Fig. 1

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Gas-grain astrochemical model results for the calculated abundances (relative to H2) of the most important species involved in the formation of aromatic molecules in dark clouds, shown as a function of cloud age. The horizontal gray region represent the observed abundances in TMC-1, with an arbitrary uncertainty of plus or minus a factor of 2: CH (Suutarinen et al. 2011), C2H (Sakai et al. 2010; Turner et al. 2000), c-C3H2 (Park et al. 2006; Turner et al. 2000), l-C3H3+ (Silva et al. 2023), CH3CCH (Askne et al. 1983; Irvine et al. 1981; Markwick et al. 2002; Turner et al. 1999), C3H6 (Marcelino et al. 2007), and c-C5H6 (Cernicharo et al. 2021a). The vertical gray region indicates the chemical age obtained by minimizing the distance of disagreement (Wakelam et al. 2006), which in this study involves the differences between the observed and modeled abundances of 62 species in TMC-1.
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