Solid-state formation of CO₂ via the H₂CO + O reaction^⋆

¹ Université de Cergy Pontoise, UMR 8112, LERMA, 95000 Cergy Pontoise Cedex, France
² LERMA, Observatoire de Paris, PSL Research University, CNRS, UMR 8112, 75014 Paris, France
e-mail: marco.minissale@obspm.fr
³ Sorbonne Universités, UPMC Univ. Paris 6, UMR 8112, LERMA, 75005 Paris, France
⁴ ISM – Université de Bordeaux – CNRS, UMR 5255, 351 cours de la Libération, 33405 Talence Cedex, France

Received: 5 June 2014
Accepted: 15 December 2014

Abstract

Context. The formation of carbon dioxide ice in quiescent regions of molecular clouds has not yet been fully understood, even though CO₂ is one the most abundant species in interstellar ices.

Aims. CO₂ formation was studied via oxidation of formaldehyde molecules on cold surfaces under conditions close to those encountered in quiescent molecular clouds to evaluate the efficiency and the activation barrier of the H₂CO + O reaction.

Methods. Formaldehyde ices were exposed to O atoms using a differentially pumped beam line. The H₂CO + O reaction experiments were carried out on two different surfaces of astrophysical interest (amorphous water ice and oxidised graphite) held at 10 or 55 K. The products were probed via infrared and mass spectroscopy by using RAIRS and temperature-programmed desorption techniques.

Results. In this paper we show that the H₂CO + O reaction can efficiently form carbon dioxide in the solid phase. The activation barrier for the reaction, based on a model fit to the experimental data, was estimated to be 335 ± 55 K.

Conclusions. The H₂CO+O reaction on cold surfaces can be added to the set of pathways that lead to carbon dioxide in the interstellar ices. Astrophysically, the abundance of CO₂ in quiescent molecular clouds may potentially be explained by three reactions occurring on cosmic grains: CO + OH,CO + O, and H₂CO + O.