Table 1
Spectroscopic parameters of oxygen protonated carbonyl sulphide HOCS+.
Parameter | Unit | This work | Nakanaga & Amano (1987)(a) | Ohshima & Endo(1996)(b) | ab initio(c) |
---|---|---|---|---|---|
A | GHz | 779.1(41) | 782.6957(38) | 779.260 | |
B | MHz | 5750.3771(30) | 5750.551(49) | 5726.66011(10) | 5749.14 |
C | MHz | 5702.9444(32) | 5703.030(50) | 5702.15 | |
DJ | kHz | 1.04165(45) | 1.104(20) | 1.0640(80) | 1.01 |
DJK | kHz | 261.19(13) | 281.9(15) | 270. | |
DK | MHz | 993.68(d) | 993.68(77) | 649.01 | |
d1 | kHz | −0.01037(99) | −0.0198(43) | −0.00706 | |
d2 | kHz | −0.000833(e) | −0.000833 | ||
# lines | 30 | ||||
σrms | kHz | 46 | |||
σw(f) | 0.63 |
Notes. Values in parentheses represent 1σ uncertainties, expressed in units of the last quoted digit. (a)Parameters converted from Watson A-reduction Hamiltonian to S-reduction (see text). (b)Values reported in Ohshima & Endo (1996) are actually Beff = (B + C)/2 and Deff = DJ + (B − C)2/{32[A − (B + C)/2]}. (c)Alessandrini et al. (2018).(d) Fixed to the value derived in Nakanaga & Amano (1987).(e) Fixed to the ab initio value. (f)Dimensionless rms, defined as , where the δs are the residuals weighted by the experimental uncertainty (err) and N the total number of transitions analysed.
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