Fig. 1

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Visual summary of the Redhead-TST method. The pre-exponential frequency factor (ν) is determined with Transition State Theory (TST). The main input are the translational () and rotational (
) partition functions, which increase as the molecule transitions from a solid to gaseous state, and Tpeak of the molecule. The Redhead equation takes Tpeak, the heating rate, and vTST as the main inputs to calculate the desorption energy, Edes.
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