Table 3
Experimental ground-state spectroscopic constants of cis-gauche and cis-trans n-PrCHO (A-Reduction, Ir-Representation).
| Parameters | cis-gauche | cis-gauche (mw)(a) | cis-trans | cis-trans (mw)(a) |
|---|---|---|---|---|
| A(b) (MHz) | 8508.53795 (16)(c) | 8508.527 (3) | 15069.38645 (92) | 15069.347 (5) |
| B (MHz) | 3588.81565 (14) | 3588.809 (1) | 2555.992540 (85) | 2555.983(2) |
| C (MHz) | 2928.57776 (10) | 2928.5749 (9) | 2278.607628 (88) | 2278.608(1) |
| |µa|, |µb|, |µc|(d) (D) | Yes/yes/yes | Yes/yes/no | Yes/yes/no | Yes/yes/no |
| ∆J (kHz) | 3.648341 (87) | 3.63 (1) | 0.611752 (30) | 0.50 (5) |
| ∆jk (kHz) | −12.199378 (19) | −12.04 (8) | −4.23054 (30) | −4.3 (3) |
| ∆K (kHz) | 23.5595 (33) | 23.3 (1) | 37.8014 (89) | − |
| δJ (kHz) | 1.110506 (38) | 1.101 (4) | 0.0994029 (45) | − |
| δK (kHz) | 5.60931 (81) | 5.3(1) | −0.1183 (10) | − |
| ΦJ (mHz) | −12.147 (23) | − | 0.0344(35) | − |
| Φjk (Hz) | 0.12797 (67) | − | 0.004310 (50) | − |
| ΦK (Hz) | 0.71765 (40) | − | 0.492 (27) | − |
| Φkj (Hz) | −0.49693 (20) | − | −0.2641 (11) | − |
| ϕJ (mHz) | −5.603 (11) | − | − | − |
| ϕjk (Hz) | −0.06452 (33) | − | − | − |
| N(e) | 2839 | 58 | 1375 | 16 |
| σ (f) (kHz) | 29 | 15 | 28 | 8 |
| σw (ɡ) | 1.02 | − | 0.95 | − |
Notes. (a)Previously measured microwave data from Hotopp et al. (2012) included for comparison. (b)A, B, and C represent the rotational constants. (c)Standard error in parentheses in units of the last digit. Their values are close to the 1σ standard uncertainties since the unit-less (weighted) deviation of the fit is very close to 1.0. (d)|µa|, |µb|, and |µc| are the absolute values of the electric dipole moment components (in D). (e)N is the number of transitions.(f)σ is the rms deviation of the fit. (ɡ)σw is the unit-less (weighted) deviation of the fit.
Current usage metrics show cumulative count of Article Views (full-text article views including HTML views, PDF and ePub downloads, according to the available data) and Abstracts Views on Vision4Press platform.
Data correspond to usage on the plateform after 2015. The current usage metrics is available 48-96 hours after online publication and is updated daily on week days.
Initial download of the metrics may take a while.