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Fig. 4

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Section of the reduced energy plot of 3-hydroxypropenal. Data points of υ = 0+ are shown in blue, those of υ = 0 in red; selected Ka series are indicated to the left. Resonant interactions with ΔKc = 2 are indicated by yellow circles. They occur at Kc = 43 for υ = 0+ and Kc = 45 for υ = 0 for 45 ≤ J ≤ 48. The resonant Kc pair increases gradually with J, Kc = 44 and 46 are resonant for 49 ≤ J ≤ 58. Two ΔKa = 3 interactions are resonant at Ka = 21/18 and J = 35 as well as Ka = 22/19 and J = 49 for ortho and J = 50 for para, which is signaled by green circles. Further ΔKa = 3 or 5 interactions are usually more local and are not highlighted.

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