Issue 
A&A
Volume 601, May 2017



Article Number  A85  
Number of page(s)  22  
Section  Atomic, molecular, and nuclear data  
DOI  https://doi.org/10.1051/00046361/201630170  
Published online  10 May 2017 
Xray emission from thin plasmas
Collisional ionization for atoms and ions of H to Zn
^{1} SRON Netherlands Institute for Space Research, Sorbonnelaan 2, 3584 CA Utrecht, The Netherlands
email: i.urdampilleta@sron.nl
^{2} Leiden Observatory, Leiden University, PO Box 9513, 2300 RA Leiden, The Netherlands
Received: 29 November 2016
Accepted: 16 February 2017
Every observation of astrophysical objects involving a spectrum requires atomic data for the interpretation of line fluxes, line ratios, and ionization state of the emitting plasma. One of the processes that determines it is collisional ionization. In this study, an update of the direct ionization (DI) and excitationautoionization (EA) processes is discussed for the H to Znlike isoelectronic sequences. In recent years, new laboratory measurements and theoretical calculations of ionization crosssections have become available. We provide an extension and update of previous published reviews in the literature. We include the most recent experimental measurements and fit the crosssections of all individual shells of all ions from H to Zn. These data are described using an extension of Younger’s and Mewe’s formula, suitable for integration over a Maxwellian velocity distribution to derive the subshell ionization rate coefficients. These ionization rate coefficients are incorporated in the highresolution plasma code and spectral fitting tool SPEX V3.0.
Key words: atomic data / plasmas / radiation mechanisms: general / Xrays: general
© ESO, 2017
1. Introduction
In calculations of thermal Xray radiation from hot optically thin plasmas, it is important to have accurate estimates of the ion fractions of the plasma, since the predicted line fluxes sometimes depend sensitively on the ion concentrations. The ion concentrations are determined from the total ionization and recombination rates. In this paper, we focus on collisional ionization rates. Radiative recombination rates (Mao & Kaastra 2016) and charge exchange rates (Gu et al. 2016) are treated in separate papers. These rates are essential for the analysis and interpretation of highresolution astrophysical Xray spectra, in particular for the future era of Xray astronomy with Athena.
An often used compilation of ionization and recombination rates is given by Arnaud & Rothenflug (1985), AR hereafter. AR treat the rates for 15 of the most abundant chemical elements. Since that time, however, many new laboratory measurements and theoretical calculations of the relevant ionization processes have become available. A good example is given by Arnaud & Raymond (1992), who reinvestigated the ionization balance of Fe using new data. Their newly derived equilibrium concentrations deviate sometimes even by a factor of 2–3 from AR. The most recent review has been performed by Dere (2007), D07 hereafter. D07 presents total ionization rates for all elements up to the Zn isoelectronic sequence that were derived mainly from laboratory measurements or Flexible Atomic Data (FAC, Gu 2002) calculations.
Motivated by the findings of AR and D07, we started an update of the ionization rates, extending it to all shells of 30 elements from H to Zn. Since we want to use the rates not only for equilibrium plasmas but also for nonequilibrium situations, it is important to know the contributions from different atomic subshells separately. Under nonequilibrium conditions inner shell ionization may play an important role, both in the determination of the ionization balance and in producing fluorescent lines.
In the following Sect. 2, we give an overview of the fitting procedure used in this work. In Sect. 3, we review the ionization crosssections obtained from experimental measurements or theoretical calculations along isoelectronic sequences. Details of the ionization rate coefficients analytical approach are given in Sect. 4, Appendices B and C. In Sect. 5 we compare and discuss the results of this work. The references used for the crosssections are included in Appendix A.
2. Fitting procedure
Collisional ionization is mainly dominated by two mechanisms: direct ionization (DI), where the impact of a free electron on an atom liberates a bound electron; and excitationautoionization (EA), when a free electron excites an atom into an autoionizing state during a collision.
2.1. Direct Ionization crosssections
An important notion in treating DI is the scaling law along the isoelectronic sequence, as first obtained by Thomson (1912): (1)where u = E_{e}/I with E_{e} (keV) the incoming electron energy and I (keV) the ionization potential of the atomic subshell; Q (10^{24} m^{2}) is the ionization crosssection. The function f(u) does not – in lowest order – depend upon the nuclear charge Z of the ion, and is a unique function for each subshell of all elements in each isoelectronic sequence.
Direct ionization crosssections are most readily fitted using the following formula, which is an extension of the parametric formula originally proposed by Younger (1981a): (2)The parameters A, B, D, and E are in units of 10^{24} m^{2} keV^{2} and can be adjusted to fit the observed or calculated DI crosssections, see Sect. 2.3 for more details. R is a relativistic correction discussed below. C is the Bethe constant and corresponds to the high energy limit of the crosssection.
The parameter C is given by Younger (1981c): (3)where σ(E) is the photoionization crosssection of the current subshell, E_{H} the ionization energy of hydrogen and α the fine structure constant. The Bethe constants used in this paper are derived from the fits to the HartreeDiracSlater photoionization crosssections, as presented by Verner & Yakovlev (1995).
As mentioned above, Eq. (2) is an extension of Younger’s formula, where we have added the term with . The main reason to introduce this term is that in some cases the fitted value for C, as determined from a fit over a relatively low energy range, differs considerably from the theoretical limit for u → ∞ as determined from Eq. (3). For example, AR give C = 12.0 × 10^{24} m^{2} keV^{2} for their fit to the 2p crosssection of C i, while the Bethe coefficient derived from Eq. (3) is 6.0 × 10^{24} m^{2} keV^{2}. However, if we fix C to the Bethe value in the fit, the resulting fit sometimes shows systematic deviations with a magnitude of 10% of the maximum crosssection. This is because the three remaining parameters A, B, and E are insufficient to model all details at lower energies. Therefore, we need an extra fit component which, for small u is close to lnu, but vanishes for large u, to accommodate for the discrepancy in C.
The relativistic correction R in Eq. (2) becomes important for large nuclear charge Z (or equivalently large ionization potential I) and large incoming electron energy E (Zhang & Sampson 1990; Moores & Pindzola 1990; Kao et al. 1992). This expression is only valid for the midly relativistic (ϵ ≲ 1, where ϵ ≡ E/m_{e}c^{2}) regime. Our approximations and crosssections do not apply to the fully relativistic regime (ϵ ≳ 1). The presence of this correction is clearly visible for the hydrogen and helium sequences, as shown in Fig. 2. Using a classical approach the relativistic correction can be written here as given by, for example, Quarles (1976) and Tinschert et al. (1989): (4)where τ ≡ I/m_{e}c^{2}, with m_{e} the rest mass of the electron and c the speed of light. The above correction factor R, when applied to the simple Lotzapproximation (Lotz 1967), is consistent with the available observational data for a wide range of nuclear charge values (Z = 1–83) and 5 mag of energy, within a range of about 15% (Quarles 1976).
For the present range of ions up to Zn (Z = 30), the ionization potential is small compared to m_{e}c^{2} and, hence, τ is small. On the other hand, we are interested in the crosssection up to high energies (~100 keV) that applies to the hottest thin astrophysical plasmas, and therefore ϵ is not always negligible. By making a Taylor’s expansion in ϵ of Eq. (4) for small τ we obtain(5)We will use this approximation Eq. (5) in our formula for the DI crosssection Eq. (2).
Analysing the asymptotic behaviour of Eq. (2) Therefore, it is evident from Eq. (6) that the fit parameters A to E must satisfy the constraint A + C + D + E> 0. Further, the Bethe constant C gives the asymptotic behaviour at high energies.
It appears that when u is not too large, lnu can be decomposed as (see Fig. 1) (8)Equation (8) has a relative accuracy that is better than 1, 3, and 16% for u smaller than 50, 100, and 1000, respectively; and the corresponding crosssection contribution lnu/u deviates never more from the true crosssection than 0.5% of the corresponding maximum crosssection (which occurs at u = e).
Fig. 1 Approximation to the Bethe crosssection. 
In all cases, where we do not fit the crosssection, based on Eq. (8), we use the following expression for the calculation of Younger’s formula parameter (with A(ref), B(ref), C(ref), D(ref) and E(ref)), as given by the parameters of the isoelectronic sequence that we use as reference. For example, the Lisequence is used as reference for the 1s crosssections of the Be to Znsequences as detailed in Sect. 3.4.1. (9)This assures that, for most of the lower energies, the scaled crosssection is identical to the reference crosssection, while at high energies it has the correct asymptotic behaviour.
In some cases, we can get acceptable fits with D = 0. In these cases, we obtain a somewhat less accurate approximation for the logarithm: (10)Equation (10) has a relative accuracy better than 14, 23, and 45% for u smaller than 50, 100, and 1000, respectively; and the corresponding crosssection never deviates more from the true crosssection than 5.6% of the maximum crosssection (which occurs at u = e).
In the case of D = 0, the equivalent of Eq. (9) becomes (11)
2.2. Excitationautoionization crosssections
The excitationautoionization (EA) process occurs when a free electron excites an atom or ion during a collision. In some cases, especially for the Li and Na isoelectronic sequence, the excited states are often unstable owing to Auger transitions, leading to simultaneous ejection of one electron and decay to a lower energy level of another electron. Many different excited energy levels can contribute to the EA process. In general, this leads to a complicated total EA crosssection, showing many discontinuous jumps at the different excitation threshold energies. Since in most astrophysical applications we are not interested in the details of the EA crosssection, but only in its value averaged over a broad electron distribution, it is reasonable to approximate the true EA crosssection by a simplified fitting formula.
The EA crosssection is most readily fitted using Mewe’s formula, originally proposed to fit excitation crosssections by Mewe (1972): (12)where u ≡ E_{e}/I_{EA} with E_{e} the incoming electron energy; Q_{EA} is the EA crosssection. The parameters A_{EA} to E_{EA} and I_{EA} can be adjusted to fit the observed or calculated EA crosssections. We note that Arnaud & Raymond (1992) first proposed to use this formula for EA crosssections, although they used a slightly different definition of the parameters.
For the Li, Be, and B isoelectronic sequences, we used the calculations of Sampson & Golden (1981). All the necessary formulae can be found in their paper. The scaled collision strengths needed were obtained from Golden & Sampson (1978), Table 5. For these sequences, we used the sum of two terms with Eq. (12), the first term corresponding to excitation 1s2ℓ, and the second term corresponding to all excitations 1snℓ with n> 2. The total fitted EA crosssection deviates no more than 5% of the maximum EA contribution, using the exact expressions of Sampson and Golden. Since, for these sequences, the EA contribution is typically less than 10% of the total crosssection, our fit accuracy is sufficient given the systematic uncertainties in measurements and theory.
For the Na to Ar isoelectronic sequences, AR recommends to extend the calculations for the Nasequence of Sampson (1982) to the MgAr sequences. In doing so, they recommend to put all the branching ratios to unity. We follow the AR recommendations and use the method described in Sampson (1982), extended to the MgAr sequences, to calculate the EA crosssection. We consider the branching ratio unity for these calculations. We include excitation from the 2s and 2p subshells to the ns, np, and nd subshells with n ranging from 3–5. We then fit these crosssections to Eq. (12), splitting it into two components: transitions towards n = 3 and n = 4,5. The advantage of this approach is that we can estimate the EA contribution for all relevant energies. Other theoretical EA calculations are often only presented for a limited energy range.
For the K to Cr isoelectronic sequences we obtain the EA parameters by fitting to Eq. (12) the FAC EA crosssections of D07, which are the same used by CHIANTI.
2.3. Fitting experimental and theoretical data
The main purpose of our fitting procedure is to obtain the parameters A, B, D, and E of Eq. (2) for all inner and outer shells that contribute to DI process, together with the EA parameters, which are calculated as explained above.
For the H and Hesequences, the DI parameters are obtained directly by fitting the crosssections from experimental measurements and theoretical calculations listed in Appendix A. The rest of sequences include the DI contribution of the outer and one or several inner shells. In this case, we cannot perform a direct fit to the data because most papers in the literature only present the total crosssections, which are not split into subshells, while our purpose is to obtain the individual outer and inner shell crosssections separately.
For this reason, we calculate first the EA and inner shell DI parameters and crosssections. The particular method used for each isoelectronic sequence is explained in Sect. 3. Afterwards, to obtain the outer shell crosssection (for example for the Lilike sequence, 2s), we subtract the inner shell (in the Lilike case, 1s) and EA contributions from total crosssection. We then fit this outer shell contribution using Eq. (2) and obtain the parameters A, B, D, and E.
The remaining crosssections, for which no data are present are obtained, using Eq. (2) with interpolated or extrapolated DI parameters. In this case, A, B, D, and E are calculated by applying linear interpolation or extrapolation of the DI parameters derived from the fitting of experimental or theoretical data along the same shell and isoelectronic sequence. The parameter C is always calculated using Eq. (3).
3. Ionization crosssections
The detailed discussion of the available data used for fitting the crosssections can be found in the following subsections. In general, we follow the recommendations of AR and D07 in selecting the most reliable data sets, but also other reviews like Kallman & Palmeri (2007) have been take into account. We do not repeat their arguments here, therefore only the relevant differences in the selection criteria and application in the code have been highlighted. Moreover, the multisearching platform GENIE^{1} has additionally been used as crosscheck. The references for the crosssection data sets used for each isoelectronic sequence (experimental data e or theoretical calculation t) are listed in Appendix A.
Fig. 2 Total DI normalized crosssection for Fe xxvi (dashed blue line) and the measurements of Kao et al. (1992; red dots) and Moores & Pindzola (1990; green triangles). Note the presence of relativistic effects for high energies. 
3.1. H isoelectronic sequence
The crosssections for this sequence include only the direct ionization process from the 1s shell. For He ii, the crosssections of Peart et al. (1969) have been selected instead of Dolder et al. (1961), Defrance et al. (1987) and Achenbach et al. (1984), because they have a larger extension to the highest energies and an acceptable uncertainty of 12%, compared to Dolder et al. (1961) with 25%.
Relativistic effects are important for the high Z elements of this sequence. This is the reason why the relativistic crosssections of Kao et al. (1992) and Fontes et al. (1999) for Ne x; Kao et al. (1992) and Moores & Pindzola (1990) for Fe xxvi; and Moores & Pindzola (1990) for Cu xxix have been chosen. They are, in general, around 5–10% larger than the nonrelativistic ones. These effects are mainly present for high Z elements of the H and He isoelectronic sequences, as can be seen in Fig. 2, where the total DI normalized crosssection of Fe xxvi is shown. For this ion the crosssection increases asymptotically with the energy beyond u = 100. The measurements of O’Rourke et al. (2001) for Fe xxvi has been neglected because they present a considerable experimental error and are in poor agreement with the selected calculations.
The crosssection comparison of this sequence with D07 shows a good agreement for all the elements except for Be iv. We calculate by linear interpolation in 1 /Z between Li iii and B v, which are fitted by experimental measurements. The value at the peak for our interpolation is 20% lower than the values used by D07. However, it follows a smooth increase, which is consistent with the trend of the rest of the elements in this sequence.
3.2. He isoelectronic sequence
The Helike ions have an 1s^{2} structure and the DI process includes ionization of the 1s shell. For He i, the experimental data of Shah et al. (1988) and Montague et al. (1984b) have been used together with the more recent measurements of Rejoub et al. (2002). These data sets are in very good agreement with the crosssections presented in Rapp & EnglanderGolden (1965), although the value at the peak is 6% lower. The final fit has an uncertainty less than 6%. For Li ii, the measurements of Peart & Dolder (1968) and Peart et al. (1969) were selected, as shown in Fig. 3, an example of the 1s shell DI fitting. For Be iii the same difference with D07 as described for the Hlike sequence occurs as well. The peak value using our linear interpolation in 1/(Z−1) is 30% lower than D07.
Since the data range for Ne ix, as measured by Duponchelle et al. (1997), is rather limited, we have supplemented their data by adding the crosssections at u = 100, as interpolated from the calculations of Zhang & Sampson (1990) for O vii and Fe xxv.
The relativistic calculations for O vii, Fe xxv, and Zn xxix of Zhang & Sampson (1990) yield crosssections that are about 15% larger at the higher energies than the corresponding crosssections interpolated from the theoretical results for N, Na and Fe (Younger 1981a, 1982a). This is similar to what we find for the Hlike sequence, and is in agreement with the relativistic effects expected for high Z elements.
Fig. 3 Total DI normalized crosssection for Li ii (dashed blue line) and the measurements of Peart & Dolder (1968; red dots) and Peart et al. (1969; green triangles) with their respective experimental error. 
3.3. Li isoelectronic sequence
Li sequence ions have a structure of 1s^{2}2s and can experience DI in both the 1s and 2s shell with a significant presence of an EA contribution in the outer shell, mainly for highly ionized elements. The DI and EA crosssections are calculated with the equations described in Sects. 2.1 and 2.2, respectively.
3.3.1. DI: 1s crosssections
Younger (1981a) showed that, except for the lower end of the sequence, the crosssections are similar to the values for the Hesequence. This is confirmed by the work of Zhang & Sampson (1990) for O, Fe, Zn, and U. Wherever needed, we have corrected for a difference in the Bethe constant between the Helike and Lilike sequence using Eq. (11). We note that, again for Ni, the crosssections of Pindzola et al. (1991) are 15–25% lower than those of Zhang & Sampson (1990).
In summary, we used Younger (1981a) for Li i, Be ii; the corresponding crosssection of the Hesequence for B iii, C iv, N v; Zhang & Sampson (1990) for O vi, Fe xxiv and Zn xxviii; and linear interpolation in 1/(Z−1) for the remaining crosssections.
3.3.2. DI: 2s crosssections
For Li i, we follow the recommendations of McGuire (1997) and we fit the convergent closecoupling calculations of Bray (1995) below 70 eV, together with the measurements of Jalin et al. (1973) above 100 eV.
For B iii, C iv, N v, O vi, and F vii, high resolution measurements exist near the EA threshold (Hofmann et al. 1990). These measurements are systematically higher than the measurements of Crandall et al. (1979) and Crandall et al. (1986), ranging from 9% for B iii, 24% for N v to 31% for O vi. Moreover, for C iv Hofmann’s data above the EA onset are inconsistent in shape with both Crandall’s measurements and the calculations of Reed & Chen (1992). Therefore we did not use the measurements of Hofmann et al. (1990).
For N v, the measurements of Crandall et al. (1979) are ~10% smaller than Defrance et al. (1990) below 300 eV, but 10% larger above 1000 eV. In the intermediate range, where the EA onset occurs, the agreement is better than 5%. We used Crandall et al. (1979), together with the high energy data of Donets & Ovsyannikov (1981).
For O vi, the measurements of Crandall et al. (1986) are ~10% smaller than those of Defrance et al. (1990) below 450 eV and above 800 eV. In the intermediate range, where the EA onset occurs the agreement is good. We have used both data sets in our fit, but scaled the measurements of Defrance et al. by a factor of 0.95, and also we have included the high energy data of Donets & Ovsyannikov (1981). Using the statistical errors in the data sets, the relative weights used in the fit are approximately 5:1:2 for Crandall et al., Defrance et al., and Donets & Ovsyannikov, respectively.
For Fe xxiv and Zn xxviii, we again considered the relativistic calculations of Zhang & Sampson (1990). Their scaled crosssections for O vi, Fe xxiv, and Zn xxviii are not too different; therefore we interpolate linearly in 1/(Z−1) all elements between Ne and Fe, and similarly between Fe and Zn.
For Ti to Fe, measurements also exist at about 2.3 times the ionization threshold (Wong et al. 1993) with an uncertainty of 10%, which are also proposed by D07. The ratio of these observed crosssections to the calculations are 0.83, 0.81, 0.85, 0.84, and 0.97, respectively for Z = 22–26. Given the measurement uncertainty, and the agreement of the calculations of Zhang & Sampson in the region of overlap with those of Chen & Reed (1992), we finally decided to use the calculations of Zhang & Sampson.
As for the 1s crosssections in the H, He, and Li sequences, the crosssections of Younger (1982a) for Fe xxiv are 5% smaller than those of Zhang & Sampson at the highest energies, instead of the typically 15% for the 1s crosssections. Thus relativistic effects are slightly less important, which can be understood given the lower ionization potential for the 2s shell, compared to the 1s shell.
Fig. 4 Total DI (dashed blue line) and DI plus EA (orange line) normalized crosssection for B iii, where the DI contribution of the 1s shell is shown as the dotted cyan line and the 2s shell in magenta. The measurements of Crandall et al. (1986; red dots) with the experimental uncertainties are also included. 
3.3.3. EA contribution
Fits to the calculations of Sampson & Golden (1981) were used to approximate the shape of the EA contribution. The contributions, which are due to excitation towards n = 2–5, are treated separately. A comparison of the results of Sampson & Golden(Q_{SG}) with the more sophisticated calculations of Reed & Chen (1992) and Chen & Reed (1992) (Q_{RC}) just above the 1s2p excitation threshold for Z = 6, 9, 18, 26, and 36 gives for the ratio Q_{RC}/Q_{SG} values of 0.52, 0.64, 0.77, 1.18, and 2.02, respectively. The following approximation has been made to these data: (13)A similar tendency is noted by AR. A more detailed analysis shows that for larger energies the discrepancy is slightly smaller. Unfortunately, Reed & Chen and Chen & Reed only give the EA crosssection near the excitation thresholds. Therefore, we decided to retain the calculations of Sampson & Golden (1981), but to scale all EA crosssections using Eq. (13). We note that, for this isoelectronic sequence, the EA contribution is, in general, smaller than ~10%, and thus slight uncertainties in the EA crosssection are not very great in the total ionization crosssection. Figure 4 shows an example of Lilike ion crosssections scaling.
3.4. Be isoelectronic sequence
The Be sequence elements have a structure of 1s^{2}2s^{2} and can experience DI through collisions in the 1s and 2s shells. There is also an EA contribution. Moreover, in experimental data, some elements, like C iii, N vi, and O v often show a high population of ions in metastable levels 1s^{2}2s2p.
3.4.1. DI: 1s crosssections
The 1s crosssections for all elements in the Be to Zn isoelectronic sequences have been calculated with Eq. (11) and, using as a reference, the parameters obtained for the 1s inner shell of Lilike ions. An example can be seen in Fig. 5 for the oxygen isoelectronic sequence.
A comparison of some Kshell measurements compiled by Llovet et al. (2014), for example for C i, Al i, and Ti i (Limandri et al. 2012), demonstrated a good agreement with the maximum difference between the measurements and the calculations with Eq. (11) at the peak for Ti i of less than 15%.
Fig. 5 Total DI crosssection for the 1s subshell for all elements of the oxygen sequence using interpolation with Eq. (11). 
3.4.2. DI: 2s crosssections
The measurements in this sequence are often greatly affected by metastable ions (see the discussion in AR). As mentioned in Loch et al. (2003) and Loch et al. (2005), it is essential to know the ratio of the metastable configuration for an accurate determination of the groundstate crosssection.
D07 proposes using the measurements of Falk et al. (1983a) for B ii, which we discard owing to the existence of a significant population of ions in metastable levels, which results in a groundstate crosssection higher than that proposed by Fogle et al. (2008) for C iii, N iv, and O v. Fogle’s measurements use the crossedbeam apparatus at Oak Ridge National Laboratory. In this experiment, it was possible to measure the metastable ion fractions present in the ion beams in the 1s^{2}2s2p levels, which were used to infer the rate coefficients for the electronimpact single ionization from the ground state and metastable term of each ion. Considering these mentioned rates in the paper for the ground crosssections calculations, they are in good agreement (error of ~7% for C iii and ~2% for N iv and O v) with the crosssections obtained by the Younger (1981d) theoretical calculation. The measurements of Loch et al. (2003) for O v have been neglected because it was not possible to determine the metastable fraction at the experimental crossedbeam.
The measurements of Bannister for Ne vii are consistent with the Duponchelle et al. (1997) ones at high energies, but show a bump around 280 eV, and are finally rejected. For S xiii, Hahn et al. (2012a) eliminated all metastable levels using hyperfine induced decays, combined with an ion storage ring, obtaining a total crosssection with 1σ uncertainty of 15%. The measurements are in very good agreement with the theoretical data of Younger (1981c) and distortedwave calculation of D07.
Lacking more reliable measurements for this isoelectronic sequence, and given the reasonable agreement with the measurements for Ne vii, we base our crosssections on the theoretical calculations of Younger (Younger 1981d, 1982a) for F vi, Ar xv, and Fe xxiii. The calculations of Fe xxiii have been multiplied by a scaling factor of 1.05, to account for these effects, as are present in the Lisequence for 2s electrons.
3.4.3. EA contribution
For all ions of this sequence, we also include the EA contribution according to Sampson & Golden (1981), although the contribution is small (in general smaller than ~5%). A comparison of the results of Sampson & Golden(Q_{SG}) with the more recent calculations of Badnell & Pindzola (1993) (Q_{BP}), which include calculations for only Fe, Kr, and Xe just above the 1s2p excitation threshold, was performed. This shows a systematic trend that can be approximated by (14)We assume that the rest of the elements of this isoelectronic sequence present the same behaviour. Therefore, we use the calculations of Sampson and Golden (1981), but scale all EA crosssections to the results of Badnell & Pindzola using Eq. (14).
3.5. The B isoelectronic sequence
The elements of the Blike sequence (1s^{2}2s^{2}2p) have an EA contribution in the outer shell that is relatively small (Yamada et al. 1989a; Duponchelle et al. 1997; Loch et al. 2003).
3.5.1. DI: 2s crosssections
Younger (1982a) shows that, for the iron ions of the Be to Ne sequences, the 2s crosssection is approximately a linear function of the number of the 2p electrons present in the ion. Following AR, we assume such a linear dependence to hold for all ions of these sequences. Thus, from the 2s crosssections for the Besequence and those of the Nesequence, the 2s crosssections for all ions between Na–Zn for intermediate sequences (Blike, Clike, Nlike, Olike, and Flike) are obtained by linear interpolation plus the Bethe coefficient difference correction applying Eq. (9).
For ions of B to F in the BF isoelectronic sequences, we cannot use the above interpolation since, in this case, there are no ions in the Nesequence. AR assume that the 2s crosssection of the Nesequence minus the 2s crosssection of the Besequence depends linearly upon the atomic number Z; since our procedure is slightly different from Arnaud & Rothenflug, we cannot confirm clear linear trends in our data. For that reason, we use for the ions from B to F a linear extrapolation of the difference coefficients given by AR: (15)where Z is the atomic number and A, B, and E are in units of 10^{24} m^{2} keV^{2}.
3.5.2. DI: 2p crosssections
For B i, we included the CHIANTI data obtained from (Tawara 2002; D07). The data of Aitken et al. (1971) for C ii are slightly higher than the measurements of Yamada et al. (1989a), especially near the threshold. Nevertheless, we use both data sets in our fit, with a larger weight given to the data of Yamada et al.
For N iii, we chose Aitken et al. (1971) and Bannister & Havener (1996) proposed by D07 because both data sets extend from near threshold to u = 20 and, besides, they are in relatively good agreement, except below the peak where the data of Bannister & Havener (1996) are ~5% higher.
The most recent measurement for the Bsequence is that of Hahn et al. (2010) for Mg viii. The innovative aspect of the Hahn et al. data is the use of an ion storage ring (TSR) for the measurements. This new experimental technique achieves a radiative relaxation of ions to the ground state after being previously stored long enough in the TSR, decreasing considerably the contribution of possible metastable ions. The data show a 15% systematic uncertainty owing to the ion current measurement. Nevertheless, the data are in good agreement with the distortedwave calculations with the GIPPER (Magee et al. 1995) and FAC (Gu 2002) codes, within the experimental uncertainties.
The theoretical data for Fe xxii are based upon Zhang & Sampson (1990) for Nelike iron. Following Younger (1982a), we assume that the scaled 2p crosssection for Blike to Nelike iron is a linear function of the number of 2pelectrons; we account for the slight difference in 2p_{1/2} and 2p_{3/2} crosssections in the work of Zhang & Sampson. Finally, we use their data for Se (Z = 34) to interpolate the ions between Fe and Zn on these sequences.
3.5.3. EA contribution
For all ions of this sequence, we include the EA contribution according to Sampson & Golden (1981), although the contribution is small (in general less than ~2.5%). A comparison of the results of Sampson & Golden(Q_{SG}) with the calculations of Badnell & Pindzola (1993) (Q_{BP}) for Fe, Kr and Xe just above the 1s2p excitation threshold, shows a systematic trend that can be approximated by (16)We retain the calculations of Sampson & Golden, but scaled all EA crosssections to the results of Badnell & Pindzola using Eq. (16).
3.6. C isoelectronic sequence
The ions of the carbon isoelectronic sequence (1s^{2}2s^{2}2p^{2}) can be directly ionized by the collision of a free electron with electrons in the 1s, 2s, and 2p shells; the same holds for all sequences up to the Nelike sequence. There is no evidence for a significant EA processes in the C to Ne sequences.
3.6.1. DI: 2p crosssection
For O iii, we use the measurements of Aitken et al. (1971), Donets & Ovsyannikov (1981), and Falk (1980). The first two are provided up to ten times the threshold. The Aitken et al. (1971) measurements are ~15% lower than those of Falk (1980) beyond the crosssection peak. We also use the data of Donets & Ovsyannikov (1981) for the high energy range. Figure 6 shows an example of the DI contribution for the 2s and 2p shells.
3.7. N isoelectronic sequence
3.7.1. DI: 2p crosssection
The measurements for Si viii (Zeijlmans van Emmichoven et al. 1993) were correctly fitted using Eq. (2), obtaining a maximum uncertainty of ~6%. The peak value of Si viii compared with CHIANTI data is ~10% lower. This difference also affects the crosssections of interpolated components between Ne iv and Si viii.
The data of Yamada et al. (1989a) for O ii are about 5% higher than the older data of Aitken et al. (1971); our fit lies between both sets of measurements. For O ii and Ne iv, the high energy measurements of Donets & Ovsyannikov (1981) are significantly higher than our fit, including that data set; we have therefore discarded these measurements for these ions.
3.8. O isoelectronic sequence
3.8.1. DI: 2p cross section
We note that the measurements for Si vii (Zeijlmans van Emmichoven et al. 1993) could be affected by metastable ions that show an increase between 10–20% of the crosssection at the peak compared with the distortedwave calculations. This is the reason we neglect this data set. For Ne iii, we discard the high energy measurements of Donets & Ovsyannikov since these are 30% below our fit including those data.
3.9. F isoelectronic sequence
Fig. 6 Total DI normalized crosssection for Ne ii (dashed blue line) and the measurements of Yamada et al. (1989a; red dots) with the experimental uncertainties. 
3.9.1. DI: 2p crosssection
The Yamada et al. (1989a) measurements were included for F i up to u = 10. The most recent measurements in this sequence are from Hahn et al. (2013) for Fe xviii up to energies of u = 3. The measurements given by Hahn et al. (2013) are 30% lower than the values provided by Arnaud & Raymond (1992) and 20% lower than D07. This is achieved by the new experimental technique of the ion storage ring. We combine these data with the theoretical calculations of Zhang & Sampson (1990) for high energies. These theoretical data were obtained directly from the total crosssection modelling for the 2p shell, as explained in Sect. 3.5.2. Figure 7 shows the DI fitting of four different experimental measurements for Ne ii.
Fig. 7 The DI normalized crosssection for Ne ii (dashed blue line) and the measurements of Achenbach et al. (1984; red dots), Diserens et al. (1984; green triangle), Donets & Ovsyannikov (1981; blue square) and Man et al. (1987a; cyan square) with their respective experimental uncertainties. 
3.10. Ne isoelectronic sequence
3.10.1. DI: 2s crosssection
For Na, Mg and Al Younger (1981c) calculates the 2s crosssections in the Nalike sequence. For the high Z end of the sequence (Ar and Fe), the difference between the Nelike and Nalike 2s crosssection is, in general, at most a few percent. Accordingly, we assume that, for the low Z end of the Nesequence, the shape of the crosssection is at least similar to that of the Nasequence.
Therefore, we have extrapolated the Nalike data of Younger (1981c) to obtain the crosssections of Na ii, Mg iii, Al iv, P vi, and Ar ix. We found that the ratio of the Nelike to the Nalike 2s crosssection is about 1.38, 1.23, 1.06, and 1.00 for the elements Na, Mg, Al, and Ar. We included a scaling factor of 1.00 for P. Our adopted 2s ionization crosssection for the Nelike ions Na ii, Mg iii, Al iv, P vi, and Ar ix are thus based upon the corresponding Nalike crosssection, multiplied by the above scaling factors. Lacking other data, for Ne i we simply used the correlation Eq. (15) between Nelike and Belike 2s crosssections. For the remaining elements from Si and higher, we use linear interpolation in 1/(Z−3).
3.10.2. DI: 2p crosssections
We used the calculations of Younger (1981b) for the 2p shell of Al iv instead of the Aichele et al. (2001) measurements because, as they explain, their data contain a 20% contribution from metastable ions contamination.
For Ar ix, we did not use the data of Zhang et al. (1991), because they contain a 3% contribution of a metastable state, which is strongly autoionising. The contribution of this metastable state, which is described well by the calculations of Pindzola et al. (1991), makes the measured crosssection ~5% higher at 1 keV; however, owing to the complex ionization crosssection of this metastable state, we do not attempt to subtract it, but merely use the data of Defrance et al. (1987) and Zhang et al. (2002) for this ion, which appears to be free of metastable contributions.
We have used the measurements of Hahn et al. (2013) for Fe xvii up to energies close to u = 3, together with Zhang & Sampson (1990) for high energies, as in the same case of Fe xviii, see Fig. 8.
Fig. 8 Total DI normalized crosssection for Fe xvii (dashed blue line) and the measurements of Hahn et al. (2013) (red dots), and calculations of Zhang & Sampson (1990; green triangles). 
3.11. Na isoeletronic sequence
3.11.1. DI: 2s and 2p crosssection
We use the theoretical calculations of Younger (1981c) for Mg ii, Al iii, P v, and Ar viii and Pindzola et al. (1991) for Ni xviii. The remaining elements have been interpolated, except for Na i, for which we adopted the scaled Mg ii parameters.
3.11.2. DI: 3s crosssection
We decided not to include the measurements for Ar viii (Rachafi et al. 1991; Zhang et al. 2002) and Cr xiv (Gregory et al. 1990), because they are higher and lower, respectively, compared with the other elements on this sequence. The Ar viii measurements are probably affected by the presence of resonant excitation double Auger ionization (REDA).
Ti xii was fitted using Gregory et al. (1990), although there are only measurements up to u = 3. For this reason we included some values from Griffin et al. (1987) calculation for higher energies. The data of Gregory et al. (1990) are about 10% higher than the calculations of Griffin et al. (1987), therefore we decided to apply a scaling factor of 0.9.
For Fe xvi, the measurements of Gregory et al. (1987) and Linkemann et al. (1995) were used, which extend till u = 2. The data of Gregory et al. (1987) are 30% higher than those of Linkemann et al. (1995), resulting in a fit with values around 15% higher than proposed by the Griffin et al. (1987). To achieve a better agreement of 5–10%, we applied a scaling factor of 0.9 to the Gregory et al. (1987) measurements. Finally, we included the theoretical calculations of Pindzola et al. (1991) for Ni xviii, which agree with Griffin et al. (1987) better than 10%.
The total crosssections obtained with our method are systematically higher than D07 by 10–30%. For several elements, the DI level seems to be of the same order and the main difference is related to EA contributions. A possible explanation could be that we use the calculations of Sampson (1982), which include more excitation transitions (from 2s, 2p, and 3s subshells to the ns, np and nd subshells with n = 3–5), while D07 use the FAC EA calculation scaled by a certain factor for excitation into 2^{7} 3l3l′ and 2^{7} 3l4l′.
3.11.3. EA contribution
For the low Z elements of this sequence (Mg ii, Al iii and Si iv) the theoretical calculations of Griffin et al. (1982) for the EA contribution fail to correctly model the measurements, mainly due to too large 2p→3p and 2p→4p crosssections, but also becuase of the presence of REDA contributions in the measured crosssections (Müller et al. 1990; Peart et al. 1991b). The measured crosssections show a distinct EA contribution, but not with the sharp edges that are usually produced by theory owing to limitations in the way the EA contribution is calculated. Therefore, we fitted the measured crosssections of Mg ii, Al iii, and Si iv to (12) after subtracting the DI contributions.
For Na i and Mg ii, there are no signs of the EA onset owing to the regularity of the measurements although some REDA contributions could be present. For Al iii and Si iv, we have followed the same procedure chosen by D07 for scaling all the EA crosssections to recreate the measured values. Therefore, we retained the calculations of Sampson (1982), but scaled by a factor of 0.4 for Al iii and 0.5 for Si iv. The rest of elements have been maintained with a scaling factor equal to 1.0.
3.12. Mg isoelectronic sequence
3.12.1. DI: 2s and 2p crosssection
The 2s and 2p crosssections for all elements from the Mg to Zn isoelectronic sequences have been calculated with Eq. (9) using, as a reference, the parameters obtained for the 2s and 2p subshell, respectively, of the previous isoelectronic sequence. Therefore, for the Mgsequence, the reference parameters for all elements are taken from the Nasequence.
To evaluate the robustness of this method, we introduced a 10% and 20% increase in the A to E parameters of the Fe xv 2s shell and analysed how it affects the 2s shells of Fe ions for the following isoelectronic sequences. If we compare the difference in the peak of the crosssections, from the Al to Ti sequences (there is no 2s shell contribution for the V to Fesequence) the error is reduced to 5–6% and 11%, respectively. This difference is maintained almost constantly for all the sequences as seen in Fig. 9. We also evaluated the impact in the calculation of the outer shell DI crosssections using the fitting procedure explained in Sect. 2.3 and the effects are negligible, being the maximum difference of 0.03%, 0.07%, and 0.06%, for an initial increase of 10%, 20%, and 50%, respectively. The main reason for this behaviour is because the 2s shell crosssections and their contribution to the single ionization is much lower than the outer shells. Therefore, a variation in the DI parameters of the 2s shell has no appreciable effects on the other shell crosssections.
We performed the same study for the 2p shell as explained above for the 2s shell. The results are slightly similar and the same conclusions are applicable in this case.
Fig. 9 Error propagation along Fe ions after applying a 10% and 20% increase in the 2s shell (orange and green circles) and the 2p shell (purple and blue triangles) DI parameters of Fe xv. 
Fig. 10 Total normalized crosssection for Sc x (orange line), DI crosssection (dashed blue line), 3s (pointed grey line), 2p (pointed purple line) and the calculations for the 3s shell of Younger (1982b; red dots). 
3.12.2. DI: 3s crosssections
Following the discussion in McGuire (1997), we scaleddown the experimental results for Mg I and Al II by multiplying by a factor of 0.8. For Si iii and S v the measurements of Djuric et al. (1993b) and Howald et al. (1986), respectively, were omitted because the measurements present clear evidence of metastable ions.
In the case of Ar vii, the measurements of Chung (1996) do not show evidence of 3s3p ^{3}P metastable ions unlike Djuric et al. (1993b), Howald et al. (1986) and Zhang et al. (2002). However, they only extend up to u = 6, where they seem to be in good agreement with Zhang et al. (2002), which contains data till 30 times the threshold. For this reason, we used the Chung (1996) measurement adding the Zhang et al. (2002) crosssections above u = 5.
Bernhardt et al. (2014) present recent measurements for Fe xv in the range 0–2600 eV. Bernhardt et al. use the TSR storagering technique, also applied to several measurements of Hahn et al., which allows them to reduce the fraction of metastable ions in the stored ion beam.
Figure 10 shows the total crosssection calculated as the sum of 3s shell data of Younger (1983) for Sc x with the rest of the innershell contributions. In this case, the main contributor to the total DI crosssection is the 3s shell followed by the 2p shell in a very low proportion. The EA contribution was added from Sampson (1982) after applying a scaling factor, as explained in the following section. As in the case of the Nalike sequence, the total crosssection compared to D07 is systematically 10–40% higher, probably for the same reason.
3.12.3. EA contribution
For the Mgsequence, we compared the EA contributions calculated with the method explained in Sect. 2.2 to other calculations available for Z = 13, 16–18 (Tayal & Henry 1986), and Z = 28 (Pindzola et al. 1991). We have compared Sampson’s crosssections Q_{SG} at about twice the EA onset towards these other calculations Q_{TP}, and have found the following relation for these elements. We assume the same relation for Z> 14 of the Mgsequence: (17)For Al ii and Si iii the scaling factor is smaller: 0.20. The observations for neutral Mg i (Freund et al. 1990; McCallion et al. 1992a) show no evidence for EA and therefore we neglected this process for neutral Mg. The available measurements (Chung 1996; Bernhardt et al. 2014) show EA enhancements that are consistent with the above scaling.
3.13. Al isoelectronic sequence
3.13.1. DI: 3s crosssections
For the Alsequence up to the Arsequence the 3s innershell contribution is interpolated from the theoretical calculations of Younger (1982a) for Ar, Sc, and Fe ions. For the Plike and Slike sequences, we included the data for Ni ions from Pindzola et al. (1991) because they correctly follow the trend of the rest of the elements in the same sequence, which is not the case for the other sequences.
EA scaling factors for the Al–Ar isoelectronic sequences needed to bring the Sampson data in accordance with the Pindzola data.
3.13.2. DI: 3p crosssections
For Fe xiv, the recent measurements of Hahn et al. (2013) using the TSR ion ring storage confirm the existence of a considerably lower crosssection than previous measurements (Gregory et al. 1987) or calculations (AR; D07). Hahn’s results agree with Gregory’s from threshold up to 700 eV, and after that they decrease until they show a difference of 40%. One of the reason for this difference could be the presence of the metastable ions in Gregory’s experiment. The major discrepancies with the theory could come from the fact that theory overestimates the EA component, specially the n = 2 → 4 transitions, in the case of D07.
3.13.3. EA contribution
For the Al to Arsequences, the EA calculations of Pindzola et al. (1991) for Ni ions can be used for comparison with the EA parameters derived from Sampson (1982). The scaling factors needed to bring the Sampson data in accordance with the Pindzola data are given in Table 1. These data show that the scaling factor gets smaller for higher sequences. This is no surprise since Sampson’s calculations were, in particular, designed for the Nasequence. We note that the relative importance of the EA process diminishes anyway for the higher sequences.
Lacking other information we assumed that, for all other ions of these isoelectronic sequences, the same scaling factors apply as for the Ni ions. Where there are measurements available with clear indications of the EA process, this scaling appeared to be justified. The possible exception is Ni xiii (Ssequence), where Pindzola et al. (1991) suggest that there is an additional contribution in the measurements of Wang et al. (1988) owing to resonant recombination followed by double autoionization. However, we decided to apply the same process as explained above for calculating the scaling factor of the Ssequence, only taking into consideration the Pindzola data.
3.14. Si isoelectronic sequence
3.14.1. DI: 3p crosssections
The experimental data available for Ar v (Crandall et al. 1979; Müller et al. 1980; Sataka et al. 1989) agree well below 200 eV but, above this energy, the Crandall et al. data are slightly higher. The three data sets are about 20% larger than expected based upon Younger’s calculations, probably due to some contamination by metastable levels in the beam. For this reason, theoretical calculations were obtained for Ar v, taking the A, B, C, and D parameters proposed by AR for Younger’s formula.The same situation occurs for Cr xi (Sataka et al. 1989) and the data were discarded.
The measurements of Hahn (Hahn et al. 2011b, 2012b) are used for Fe xiii. These data are 20% lower than the Arnaud & Raymond (1992) calculations and 15% lower above ~680 eV, compared with the FAC calculations of D07. The Hahn et al. experimental data show a faster increase of the crosssection in the onset compared with the calculations, probably owing to the excitation of the 3s shell electron, which the calculations did not include. The possible explanation for the higher EA contribution above the threshold proposed by Hahn is that the calculations overestimate the branching ratio of the autoionization and, additionally, the intermediate states could decay by double ionization rather than single ionization.
Fig. 11 Total normalized crosssection for Fe xi (orange line), DI crosssection (dashed blue line), 3p (dotted blue line), 3s (dotted grey line) and the measurements of Hahn et al. (2012c; red dots). 
3.15. P isoelectronic sequence
3.15.1. DI: 3p crosssections
The measurements of Freund et al. (1990) for P i are used for the 3p crosssection fitting with an error less than 6%. In the case of S ii, two data set are available, Yamada et al. (1988) and Djuric et al. (1993a), which agree within ±15%. Yamada’s measurements extent up to u = 12. However, the crosssection at the peak appears about ~40–50% larger than expected base on the general trend of the elements in this sequence. The measurements are probably affected by metastable ions in the beam. For this reason, we decided to use interpolation for this element. The measurements of Hahn et al. (2011a) are used for Fe xii instead of Gregory et al. (1983) because the latter data are compromised owing to metastable ions in the beam. Hahn’s data are about ~30% lower than the data of Gregory et al. (1983) and the calculations of Arnaud & Raymond (1992), and are in agreement with the theoretical crosssection of D07 within ±20%.
3.16. S isoelectronic sequence
3.16.1. DI: 3p crosssections
For Ar iii, we followed the discussion in Diserens et al. (1988) and did not include the data of Müller et al. (1980), Mueller et al. (1985), and Danjo et al. (1984), whose data are larger at high energies than the presently adopted data of Diserens et al. (1988) and Man et al. (1993). As explained by Diserens, the increased crosssections may indicate the presence of metastable ions in the beam.
The measurements of Hahn et al. (2012c) for Fe xi are about 35% lower than the Arnaud & Raymond (1992) theoretical calculations and are in reasonable good agreement with D07. The main differences are twofold. First, at 650 eV, a step appears in the crosssection owing to n = 2 → 3 excitations not included in D07; and secondly, for higher energies D07 considers the n = 2 → 4 and n = 2 → 5 EA transitions, resulting in a higher crosssection. However, the experiments do not show evidence for these last processes.
3.17. Cl isoelectronic sequence
3.17.1. DI: 3p crosssections
For K iii and Sc v, the theoretical calculations of Younger (1982c) for the 3p shell were used. For Ni xii, the measurements of CherkaniHassani et al. (2001) and the calculations of Pindzola et al. (1991) seem to be in good agreement, see Fig. 13.
Fig. 12 Total normalized crosssection for Ni xii (orange line), DI crosssection (dashed blue line), 3p (dotted blue line), 3s (dotted grey line) and the measurements of CherkaniHassani et al. (2001; red dots). 
The measurements of Hahn et al. (2012c) are used for Fe x. These are 35% lower than the Gregory et al. (1987) measurements. The theoretical calculations of Arnaud & Raymond (1992) and D07 lie within the experimental uncertainties, although some discrepancies can be found owing to the nonidentical EA processes modeling. The reason for these differences are the same as for Fe xi, explained in Sect. 3.16.1.
3.18. Ar isoelectronic sequence
3.18.1. DI: 3p crosssections
The theoretical data of Younger (1982d) for the 3p shell of Sc iv were taken into account, which are in good agreement with the D07 FAC calculations. Otherwise, for Fe ix recent measurements of Hahn et al. (2016) are available. In this case, the storage ring could not eliminate all the metastable ions from the beam. However, Hahn et al. are able to estimate a metastable fraction of 30% in the 3p^{5}3d level and they obtain a new estimated ground state crosssection (subtracting the metastable states from the experimental data), which is 15–40% lower than the AR and D07 calculations, and 20% lower than the total crosssection derived from the Younger (1982d) data for the 3p shell. Owing to those lower values of the total crosssection, the rest of the elements interpolated or extrapolated based on Fe ix will be affected as well by a systematic decrease of their total crosssection.
3.19. K isoelectronic sequence
The Klike (3s^{2}3p^{6}4s) ions have the 3p and 3d shells as the main contributors to the DI and the EA process is dominated by excitation from 3p^{6}3d to the 3p^{5}3dnl levels with n = 4,5. The DI contribution of 4s is taken into account for the elements that have some electrons in the 4s shell, such as K i and Ca ii with a structure of 3s^{2}3p^{6}4s. The same process has been followed for the ions up to the Znlike sequence that have the 4s shell contribution.
3.19.1. DI: 3s and 3p crosssections
For the calculation of the 3s and 3p shells DI crosssection contribution, we have followed the same procedure as for the 2s and 2p shells, explained in Sect. 3.12.1. We calculated the A, B, D, and E parameters with Eq. (9) using, as reference, the parameters of the previous isoelectronic sequence. The same process was applied for all elements from the Ksequence up to the Znsequence.
3.19.2. DI: 3d and 4s crosssections
For K i and Ni x we used the theoretical data of McCarthy & Stelbovics (1983) and Pindzola et al. (1991), respectively, which are well fitted. For Fe viii, the recent measurements of Hahn et al. (2015) were used, from the ionization threshold up to 1200 eV. They remain 30–40% lower than theoretical calculations of Arnaud & Raymond (1992), based on Pindzola et al. (1987), and are in good agreement (10%) with D07. The reason for these discrepancies are similar to the case of Fe xi, as explained in Sect. 3.16.1.
3.19.3. EA contribution
We adopted the EA parameters calculated by D07 from his FAC EA calculations, which are the same as used by CHIANTI for all the sequences from the Klike up to the Crlike sequences.
3.20. Ca isoelectronic sequence
3.20.1. DI: 3d and 4s crosssections
For Ca i we selected three data sets (McGuire 1977, 1997; Roy & Kai 1983) of theoretical calculations. The first two sets of McGuire are in reasonably good agreement, although they are ~30% higher than Roy’s. There are no apparent reasons for discarding any of the three sets and therefore we decided to include all of them. For Fe vii we use the sets of Gregory et al. (1986) and Stenke et al. (1999) and for Ni ix the calculations of Pindzola et al. (1991) and Wang et al. (1988).
3.21. Sc isoelectronic sequence
3.21.1. DI: 3d and 4s crosssections
We include measurements of Ti ii, Fe vi, and Ni viii to obtain the DI and EA crosssections of the scandium (3p^{6}3d^{3}) sequence. The rest of the elements are interpolated or extrapolated. For Fe vi, the measurements of Gregory et al. (1987) and Stenke et al. (1999) are in good agreement with our fit. The data sets of Wang et al. (1988) and Pindzola et al. (1991) were used for Ni viii.
3.22. Ti isoelectronic sequence
3.22.1. DI: 3d and 4s crosssections
For the titanium sequence (3p^{6}3d^{4}) the measurements of Stenke et al. (1999) for the Fe v, as can be seen in Fig. 13, and Ni vii 3d shell, respectively, were selected. In the case of Ti i, with an irregular structure of 3d^{2}4s^{2}, the McGuire (1977) theoretical calculations are used to obtain the 4s shell contribution.
Fig. 13 Total normalized crosssection for Fe v (orange line), DI crosssection (dashed blue line), 3d (dotted blue line), 3p (dotted blue line) and the measurements of Stenke et al. (1999; red dots). 
3.23. V isoelectronic sequence
3.23.1. DI: 3d and 4s crosssections
The measurements used for the Vlike sequence are Tawara (2002) for V i (obtained directly from CHIANTI), Man et al. (1987b) for Cr ii, Stenke et al. (1999) for Fe iv and Wang et al. (1988) for Ni vi, which are well fitted. The remaining elements are interpolated or extrapolated.
3.24. Cr isoelectronic sequence
3.24.1. DI: 3d and 4s crosssections
For Cr i there are no measurements available and we use the calculations of Reid et al. (1992) and McGuire (1977) for high energies. The measurements of Bannister & Guo (1993) and calculations of Pindzola et al. (1991) are in good agreement for Ni v.
3.25. Mn isoelectronic sequence
3.25.1. DI: 3d and 4s crosssections
For the manganese sequence (3p^{6}3d^{7}) elements 3d shell DI crosssection, we use the theoretical calculation of Younger (1983) for Fe ii and the measurements of Gregory et al. (1986) for Ni iv. Since the Fe ii element has a ground state configuration of 3d^{6}4s, we considered the measurements of the total DI crosssection of Montague et al. (1984a) for subtracting the contribution of the rest of the innershells and for obtaining the 4s shell DI crosssections. Mn i was fitted with data of Tawara (2002) taken from CHIANTI (D07). The remaining elements of the sequence are interpolated.
3.26. Fe isoelectronic sequence
3.26.1. DI: 3d and 4s crosssections
For Fe i, we included the measurements of Freund et al. (1990) and the FAC DI calculations of D07 for Co ii. We use the Pindzola et al. (1991) theoretical calculations for Ni iii, which are in good agreement with Stenke et al. (1999) at high energies; and Gregory et al. (1986) for Cu iv. The rest of the elements of the sequence are interpolated.
3.27. Co isoelectronic sequence
3.27.1. DI: 3d and 4s crosssections
The measurements found for the cobalt sequence are Montague et al. (1984a) for Ni ii and Gregory et al. (1986) for Cu iii, which are well fitted. Co i was fitted with data of Tawara (2002) taken from CHIANTI (D07) and Zn iv with the extrapolation of Ni ii and Cu iii.
3.28. Ni isoelectronic sequence
3.28.1. DI: 3d and 4s crosssections
For Ni i (with ground configuration 3d^{8}4s^{2}) the Pindzola et al. (1991) and McGuire (1977) data were selected for the 3d and 4s DI contribution, respectively. For Cu ii and Zn iii, there are no known measurements, therefore, the 3d DI crosssections were calculated as the extrapolation of Pindzola’s data for Ni i.
3.29. Cu isoelectronic sequence
3.29.1. DI: 3d and 4s crosssections
The measurements considered for the 4s shell DI fit of the copper sequence (3d^{10}4s) are for Cu i, Bolorizadeh et al. (1994) and Bartlett & Stelbovics (2002); and for Zn ii, Peart et al. (1991a) and Rogers et al. (1982). The fit is in a reasonably good agreement with the measurements. The 3d shell DI contribution of both elements were calculated with FAC.
3.30. Zn isoelectronic sequence
3.30.1. DI: 3d and 4s crosssections
For the Zn i ion, which has a 3d^{10}4s^{2} ground configuration, the calculations of Omidvar & Rule (1977) were used for the fit of the 4s DI crosssection contribution instead of McGuire (1977), because they are around 5–10% higher than Omidvar’s values before the crosssection peak and more than 20% lower after, which disagrees with the contribution of the innershells. Otherwise, FAC was used forthe 3d DI crosssection calculation.
4. Ionization rate coefficients
In the previous section, we obtained the ionization crosssections for all subshells of all elements from H to Zn isoelectronic sequence by applying Eq. (2) for DI and Eq. (12) for EA. The total crosssection for DI can be written as the sum of j innershells, where u_{j} = E_{e}/I_{j} with E_{e} the incoming electron energy (in keV) and I_{j} the ionization potential of the atomic subshell (in keV): (18)The parameters A_{j}, B_{j}, C_{j}, D_{j}, and E_{j} (in units of 10^{24} m^{2} keV^{2}) for Silike Fe xi are given in Table E.1.
The direct ionization rate is written as a function of the temperature kT as (19)where n_{e} and n_{i} are the electron and ion density, respectively, m_{e} the electron mass, and C_{i} and g_{i}(u_{j}) are given in Appendix B. The same approach can be taken with the EA process. The EA crosssection contribution to the outer shell of each ion, is the sum of k energy level transitions with I_{EAk} the excitationautoionization threshold (in keV): (20)where A_{EAk}, B_{EAk}, C_{EAk}, D_{EAk}, and E_{EAk} (in units of 10^{24} m^{2} keV^{2}) are the parameters obtained for each ion in presence of the EA process.
Moreover, the total excitationautoionization rate coefficient is expressed as (21)A detailed description of the D_{i} and m_{i}(u_{k}) terms of this parametric formula is shown in Appendix C.
The total ionization rate coefficient is given by the sum of Eqs. (19) and (21) and includes the contributions from all innershells.
Fig. 14 Left axis: ionization rates comparison between Bryans et al. (2009; dashed lines) and the present work (solid lines) for Cl vii (Nalike), Cl vi (Mglike, rate multiplied by factor 10) and Cl v (Allike, rate multiplied by factor 50). 
Fig. 15 Ionization rates comparison between Bryans et al. (2009; dashed lines) and the present work (solid lines) for Fe xvi (Nalike), Fe xv (Mglike, rate multiplied by factor 10), and Fe xiv (Allike, rate multiplied by factor 100). 
5. Discussion
A systematic comparison was made with the Bryans et al. (2009) atomic data, which adopt the D07 electronimpact ionization rates. This shows that the present work and Bryans et al. (2009) rates are in good agreement (differences less than 10–20%) for more than 85% of the elements. The highest differences appear for the isoelectronic sequences of Na, Mg (Si iii, P iv, S v and Cl vi), and Al (P iii, S iv, Cl v and Ar vi), where some of the ions show a difference of 30–40% in the crosssections compared with D07. As a consequence, the ionization rates for these ions are up to 2–3 times higher than D07 for high temperatures. An example for Cl is shown in Fig. 14. This difference decreases for high Z elements as can be seen in Fig. 15 where the ionization rates for Fe are represented.
A possible explanation could be that the D07 crosssections are mainly calculated with FAC, instead of fitted to experimental data, as performed in the present work (see Appendix A). The measurements represent a more realistic scenario and include more transitions, since REDA or multiple ionization are not usually incorporated in the theoretical calculations.
Fig. 16 Fe xiv total crosssection. The experimental results of Hahn et al. are shown by the green dots. The theoretical calculations of D07 are given by the blue line and the results of this work derived from the fitting process described in Sect. 3.13 by the red line. 
As explained in the previous sections, the most recent experimental measurements included in this work are Fe xviii, Fe xvii, and Fe xiv (Hahn et al. 2013), Fe xiii (Hahn et al. 2012b), Fe xii (Hahn et al. 2011a), Fe xi and Fe x (Hahn et al. 2012c), Fe ix (Hahn et al. 2016) and Fe viii (Hahn et al. 2015), and Bernhardt et al. (2014) for Fe xv. They used the new TSR technique to reduce the metastable ion levels to obtain lower crosssections than AR for all the ions. D07’s crosssections are about 20% higher than Hahn’s for Fe xiv, Fe xiii, Fe xii, Fe xi, Fe x, Fe ix, and Fe viii. For the other ions, the crosssections are comparable, with the difference that the D07 EA threshold is located at higher energy, probably because D07 does not include the n = 2 → 3 excitations, see Fig. 16.
Figure 17 contains the ionization comparison rates for some ions: Fe xviii, Fe xvii, Fe xiv, Fe xii, and Fe ix. The plot shows that the ionization rates are similar or lower than D07, as expected from the experimental measurements. For Fe xi to Fe xv we obtain a higher value than D07 for low temperature. The reason for this is probably that, at low temperature, the rates are very sensitive to the weighting of the crosssection with the Maxwellians velocity and a small variance in the crosssection fit at low energies could have a major impact in this region.
Fig. 17 Ionization rates comparison between Bryans et al. (2009; dashed lines) and the present work (solid lines). 
The major impact of the new crosssections used in this work is on the ion fractions obtained by the ionization balance. As an example, we compared the ion fractions from Bryans et al. (2009) with the present work for all ions of Fe. In this comparison, we used the same recombination rates as Bryans et al. (2009), so the only differences are the ionization rates.
Figure 18 (top) shows the first ten ions from Fe xxvi to Fe xvii. The ion fraction is relatively similar for all ions, except for Nelike Fe xvii. The lower temperature ionic fraction in this work is clearly higher than using Bryans et al. (2009). This is mainly influenced by ions of adjacent isoelectronic sequences such as Nalike or Mglike, which have higher ionization rates, as explained above.
Fig. 18 Top: ion fraction for Hlike to Nelike Fe including the ionization rates of Bryans et al. (2009; dashed lines) and present work (solid lines). Middle: ion fraction for Nalike to Arlike. Bottom: ion fraction for Klike to Felike. 
Figure 18 (middle) presents the ion fraction for Fe ix up to Fe xvi. In this case, there is a more appreciable difference. The peak ion concentration in the present work is lower than in Bryans et al. and it seems to be slightly displaced to lower temperatures. However, for Fe xvi the ion concentration behaviour is similar to Fe xvii. The least ionized Fe (Fe viii up to Fe i) ion fractions are plotted in Fig. 18 (bottom). From Fe viii to Fe vi, the values at the peak of the ion fractions are similar but they are displaced at lower temperatures around ~10^{4}–10^{5} K. For Fe iii, the value at the peak is ~20% lower. The Fe i and Fe ii ions are in good agreement.
6. Summary and conclusions
We produced a complete set of electron direct collisional ionization crosssections together with excitationautoionization crosssections. We were able to obtain not only the total crosssections, such as D07, but all the individual inner shells crosssection of all elements from the H to Zn isoelectronic sequences. They were obtained from experimental measurements, theoretical calculations, and interpolation/extrapolation among the data sets. We incorporated the most recent experimental measurements available at the moment, taken by Fogle et al. (2008), Hahn et al. (2011a,b, 2012a,b,c, 2013, 2015, 2016), and Bernhardt et al. (2014).
This method enables a much more efficient analytical calculation of ionization rate coefficients than other plasma codes with a comparable accuracy. The corresponding rates are in good agreement with Bryans et al. (2009) in at least 85% of the cases. This capability is essential to resolve emission lines and line fluxes in a highresolution Xray spectra.
The results of the present work are included in the SPEX^{2} (Kaastra et al. 1996) software, utilized for Xray spectra modeling, fitting, and analysis.
Acknowledgments
SRON is supported financially by NWO, the Netherlands Organization for Scientific Research. We thank J. Mao, L. Gu, T. Raassen and J. de Plaa for their support in the different stages of this project.
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Appendix A: References for used crosssection data
List of references for used crosssection data.
Appendix B: Calculation of DI ionization rate coefficients
As explained in Sect. 2, for the direct ionization crosssection calculation, the extended Younger’s Eq. (2) was used: (B.1)where with E the kinetic energy of the colliding electron and I the ionization potential of the relevant subshell.
If we generalize the formula for all the inner shells j and the summation over all shells is taken into account for the total direct ionization crosssection, the parametric formula is (B.2)Eq. (B.1) can be written as follows being u_{j} = E/I_{j}: (B.3)with As a consequence, the direct ionization rate coefficients versus the temperature [T] are: (B.4)with y ≡ I/kT and (B.5)with being E_{1} the first exponential integral function. For small y (y< 0.6): (B.13)where γ = 0.577216 is the EulerMascheroni constant. For intermediate y(0.6 ≤ y ≥ 20): (B.14)with, For large y (y> 20): (B.15)(B.16)For small y (y< 0.5): (B.17)For intermediate y(0.5 ≤ y ≥ 20): (B.18)with, For large y (y> 20): (B.19)with,
Appendix C: Calculation of EA ionization rate coefficients
The excitationautoionization rate coefficients were calculated applying the integral to a Maxwellian velocity distribution of Mewe’s equation, mentioned in Sect. 2.2: (C.1)The EA crosssection contribution that affects the outer shell of each element, is the summation over k energy level transitions with I_{EAk} the excitationautoionization potential being u_{k} = E/I_{EAk}: (C.2)
with, Therefore, the EA ionization rate coefficients versus the temperature [T] are (C.3)with y ≡ I_{EA}/kT and (C.4)with:
Appendix D: The DI coefficients
Table D.1 shows an example of the DI coefficients calculated by Eq. (2) for Silike Fe xi.
The DI coefficients.
Appendix E: The EA coefficients
Table E.1 shows an example of the DI coefficients calculated by Eq. (12) for Silike Fe xi.
The EA coefficients.
All Tables
EA scaling factors for the Al–Ar isoelectronic sequences needed to bring the Sampson data in accordance with the Pindzola data.
All Figures
Fig. 1 Approximation to the Bethe crosssection. 

In the text 
Fig. 2 Total DI normalized crosssection for Fe xxvi (dashed blue line) and the measurements of Kao et al. (1992; red dots) and Moores & Pindzola (1990; green triangles). Note the presence of relativistic effects for high energies. 

In the text 
Fig. 3 Total DI normalized crosssection for Li ii (dashed blue line) and the measurements of Peart & Dolder (1968; red dots) and Peart et al. (1969; green triangles) with their respective experimental error. 

In the text 
Fig. 4 Total DI (dashed blue line) and DI plus EA (orange line) normalized crosssection for B iii, where the DI contribution of the 1s shell is shown as the dotted cyan line and the 2s shell in magenta. The measurements of Crandall et al. (1986; red dots) with the experimental uncertainties are also included. 

In the text 
Fig. 5 Total DI crosssection for the 1s subshell for all elements of the oxygen sequence using interpolation with Eq. (11). 

In the text 
Fig. 6 Total DI normalized crosssection for Ne ii (dashed blue line) and the measurements of Yamada et al. (1989a; red dots) with the experimental uncertainties. 

In the text 
Fig. 7 The DI normalized crosssection for Ne ii (dashed blue line) and the measurements of Achenbach et al. (1984; red dots), Diserens et al. (1984; green triangle), Donets & Ovsyannikov (1981; blue square) and Man et al. (1987a; cyan square) with their respective experimental uncertainties. 

In the text 
Fig. 8 Total DI normalized crosssection for Fe xvii (dashed blue line) and the measurements of Hahn et al. (2013) (red dots), and calculations of Zhang & Sampson (1990; green triangles). 

In the text 
Fig. 9 Error propagation along Fe ions after applying a 10% and 20% increase in the 2s shell (orange and green circles) and the 2p shell (purple and blue triangles) DI parameters of Fe xv. 

In the text 
Fig. 10 Total normalized crosssection for Sc x (orange line), DI crosssection (dashed blue line), 3s (pointed grey line), 2p (pointed purple line) and the calculations for the 3s shell of Younger (1982b; red dots). 

In the text 
Fig. 11 Total normalized crosssection for Fe xi (orange line), DI crosssection (dashed blue line), 3p (dotted blue line), 3s (dotted grey line) and the measurements of Hahn et al. (2012c; red dots). 

In the text 
Fig. 12 Total normalized crosssection for Ni xii (orange line), DI crosssection (dashed blue line), 3p (dotted blue line), 3s (dotted grey line) and the measurements of CherkaniHassani et al. (2001; red dots). 

In the text 
Fig. 13 Total normalized crosssection for Fe v (orange line), DI crosssection (dashed blue line), 3d (dotted blue line), 3p (dotted blue line) and the measurements of Stenke et al. (1999; red dots). 

In the text 
Fig. 14 Left axis: ionization rates comparison between Bryans et al. (2009; dashed lines) and the present work (solid lines) for Cl vii (Nalike), Cl vi (Mglike, rate multiplied by factor 10) and Cl v (Allike, rate multiplied by factor 50). 

In the text 
Fig. 15 Ionization rates comparison between Bryans et al. (2009; dashed lines) and the present work (solid lines) for Fe xvi (Nalike), Fe xv (Mglike, rate multiplied by factor 10), and Fe xiv (Allike, rate multiplied by factor 100). 

In the text 
Fig. 16 Fe xiv total crosssection. The experimental results of Hahn et al. are shown by the green dots. The theoretical calculations of D07 are given by the blue line and the results of this work derived from the fitting process described in Sect. 3.13 by the red line. 

In the text 
Fig. 17 Ionization rates comparison between Bryans et al. (2009; dashed lines) and the present work (solid lines). 

In the text 
Fig. 18 Top: ion fraction for Hlike to Nelike Fe including the ionization rates of Bryans et al. (2009; dashed lines) and present work (solid lines). Middle: ion fraction for Nalike to Arlike. Bottom: ion fraction for Klike to Felike. 

In the text 
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