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Table 6

Contributions of the different surface reaction routes to OH and H2O formation after a coverage of 1 ML is reached, and the total produced water rate for dense clouds I and II for different values of kH2 + O.

Cloud H2 + O H + O H + HO2 H + O3 H + H2O2 H + OH H2 + OH H2O prod.
OH + H OH OH + OH OH + O2 OH + O H2O H2O + H
k H2 + O (s-1) (%) (%) (%) (%) (%) (%) (%) (ML kyr-1)

I k exo.tunn. a = 2.3 × 105 95.0 4.5 ~0 ~0 ~0 ~100 ~0 0.19
I k exp.max. b = 3.0 × 10-2 11.0 74.0 12.0 0.5 2.5 86.5 9.0 0.15
I k endo.tunn c = 4.4 × 10-29 0 82.0 14.0 1.0 3.0 75.5 19.5 0.14
II k exo.tunn. a = 2.3 × 105 98.5 1.5 ~0 0 ~0 99.0 1.0 0.54
II k exp.max. b = 3.5 × 10-9 1.0 56.0 31.0 6.0 6.0 26.0 60.0 0.24
II k endo.tunn c = 5.0 × 10-36 0 54.0 35.0 5.5 5.5 20.5 63.5 0.24

Notes.

(a)

Equation (2), with Ea equal to Ea + ΔE from Fig. 1, i.e. 3000 K.

(b)

Equation (7).

(c)

Equation (4), with Ea = 2040 K and ΔE = 960 K.

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