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Table B1

Input parameters for our photochemical model

Species Mixing ratio Flux [molecules cm−2 s−1] Deposition velocity [cm s−1]
CO2 4.6% - -

O2 Anoxic: 0% Oxic: 21% - -

H2Oa rel. hum. - -

CH4 - Abiotic: 108 Biotic: 1011 -

COb - Anoxic: 107 − 3.2 × 1012 Oxic: 2.1 × 106 − 6.7 × 1011 Abiotic: 10−8 Biotic: 1.2 × 10−4

NOb,c - Anoxic: 5.4 × 106 − 1.7 × 1012 Oxic: 3.5 × 107 − 1.1 × 1013 3 × 10−4

NO2 - - 3 × 10−3

HNO - - 1

HNO3c - - 0.2

H2b - Anoxic: 1010 (anoxic) Oxic: 0 2.4 × 10−4

H2Sb - Anoxic: 3.5 × 108 Oxic: 2 × 108 0.02

SO2b - Anoxic: 3.5 × 109 Oxic: 9 × 109 1

aDepending on surface temperatures. bDistributed over the lower 10 km of atmosphere. cOnly dry depositions

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