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Table 4

Sum of photo-dissociation and photo-ionisation rates of the molecules at rh = 1.0 au.

Molecule Sum of photo-dissociation and photo-ionisation rate (× 10−5 s−1)
C1994 (a) H2015 (b) H2017 (c) Adopted (d) Comets (e)
H2O 1.3 1.21–2.20 0.9 1.21
HCN 1.5 1.31–3.24 0.8 1.54
HNC 1.54
HC3N 6.6 3.92–6.79 3.7 6.6 2–10
CH3CN 0.67 1.12–2.63 0.47 0.68 1–5
HNCO 2.9 2.87–5.08 2.9 2–10
NH2CHO 67 10.3 10.0 ~10
CH3NH2 67 24.4 20.0
C2H3CN 2
C2H5CN 2
CH3OH 1.3 1.14-2.07 0.85 1.31
H2CO 20 21–22 19.3 20.0 1–8 (f)
CO 0.075 0.075–0.188 0.055 0.065 <0.5–2
CH3CHO 7.5 17.9–18.2 18.2 18.0 8–20
HCOOH 3.2 88–113 10.0 5–15
C2H5OH 1.8 1.5 1.8 2–5
(CH2OH)2 2–5 3–10
HCOOCH3 4.7 4.7
CH2OHCHO 2
CH2CO 44 44
CH3COOH 5.1 5.1
CH3OCH3 3.1 3.1
CH3COCH3 5.0
c-C2H4O 10
H2S 25 32.6–26.8 23.1 25
CS 1.2 2.5 (g)
H2CS 20 (h) 2–30
OCS 9.4 10.2–13.0 6.9 9.4 4–20
SO 15 62–66 45 15 ~10 (f)
SO2 21 25–28 19.3 25
CH3SH 250–253 32.6 50
NS 5 (i)
Glycine 1000 (j)
PH3 6.1–7.6 6.1
PO 10
PN 10

Notes. (a) From Crovisier (1994) and references therein. (b)For the quiet and active Sun from Huebner &Mukherjee (2015). (c)Solar value from Heays et al. (2017): values given in bold have an uncertainty below 30%, and values in italics have an uncertainty larger than a factor of 2. (d) Assumed values with no constraint are in italics. (e)Constraints obtained from line width (see text, Appendix D, and e.g. Biver et al. 2011). (f) For H2 CO and SO, the constraint from line width is on the combined scale length of parent + daughter. For SO, it is compatible with the assumed SO2 and SO lifetimes (see also Boissier et al. 2007). (g)Estimate from Biver et al. (2011). (h)Value proposed by Woodney et al. (1999). (i)Centre of the range proposed by Irvine et al. (2000), which is estimated from the analogy between NS and NO and the fact that sulphur species have shorter lifetimes. (j)Value used in Hadraoui et al. (2019).

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