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Table 1

Spectroscopic parameters of oxygen protonated carbonyl sulphide HOCS+.

Parameter Unit This work Nakanaga & Amano (1987)(a) Ohshima & Endo(1996)(b) ab initio(c)
A GHz 779.1(41) 782.6957(38) 779.260
B MHz 5750.3771(30) 5750.551(49) 5726.66011(10) 5749.14
C MHz 5702.9444(32) 5703.030(50) 5702.15
DJ kHz 1.04165(45) 1.104(20) 1.0640(80) 1.01
DJK kHz 261.19(13) 281.9(15) 270.
DK MHz 993.68(d) 993.68(77) 649.01
d1 kHz −0.01037(99) −0.0198(43) −0.00706
d2 kHz −0.000833(e) −0.000833

# lines 30
σrms kHz 46
σw(f) 0.63

Notes. Values in parentheses represent 1σ uncertainties, expressed in units of the last quoted digit. (a)Parameters converted from Watson A-reduction Hamiltonian to S-reduction (see text). (b)Values reported in Ohshima & Endo (1996) are actually Beff = (B + C)/2 and Deff = DJ + (BC)2/{32[A − (B + C)/2]}. (c)Alessandrini et al. (2018).(d) Fixed to the value derived in Nakanaga & Amano (1987).(e) Fixed to the ab initio value. (f)Dimensionless rms, defined as σw=i(δi/erri)2N${\sigma _w} = \sqrt {{{\sum\nolimits_i {{{({\delta _i}/er{r_i})}^2}} } \over N}} $, where the δs are the residuals weighted by the experimental uncertainty (err) and N the total number of transitions analysed.

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