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Table D.1

List of bimolecular surface reactions used in this paper and their respective energies barrier (ΔΕ). See Equation 9.

Reaction ΔΕ (K) Note/Reference
Methanol-related reactions
CH3OH# + OH# → CH2OH# + H2O# 1000 Esplugues et al. (2016)
H# + CH2OH# → CH3OH# 0 Hasegawa & Herbst (1993)
H# + CH3O# → CH3OH# 0 Esplugues et al. (2016)
OH# + CH3# → CH3OH# 0 KIDA
H# + CH2OH# → CH3OH 0 Hasegawa & Herbst (1993)
H# + CH3O# → CH3OH 0 Esplugues et al. (2016)
OH# + CH3# → CH3OH 0 KIDA
Other reactions
H# + H# → H2# 0 Hasegawa & Herbst (1993)
H# + C# → CH# 0 Hasegawa & Herbst (1993)
H# + O# → OH# 0 Hasegawa & Herbst (1993)
H# + CH# → CH2# 0 Hasegawa & Herbst (1993)
H# + OH# → H2O# 0 Hasegawa & Herbst (1993), Ioppolo et al. (2008)
H# + C2# → C2H# 0 Hasegawa & Herbst (1993)
H# + C2H# → C2H2 0 Hasegawa & Herbst (1993)
H# + O2# → O2H# 1200 Hasegawa & Herbst (1993)
H# + CO# → HCO# 520 Fuchs et al. (2009)
H# + CO# → HCO# 1106 Rimola et al. (2014)
H# + CO# → HCO# 2000 Awad et al. (2005)
H# + CO# → HOC# 1106 Rimola et al. (2014)
H# + CH2# → CH3# 0 Hasegawa & Herbst (1993)
H# + CO2# → CO# + OH# 10000 Esplugues et al. (2016)
H# + O2H# → H2O2# 0 Chaabouni et al. (2012)
H# + O2H# → OH# + OH# 0 Esplugues et al. (2016)
H# + O3# → O2# + OH# 480 Esplugues et al. (2016)
H# + C3# → C3H# 0 Hasegawa & Herbst (1993)
H# + HOC# → CHOH# 0 Hasegawa & Herbst (1993)
H# + HCO# → H2CO# 0 Hasegawa & Herbst (1993)
H# + HCO# → H2CO 0 Hasegawa & Herbst (1993)
H# + HCO# → CO# + H2# 0 Minissale et al. (2016)
H# + H2O2# → H2O# + OH# 1000 Esplugues et al. (2016)
H# + H2O2# → H2# + O2H# 1900 Lamberts et al. (2016)
H# + CH3# → CH4# 0 Hasegawa & Herbst (1993)
H# + CH3# → CH4 0 Hasegawa & Herbst (1993)
H# + C3H# → C3H2# 0 Hasegawa & Herbst (1993)
H# + C4# → C4H# 0 Hasegawa & Herbst (1993)
H# + C2H2# → C2H3# 1200 Hasegawa & Herbst (1993)
H# + CHOH# → CH2OH# 0 Hasegawa & Herbst (1993)
H# + CHOH# → CH2OH 0 Hasegawa & Herbst (1993)
H# + H2CO# → CH2OH# 5660 Skouteris et al. (2018)
H# + H2CO# → CH2OH 5660 Skouteris et al. (2018)
H# + H2CO# → CH3O# 1890 Skouteris et al. (2018)
H# + H2CO# → CH3O 1890 Skouteris et al. (2018)
H# + H2CO# → HCO# + H2# 3030 Skouteris et al. (2018)
H# + HOCO# → HCOOH# 0 KIDA
H# + HOCO# → HCOOH 0 KIDA
H# + C4H# → C4H2# 0 Hasegawa & Herbst (1993)
H# + C5# → C5H# 0 Hasegawa & Herbst (1993)
H# + C5# → C5H 0 Hasegawa & Herbst (1993)
H# + C2H3# → C2H4# 0 Hasegawa & Herbst (1993)
H# + C2H3# → C2H4 0 Hasegawa & Herbst (1993)
H# + C3H2# → C3H3# 1210 Hasegawa & Herbst (1993)
H# + C3H2# → C3H3 1210 Hasegawa & Herbst (1993)
H# + CH3O# → H2CO# + H2# 850 Li et al. (2004)
H# + C2H4# → C2H5# 1570 Hasegawa & Herbst (1993)
H# + C2H4# → C2H5 1570 Hasegawa & Herbst (1993)
H# + C3H3# → C3H4# 0 Hasegawa & Herbst (1993)
H# + C4H2# → C4H3# 1200 Hasegawa & Herbst (1993)
H# + C5H# → C5H2# 0 Hasegawa & Herbst (1993)
H# + C6# → C6H# 0 Hasegawa & Herbst (1993)
H# + C2H5# → C2H6# 0 Hasegawa & Herbst (1993)
H# + C4H3# → C4H4# 0 Hasegawa & Herbst (1993)
H# + C5H2# → C5H3# 1210 Hasegawa & Herbst (1993)
H# + C6H# → C6H2# 0 Hasegawa & Herbst (1993)
H# + C7# → C7H# 0 Hasegawa & Herbst (1993)
H# + C5H3# → C5H4# 0 Hasegawa & Herbst (1993)
H# + C6H2# → C6H3# 1210 Hasegawa & Herbst (1993)
H# + C7H# → C7H2# 0 Hasegawa & Herbst (1993)
H# + C5H3# → C5H4# 0 Hasegawa & Herbst (1993)
H# + C6H2# → C6H3# 1210 Hasegawa & Herbst (1993)
H# + C7H2# → C7H3# 1210 Hasegawa & Herbst (1993)
H# + C8# → C8H# 0 Hasegawa & Herbst (1993)
H# + C6H3# → C6H4# 0 Hasegawa & Herbst (1993)
H# + C7H2# → C7H3# 1210 Hasegawa & Herbst (1993)
H# + C8H# → C8H2# 0 Hasegawa & Herbst (1993)
H# + C9# → C9H# 0 Hasegawa & Herbst (1993)
H# + C7H3# → C7H4# 0 Hasegawa & Herbst (1993)
H# + C8H2# → C8H3# 1210 Hasegawa & Herbst (1993)
H# + C9H# → C9H2# 0 Hasegawa & Herbst (1993)
H# + C8H3# → C8H4# 0 Hasegawa & Herbst (1993)
H# + C9H2# → C9H3# 1210 Hasegawa & Herbst (1993)
H# + C9H3# → C9H4# 1210 Hasegawa & Herbst (1993)
H# + H2C2O2# → H3C2O2# 0 Paardekooper et al. (2016)
H# + H3C2O2# → H4C2O2# 0 Paardekooper et al. (2016)
H# + H4C2O2# → H5C2O2# 0 Paardekooper et al. (2016)
H# + H5C2O2# → H6C2O2# 0 Paardekooper et al. (2016)
H# + H4C2O2# → H5C2O2# 0 Paardekooper et al. (2016)
H# + H5C2O2# → H6C2O2# 0 Paardekooper et al. (2016)
C# + C# → C2# 161 Hasegawa & Herbst (1993)
C# + C# → C2 161 Hasegawa & Herbst (1993)
C# + O# → CO# 0 Hasegawa & Herbst (1993)
C# + O# → CO 0 Hasegawa & Herbst (1993)
C# + C2# → C3# 0 Hasegawa & Herbst (1993)
C# + C2# → C3 0 Hasegawa & Herbst (1993)
C# + OH# → HOC# 0 Hasegawa & Herbst (1993)
C# + OH# → HOC 0 Hasegawa & Herbst (1993)
C# + O2# → CO# + O# 0 Hasegawa & Herbst (1993)
C# + CH2# → C2H2# 0 Hasegawa & Herbst (1993)
C# + C2H# → C3H# 0 Hasegawa & Herbst (1993)
C# + CH3# → C2H3# 0 Hasegawa & Herbst (1993)
C# + C3# → C4# 0 Hasegawa & Herbst (1993)
C# + C3# → C4 0 Hasegawa & Herbst (1993)
C# + C3H# → C4H# 0 Hasegawa & Herbst (1993)
C# + C4# → C5# 0 Hasegawa & Herbst (1993)
C# + C5# → C6# 0 Hasegawa & Herbst (1993)
C# + C2H3# → CH2C2H# 1210 KIDA
C# + C2H3# → CH2C2H 1210 KIDA
C# + C6# → C7# 0 Hasegawa & Herbst (1993)
C# + C7# → C8# 0 Hasegawa & Herbst (1993)
C# + C8# → C9# 0 Hasegawa & Herbst (1993)
O# + O# → O2# 0 Hasegawa & Herbst (1993)
O# + O# → O2 0 Hasegawa & Herbst (1993)
O# + H2# → OH# + H# 2040 Lamberts et al. (2014)
O# + CH# → HCO# 0 Hasegawa & Herbst (1993)
O# + CH# → HCO 0 Hasegawa & Herbst (1993)
O# + CH# → CO# + H# 0 Hasegawa & Herbst (1993)
O# + OH# → O2H# 0 Hasegawa & Herbst (1993)
O# + OH# → O2H 0 Hasegawa & Herbst (1993)
O# + OH# → O2# + H# 0 Hasegawa & Herbst (1993)
O# + CO# → CO2# 650 Raut & Baragiola (2011)
O# + CO# → CO2 650 Goumans et al. (2008)
O# + O2# → O3# 0 Hasegawa & Herbst (1993)
O# + O2# → O3 0 Hasegawa & Herbst (1993)
O# + O2H# → O2# + OH# 0 Hasegawa & Herbst (1993)
O# + CH2# → H2CO# 0 Hasegawa & Herbst (1993)
O# + CH2# → H2CO 0 Hasegawa & Herbst (1993)
O# + C3# → C3O# 0 Hasegawa & Herbst (1993)
O# + HCO# → CO2# + H# 0 Hasegawa & Herbst (1993); Esplugues et al. (2016)
O# + HOCO# → CO2# + OH# 0 KIDA
O# + H2CO# → CO2# + H2# 335 Minissale et al. (2015)
O# + CH3O# → CH3# + O2# 240 Hasegawa & Herbst (1993)
CH# + CH# → C2H2# 0 Hasegawa & Herbst (1993)
CH# + OH# → CHOH# 0 Hasegawa & Herbst (1993)
CH# + C2# → C3H# 0 Hasegawa & Herbst (1993)
CH# + CH3# → C2H4# 0 Hasegawa & Herbst (1993)
CH# + C3# → C4H# 0 Hasegawa & Herbst (1993)
CH# + C4# → C5H# 0 Hasegawa & Herbst (1993)
CH# + C5# → C6H# 0 Hasegawa & Herbst (1993)
CH# + C6# → C7H# 0 Hasegawa & Herbst (1993)
CH# + C7# → C8H# 0 Hasegawa & Herbst (1993)
CH# + C8# → C9H# 0 Hasegawa & Herbst (1993)
C2H# + CH# → C3H2# 0 Hasegawa & Herbst (1993)
C2H# + CH# → C3H2 0 Hasegawa & Herbst (1993)
CH3# + CH3# → C2H6# 0 KIDA
H2# + OH# → H2O# + H# 2100 Oba et al. (2012)
H2# + CH# → CH3# 116 NIST
H2# + CH# → CH3 116 NIST
H2# + H2CO# → CH3OH# 35119 NIST
H2# + C2H3# → C2H4# + H# 2646 Fahr & Laufer (1995), Lara et al. (2014)
H2# + C2H# → C2H2# + H# 1443 Opansky & Leone (1996), Lara et al. (2014)
H2# + C2# → C2H# + H# 1469 Lara et al. (2014)
H2# + C4H# → C4H2# + H# 998 Lavvas et al. (2008), Lara et al. (2014)
OH# + OH# → H2O2# 0 Esplugues et al. (2016)
OH# + OH# → H2O2 0 Esplugues et al. (2016)
OH# + CH2# → CH2OH# 0 Hasegawa & Herbst (1993)
OH# + CH4# → CH3# + H2O# 1160 Qasim et al. (2018)
OH# + CO# → HOCO# 150 Ruaud et al. (2015)
OH# + CO# → HOCO 150 Ruaud et al. (2015)
OH# + CO# → CO2# + H# 150 Ruaud et al. (2015)
H2CO# + OH# → HCO# + H2O# 0 KIDA
H2CO# + OH# → HCO + H2O# 0 KIDA
CH3OH# + OH# → CH2OH + H2O# 1000 Esplugues et al. (2016)
H2# + H2O# → H2OH2# 0 Guess
H2OCO# + OH# → H2O# + CO#2 + H# 150 Guess
H2OCO# + O# → H2O# + CO2# 650 Guess
H2OCO# + H# → H2O# + HCO# 0 Guess
H2OCO# + CH# → CH2OH# + CO# 0 Guess
H2OCO# + CH# → H2CO# + CO# + H# 0 Guess
H2OCO# + C# → CH2O# + CO# 0 Guess
H2OCO# + OH# → H2O# + HOCO# 0 Guess
H2OCO# + CH2# → H2O# + H2CO# + C# 0 Guess
CO# + H2O# → H2OCO# 0 Guess
C# + H2O# → H2OC# 0 Guess
CH2OH# + O# → HCOOH# + H# 0 Guess
HCO# + OH# → HCOOH# 0 Guess
HCO# + OH# → HCOOH 0 Guess
HOCO# + H# → HCOOH# 0 Guess
HOCO# + H# → HCOOH 0 Guess

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