Fig. 6

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TPD curves of two mixed-ice experiments, H2O:H2S = 9.3:1 (top) and H2O:13CO2 = 14:1 (bottom). The desorption data of H2O, H2S, and 13CO2 are shown in gray (m/z = 18, [H2O]+), red (m/z = 34, [H2S]+), and blue (m/z = 45, [13CO2]+), respectively. Two desorption regimes are seen for H2S: a submonolayer H2S-H2O desorption feature and a molecular volcano desorption peak. For 13CO2, a third regime is observed between its submonolayer and volcano peaks, indicating constant sublimation within that temperature range.
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