Fig. 1

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Potential energy surface of the reactions of H-atom abstraction (e) and addition (a) with trans- and cis-CH2CHCHO molecules. The energies are provided in kJ mol−1 relative to the trans-CH2CHCHO (+2H•) species. The radical–radical reaction pathways hypothesized theoretically and generally expected, without computational verification, are indicated with dashed lines.
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