Electronic structure, oscillator strength, and rovibrationally resolved photodissociation of 24MgH

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Table A.3

Band oscillator strengths and transition energies (cm^–1) of B′²Σ⁺ ← X²Σ⁺ and A²Π ← X²Σ⁺, with J′ = and J″ = 0.

X²Σ⁺(v″)

	ν″ =0				ν″ = 1				ν″ =2				ν″ =3

B′²Σ⁺(v′)	$E_{v^{'} v^{''}}$ ${E_{v'v''}}$		$f_{v^{'} v^{''}}$ ${f_{v'v''}}$		$E_{v^{'} v^{''}}$ ${E_{v'v''}}$		$f_{v^{'} v^{''}}$ ${f_{v'v''}}$		$E_{v^{'} v^{''}}$ ${E_{v'v''}}$		$f_{v^{'} v^{''}}$ ${f_{v'v''}}$		$E_{v^{'} v^{''}}$ ${E_{v'v''}}$		$f_{v^{'} v^{''}}$ ${f_{v'v''}}$

	I	II	I	II	I	II	I	II	I	II	I	II	I	II	I	II
0	22057	22082	9. 81(-7)	7.44(-7)	20612	20651	2.14(-5)	1. 58(-5)	19233	19282	2.10(-4)	1.51(-4)	17922	17980	1.23(-3)	9.30(-4)
1	22870	22887	8. 36(-6)	6.69(-6)	21426	21456	1.40(-4)	1. 09(-4)	20046	20087	9.76(-4)	7.51(-4)	18736	18785	3.66(-3)	3.02(-3)
2	23660	23667	3. 51(-5)	2.95(-5)	22215	22235	4.49(-4)	3. 71(-4)	20836	20867	2.19(-3)	1.80(-3)	19526	19566	4.93(-3)	4.46(-3)
3	24426	24427	9. 71(-5)	8.55(-5)	22982	22995	9.47(-4)	8. 20(-4)	21602	21627	3.11(-3)	2.72(-3)	20292	20325	3.67(-3)	3.69(-3)
4	25169	25163	2. 00(-4)	1.83(-4)	23724	23732	1.47(-3)	1. 33(-3)	22345	22363	3.06(-3)	2.84(-3)	21035	21061	1.34(-3)	1.59(-3)
5	25888	25876	3. 24(-4)	3.09(-4)	24443	24444	1.79(-3)	1. 68(-3)	23064	23075	2.12(-3)	2.09(-3)	21753	21773	6.21(-5)	1.61(-4)
6	25582	26565	4. 29(-4)	4.28(-4)	25137	25133	1.77(-3)	1. 71(-3)	23758	23764	9.46(-4)	1.02(-3)	22447	22462	2.72(-4)	1.41(-4)
7	27251	27229	4. 71(-4)	4.96(-4)	25806	25797	1.43(-3)	1. 43(-3)	24427	24428	1.86(-4)	2.44(-7)	23116	23126	9.62(-4)	7.79(-4)
8	27893	27868	4. 28(-4)	4.88(-4)	26448	26436	9.51(-4)	9. 92(-4)	25069	25067	2.85(-6)	2.95(-7)	23759	23765	1.20(-3)	1.13(-3)
9	28508	28479	3. 17(-4)	4.07(-4)	27063	27047	5.21(-4)	5. 67(-4)	25684	25678	1.66(-4)	1.18(-4)	24373	24376	8.79(-4)	9.49(-4)
10	29093	29060	1. 77(-4)	2.83(-4)	27649	27628	2.30(-4)	2. 61(-4)	26269	26259	3.69(-4)	3.11(-4)	24959	24957	3.90(-4)	5.14(-4)
11	29647	29609	6. 02(-5)	1.58(-4)	28202	28177	8.02(-5)	9. 24(-5)	26823	26808	4.38(-4)	4.01(-4)	25513	25506	7.48(-5)	1.64(-4)
12	30166	30123	3. 67(-6)	6.21(-5)	28721	28691	2.42(-5)	2. 22(-5)	27342	27322	3.82(-4)	3.64(-4)	26031	26020	6.07(-7)	1.48(-5)
13	30646	30597	1. 35(-5)	1.13(-5)	29201	29165	9.20(-6)	2. 53(-6)	27822	27796	2.69(-4)	2.59(-4)	26511	26494	5.39(-5)	7.73(-6)
14	31081	31023	7. 02(-5)	2.66(-7)	29636	29591	8.56(-6)	8.99(-10)	28257	28222	1.65(-4)	1.53(-4)	26946	26920	1.17(-4)	4.45(-5)

A²Π(v′)	$E_{v^{'} v^{''}}$ ${E_{v'v''}}$		$f_{v^{'} v^{''}}$ ${f_{v'v''}}$		$E_{v^{'} v^{''}}$ ${E_{v'v''}}$		$f_{v^{'} v^{''}}$ ${f_{v'v''}}$		$E_{v^{'} v^{''}}$ ${E_{v'v''}}$		$f_{v^{'} v^{''}}$ ${f_{v'v''}}$		$E_{v^{'} v^{''}}$ ${E_{v'v''}}$		$f_{v^{'} v^{''}}$ ${f_{v'v''}}$

	I	II	I	II	I	II	I	II	I	II	I	II	I	II	I	II

0	19315	19288	1.54(-1)	1.61(-1)	17871	17856	1.16(-2)	8. 61(-3)	16491	16490	9.09(-4)	5. 3(-4)	15181	15184	8.29(-5)	4. 1(-5)
1	20863	20822	7. 82(-3)	5.14(-3)	19418	19391	1.29(-1)	1. 41(-1)	18039	18024	2.07(-2)	1.59(-2)	16728	16718	2.51(-3)	1.52(-3)
2	22339	22288	4. 14(-6)	3. 9(-6)	20895	20856	1.42(-2)	9. 38(-3)	19515	19490	1.06(-1)	1.24(-1)	18205	18185	2.74(-2)	1.99(-2)
3	23744	23682	1. 09(-6)	4. 0(-7)	22300	22250	3.68(-6)	4. 4(-5)	20920	20884	1.91(-2)	1.14(-2)	19610	19579	8.59(-2)	1.09(-1)
4	25071	25002	9.14(-10)	< 1. 0(-7)	23627	23570	4.93(-6)	7. 0(-6)	22247	22204	1.04(-7)	2. 4(-4)	20937	20899	2.26(-2)	1.27(-2)
5	26316	26243	6. 63(-9)	< 1. 0(-7)	24872	24811	1.01(-7)	< 1. 0(-7)	23492	23445	1.20(-5)	5. 0(-6)	22182	22140	1.25(-5)	5. 2(-4)
6	27472	27398	4.86(-10)	< 1. 0(-7)	26027	25966	1.05(-8)	4. 0(-7)	24648	24600	3.39(-7)	2. 0(-6)	23337	23295	2.53(-5)	1. 0(-6)
7	28529		4. 87(-9)	.	27084		2.86(-8)	.	25705		4.73(-9)	.	24394		1.52(-6)	.
8	29479		1. 43(-9)	.	28035		5.01(-9)	.	26655		1.55(-9)	.	25345		8.72(-9)	.
9	30311		1.75(-10)	.	28866		1.88(-9)	.	27487		1.06(-8)	.	26176		3.50(-9)	.
10	31009		1. 69(-9)	.	29565		8.62(-9)	.	28185		1.10(-8)	.	26875		5.42(-9)	.

Notes. I: This work. II: Kirby et al. (1979). m(n) denotes m × 10ⁿ.

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