS is kept separate as it transmits more into the red. |
| In the text | |
![]() |
Fig. 2 Distribution of observed geometric albedos for both bandpasses (CoRoT-Kepler-CHEOPS (CKC) in blue and TESS in orange), where each observation (from Table A.1) is treated as a Gaussian distribution with a width given by the 1-sigma uncertainty reported. This histogram plot is made from 10000 samples of each observation and then normalised. The CKC sample peaks around Ag = 0.1, whereas the TESS sample has a wider peak and has a maximum at Ag = 0. However, this could be a result of the much wider error bars in the TESS data, smoothing out any peaks. |
| In the text | |
![]() |
Fig. 3 Three panels show the best-fit models (Rayleigh, half-Gaussian, and Beta distributions) plotted over the observed geometric albedos, with the shading showing the 1σ uncertainties in the fits. In orange is the TESS band and in the blue the CKC band. We find that the best-fit models from the two bandpasses are consistent. We also find that, by calculating the BIC of each fit, the Rayleigh distribution is the best-fitting model for this data (although not very significantly) and the Beta distribution the worst. |
| In the text | |
![]() |
Fig. 4 Geometric albedos and physical parameters for targets observed with CoRoT-Kepler-CHEOPS (blue points) and TESS (orange points). The trend results can be found in Table 2. We have restricted the y axis to physical values of the geometric albedo; however, it should be noted that some targets (WASP-18b and WASP-33b) have median posterior values below 0. |
| In the text | |
![]() |
Fig. 5 Geometric albedo model results, produced by sampling over the input parameter prior distributions (see Table 3) and assuming chemical equilibrium. The wavelength-dependent albedos were then bandpass-integrated to produce the expected albedos in the TESS (orange) and CKC (blue) band. Not shown are the albedos as a function of T*, Tplanet and pressure, as these show no discernible correlation. We find that the metallicity (log [M/H]) has the largest impact on the geometric albedo and that, from this, the water abundance produces slightly tighter constraints on Ag than sodium. We also see very distinct differences between the CHEOPS and TESS bandpasses. |
| In the text | |
![]() |
Fig. 6 Geometric albedo model results, produced by sampling over the input parameter prior distributions (see Table 4) and using a scaling factor distribution to move the model away from chemical equilibrium. The wavelength-dependent albedos were then bandpass-integrated to produce the expected albedos in the TESS (orange) and CKC (blue) band. We find similar results to the chemical equilibrium model: temperature and pressure had no effect on the geometric albedo (so they are not shown here), and metallicity is the main driver. Due to increased parameter space from the relaxation of the chemical equilibrium constraint, the posteriors of TESS and CKC albedos are now wider and begin to overlap slightly. It is clear that the higher the metallicity, the lower the geometric albedo. |
| In the text | |
![]() |
Fig. 7 The influence of the assumed priors for the underlying abundances of water and sodium on the modelled geometric albedo. In the left panel we show the distributions in the CHEOPS bandpass, and in the right one we show the distributions in the TESS bandpass. We overlay the observed distribution to suggest that perhaps the underlying effective metallicity distribution is within these ranges; however, we are also very aware that the uncertainties of the observations highly influence this shape (due to the low number of observations). |
| In the text | |
![]() |
Fig. 8 The influence of the permitted distance from equilibrium of the abundances of water and sodium on the modelled geometric albedo. This is mostly due to the fact that larger metallicities can be explored with a larger scaling prior. In the left panel we show the distributions in the CHEOPS bandpass, and in the right one we show the distributions in the TESS bandpass. Here we keep the metallicity distribution fixed to log U[–1,1]. We overlay the observed distribution. |
| In the text | |
![]() |
Fig. 9 Geometric albedo model results without condensation, produced by sampling over the input parameter prior distributions (see Table 5) and using a scaling factor distribution to move the model away from chemical equilibrium. The wavelength-dependent albedos were then bandpass-integrated to produce the expected albedos in the TESS (orange) and CKC (blue) band. We find that the presence of additional optical absorbers forces the albedo to stay near zero, even when the metallicity is low. |
| In the text | |
![]() |
Fig. 10 Geometric albedo model results including condensation, produced by sampling over the input parameter prior distributions (see Table 5) and using a scaling factor distribution to move the model away from chemical equilibrium. The wavelength-dependent albedos were then bandpass-integrated to produce the expected albedos in the TESS (orange) and CKC (blue) band. We find that high albedos are reachable with high metallicites, due to condensation removing the effect of metals from the upper atmosphere. |
| In the text | |
![]() |
Fig. C.1 Distribution of observed geometric albedos for both bandpasses (CoRoT-Kepler-CHEOPS (CKC) in blue and TESS in orange), similar to Figure 2, but with some results modified to account for potential absorption in the Spitzer band (as explained in Section C. This histogram plot is made from 10,000 samples of each observation and then normalised. |
| In the text | |
![]() |
Fig. C.2 Geometric albedos and physical parameters for targets observed with CoRoT-Kepler-CHEOPS (blue points) and TESS (orange points), but with some results modified to account for potential absorption in the Spitzer band (as explained in Section C. We have restricted the y axis to physical values of the geometric albedo, however it should be noted that some targets have median posterior values below 0. |
| In the text | |
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