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Fig. 2

image

Schematic cross sections for photodissociation and their associated dynamical pathway (arrows) through ground and excited state potential-energy curves. For polyatomic molecules these curves represent a cross section through a multidimensional energy surface. We note that the integrated values of the various cross sections may be similar, leading to orders-or-magnitude greater peak magnitudes for indirect mechanisms. Modified from van Dishoeck & Visser (2015).

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