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Table A.23
Thermodynamic properties of equilibrium H2.
| T | Q int | Eint/RT | H−H(0) | S | C p | C v | −[G−H(0)] /T | γ |
| [K] | [J] | [J mol-1] | [J K-1 mol-1] | [J K-1 mol-1] | [J K-1 mol-1] | [J K-1 mol-1] | ||
|
|
||||||||
| 5.0 | 0.25 | 0.0 | 103.931 | 21.095 | 20.786 | 0.0 | −40.026 | 1.667 |
| 10.0 | 0.25 | 0.0 | 207.862 | 35.503 | 20.787 | 0.001 | 64.026 | 1.667 |
| 15.0 | 0.25 | 0.001 | 311.94 | 43.942 | 20.898 | 0.112 | 222.473 | 1.666 |
| 20.0 | 0.25 | 0.015 | 418.257 | 50.053 | 21.864 | 1.078 | 416.507 | 1.66 |
| 25.0 | 0.252 | 0.066 | 533.473 | 55.184 | 24.518 | 3.732 | 638.256 | 1.638 |
| 30.0 | 0.258 | 0.169 | 665.765 | 59.996 | 28.537 | 7.751 | 884.693 | 1.599 |
| 35.0 | 0.267 | 0.315 | 819.085 | 64.715 | 32.706 | 11.92 | 1154.933 | 1.551 |
| 40.0 | 0.282 | 0.48 | 991.15 | 69.305 | 35.893 | 15.107 | 1448.489 | 1.505 |
| 45.0 | 0.301 | 0.642 | 1175.533 | 73.647 | 37.61 | 16.824 | 1764.426 | 1.467 |
| 50.0 | 0.324 | 0.783 | 1364.975 | 77.638 | 37.97 | 17.184 | 2101.227 | 1.438 |
| 60.0 | 0.382 | 0.984 | 1737.824 | 84.441 | 36.242 | 15.456 | 2829.782 | 1.403 |
| 70.0 | 0.448 | 1.085 | 2086.766 | 89.826 | 33.537 | 12.75 | 3619.013 | 1.387 |
| 80.0 | 0.519 | 1.123 | 2409.737 | 94.142 | 31.153 | 10.367 | 4456.451 | 1.381 |
| 90.0 | 0.593 | 1.124 | 2711.881 | 97.703 | 29.377 | 8.591 | 5333.052 | 1.381 |
| 100.0 | 0.667 | 1.107 | 2999.115 | 100.73 | 28.151 | 7.365 | 6242.444 | 1.384 |
| 110.0 | 0.74 | 1.082 | 3276.322 | 103.373 | 27.351 | 6.565 | 7180.087 | 1.387 |
| 120.0 | 0.813 | 1.055 | 3547.19 | 105.73 | 26.867 | 6.081 | 8142.661 | 1.391 |
| 130.0 | 0.883 | 1.029 | 3814.429 | 107.869 | 26.613 | 5.827 | 9127.671 | 1.395 |
| 140.0 | 0.952 | 1.005 | 4080.006 | 109.837 | 26.526 | 5.739 | 10 133.185 | 1.399 |
| 150.0 | 1.02 | 0.984 | 4345.331 | 111.668 | 26.556 | 5.77 | 11 157.669 | 1.403 |
| 200.0 | 1.341 | 0.923 | 5692.821 | 119.414 | 27.448 | 6.662 | 16 527.172 | 1.413 |
| 150.0 | 1.02 | 0.984 | 4345.331 | 111.668 | 26.556 | 5.77 | 11 157.669 | 1.403 |
| 298.15 | 1.931 | 0.916 | 8467.176 | 130.682 | 28.836 | 8.05 | 28 016.705 | 1.414 |
| 300.0 | 1.942 | 0.916 | 8520.534 | 130.86 | 28.849 | 8.063 | 28 243.25 | 1.414 |
| 350.0 | 2.238 | 0.926 | 9969.563 | 135.327 | 29.081 | 8.294 | 34 484.941 | 1.412 |
| 400.0 | 2.534 | 0.936 | 11 426.436 | 139.218 | 29.181 | 8.395 | 40 934.958 | 1.411 |
| 450.0 | 2.831 | 0.944 | 12 886.795 | 142.658 | 29.229 | 8.442 | 47 567.798 | 1.409 |
| 500.0 | 3.128 | 0.952 | 14 349.02 | 145.739 | 29.259 | 8.473 | 54 363.344 | 1.408 |
| 600.0 | 3.725 | 0.963 | 17 278.057 | 151.079 | 29.326 | 8.54 | 68 380.83 | 1.406 |
| 700.0 | 4.324 | 0.973 | 20 215.836 | 155.608 | 29.44 | 8.654 | 82 889.4 | 1.404 |
| 800.0 | 4.928 | 0.983 | 23 168.335 | 159.55 | 29.623 | 8.837 | 97 820.014 | 1.403 |
| 900.0 | 5.536 | 0.994 | 26 142.864 | 163.053 | 29.88 | 9.094 | 113 121.903 | 1.401 |
| 1000.0 | 6.151 | 1.006 | 29 146.545 | 166.217 | 30.204 | 9.418 | 128 756.479 | 1.399 |
| 1100.0 | 6.774 | 1.019 | 32 185.337 | 169.113 | 30.579 | 9.793 | 144 693.583 | 1.397 |
| 1200.0 | 7.406 | 1.034 | 35 263.602 | 171.792 | 30.991 | 10.204 | 160 909.037 | 1.395 |
| 1300.0 | 8.051 | 1.051 | 38 384.094 | 174.289 | 31.421 | 10.635 | 177 383.01 | 1.392 |
| 1400.0 | 8.709 | 1.069 | 41 548.164 | 176.634 | 31.86 | 11.074 | 194 098.888 | 1.389 |
| 1500.0 | 9.382 | 1.089 | 44 756.054 | 178.847 | 32.297 | 11.511 | 211 042.494 | 1.386 |
| 2000.0 | 13.015 | 1.193 | 61 416.861 | 188.419 | 34.278 | 13.492 | 298 792.538 | 1.371 |
| 2500.0 | 17.181 | 1.299 | 78 962.143 | 196.243 | 35.838 | 15.052 | 390 859.016 | 1.357 |
| 3000.0 | 21.964 | 1.397 | 97 201.242 | 202.89 | 37.077 | 16.291 | 486 526.148 | 1.345 |
| 3500.0 | 27.428 | 1.486 | 116 007.0 | 208.686 | 38.121 | 17.335 | 585 293.496 | 1.335 |
| 4000.0 | 33.632 | 1.568 | 135 302.809 | 213.838 | 39.043 | 18.257 | 686 790.762 | 1.326 |
| 4500.0 | 40.634 | 1.644 | 155 031.8 | 218.484 | 39.852 | 19.066 | 790 732.925 | 1.318 |
| 5000.0 | 48.492 | 1.713 | 175 128.639 | 222.719 | 40.508 | 19.721 | 896 892.151 | 1.311 |
| 6000.0 | 66.988 | 1.831 | 216 042.905 | 230.176 | 41.156 | 20.37 | 1.115128382e6 | 1.3 |
| 7000.0 | 89.448 | 1.917 | 257 096.393 | 236.506 | 40.779 | 19.993 | 1.340240895e6 | 1.293 |
| 8000.0 | 115.989 | 1.97 | 297 322.673 | 241.879 | 39.553 | 18.767 | 1.571192049e6 | 1.288 |
| 9000.0 | 146.498 | 1.991 | 336 046.785 | 246.442 | 37.836 | 17.049 | 1.807099542e6 | 1.286 |
| 10 000.0 | 180.675 | 1.986 | 372 961.362 | 250.333 | 35.979 | 15.193 | 2.047222929e6 | 1.287 |
| 11 000.0 | 218.099 | 1.962 | 408 052.021 | 253.679 | 34.211 | 13.425 | 2.29095485e6 | 1.289 |
| 12 000.0 | 258.301 | 1.925 | 441 490.549 | 256.589 | 32.676 | 11.89 | 2.537806546e6 | 1.292 |
| 13 000.0 | 300.818 | 1.881 | 473 549.464 | 259.156 | 31.484 | 10.698 | 2.787389971e6 | 1.296 |
| 14 000.0 | 345.231 | 1.834 | 504 545.723 | 261.453 | 30.59 | 9.804 | 3.039399948e6 | 1.3 |
| 15 000.0 | 391.19 | 1.788 | 534 806.189 | 263.541 | 29.996 | 9.21 | 3.293598228e6 | 1.304 |
| 16 000.0 | 438.423 | 1.744 | 564 646.464 | 265.467 | 29.722 | 8.936 | 3.549799968e6 | 1.308 |
| 17 000.0 | 486.741 | 1.705 | 594 357.51 | 267.269 | 29.744 | 8.958 | 3.80786255e6 | 1.312 |
| 18 000.0 | 536.03 | 1.671 | 624 196.974 | 268.974 | 29.964 | 9.178 | 4.067676383e6 | 1.315 |
| 19 000.0 | 586.244 | 1.642 | 654 383.656 | 270.606 | 30.448 | 9.662 | 4.329157371e6 | 1.318 |
| 20 000.0 | 637.389 | 1.62 | 685 094.498 | 272.181 | 39.3 | 18.514 | 4.59224074e6 | 1.321 |
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