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Fig. 3

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Details of the MPI peaks from benzonitrile with nearest-integer m/z values of 26, 77, and 88. The experimental data points are shown in blue and the Gaussian fits in green. (a) The fitted center (m/z 26.012 ± 0.005) indicates that C2H2•+ (26.016) dominates over any CN••+ (26.003). (b) The fitted center (m/z 77.040 ± 0.005) indicates that C6H5+ (77.039) dominates over any C5H3N•+ (77.027). (c) The fitted center (m/z 88.015 ± 0.005) indicates that C6H2N+ (88.019) dominates over any C7H4•+ (88.031).

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