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Table A.1.
Branching fractions and oscillator strengths for 3d3 (4F)4p–3d3 (4F)4d transitions in V II.
Upper | Lower | λaira (Å) | σa (cm−1) | BFexp | UncBF | BFtheoryb | BFtheoryc | log(gf)exp | Uncgf |
---|---|---|---|---|---|---|---|---|---|
levela | levela | (%) | (%) | ||||||
3d3 (4F)4d e5P1 | z5D0 | 2830.6580 | 35317.085 | 0.218 | 8.9 | 0.205 | 0.203 | −0.388 | 12 |
z5D1 | 2835.3139 | 35259.093 | 0.409 | 6.3 | 0.417 | 0.418 | −0.128 | 10 | |
z5D2 | 2844.1564 | 35149.478 | 0.263 | 7.1 | 0.269 | 0.273 | −0.302 | 11 | |
Residual | 0.110 | ||||||||
3d3 (4F)4d e5P2 | z5F2 | 2776.8557 | 36001.328 | 0.032 | 13.5 | 0.023 | 0.034 | −1.028 | 16 |
z3D2 | 2805.5024 | 35633.741 | 0.041 | 13.6 | 0.083 | 0.064 | −0.908 | 16 | |
z3D3 | 2818.4608 | 35469.916 | 0.168 | 4.5 | 0.231 | 0.176 | −0.289 | 9 | |
z5D1 | 2822.8001 | 35415.393 | 0.088 | 6.6 | 0.095 | 0.083 | −0.571 | 11 | |
z5D2 | 2831.5654 | 35305.767 | 0.295 | 3.6 | 0.300 | 0.273 | −0.041 | 9 | |
z5D3 | 2843.7697 | 35154.257 | 0.345 | 3.3 | 0.237 | 0.329 | 0.030 | 9 | |
Residual | 0.032 | ||||||||
3d3 (4F)4d e5P3 | z3D3 | 2799.9833 | 35703.975 | 0.098 | 6.4 | 0.230 | 0.092 | −0.366 | 11 |
z5D2 | 2812.9153 | 35539.839 | 0.021 | 16.6 | 0.041 | 0.039 | −1.036 | 19 | |
z5D3 | 2824.9586 | 35388.334 | 0.105 | 6.6 | 0.180 | 0.068 | −0.326 | 11 | |
z5D4 | 2825.7945 | 35377.866 | 0.719 | 3.1 | 0.492 | 0.692 | 0.508 | 9 | |
Residual | 0.058 | ||||||||
3d3 (4F)4d e5F1 | z5G2 | 2613.8377 | 38246.503 | 0.094 | 5.2 | 0.092 | 0.089 | −0.818 | 10 |
z3D1 | 2750.2255 | 36349.908 | 0.370 | 3.5 | 0.399 | 0.389 | −0.179 | 9 | |
z5F2 | 2764.2295 | 36165.763 | 0.163 | 5.0 | 0.183 | 0.169 | −0.530 | 10 | |
z5F1 | 2785.8843 | 35884.659 | 0.112 | 7.4 | 0.049 | 0.067 | −0.688 | 11 | |
z5D0 | 2805.1817 | 35637.814 | 0.117 | 7.4 | 0.127 | 0.124 | −0.661 | 11 | |
z5D1 | 2809.7551 | 35579.810 | 0.096 | 8.8 | 0.102 | 0.091 | −0.746 | 12 | |
Residual | 0.048 | ||||||||
3d3 (4F)4d e5F2 | z5G2 | 2601.0539 | 38434.469 | 0.207 | 5.3 | 0.204 | 0.096 | −0.265 | 10 |
z5G3 | 2611.4491 | 38281.485 | 0.135 | 5.5 | 0.131 | 0.144 | −0.447 | 10 | |
z3D1 | 2736.0767 | 36537.870 | 0.080 | 6.3 | 0.106 | 0.020 | −0.632 | 10 | |
z5F2 | 2749.9364 | 36353.729 | 0.262 | 5.2 | 0.294 | 0.360 | −0.114 | 10 | |
z5F3 | 2768.6482 | 36108.046 | 0.072 | 7.2 | 0.076 | 0.126 | −0.671 | 11 | |
z5F1 | 2771.373 | 39072.550 | bl* | 0.066 | 0.016 | ||||
z3D2 | 2778.0285 | 35986.130 | 0.102 | 6.3 | 0.048 | 0.082 | −0.513 | 10 | |
z5D1 | 2794.9883 | 35767.780 | 0.048 | 10.7 | 0.047 | 0.095 | −0.834 | 14 | |
Residual | 0.095 | ||||||||
3d3 (4F)4d e5F3 | z5G3 | 2603.3537 | 38400.518 | 0.146 | 3.1 | 0.154 | 0.080 | −0.271 | 9 |
z5G4 | 2617.0400 | 38199.707 | 0.136 | 3.2 | 0.145 | 0.150 | −0.296 | 9 | |
z5F2 | 2740.9613 | 36472.761 | 0.083 | 3.8 | 0.108 | 0.037 | −0.471 | 9 | |
z5F3 | 2759.5520 | 36227.061 | 0.422 | 1.8 | 0.405 | 0.462 | 0.241 | 8 | |
z3D2 | 2768.8722 | 36105.126 | 0.037 | 7.2 | 0.010 | 0.000 | −0.820 | 11 | |
z5F4 | 2777.2875 | 35995.731 | 0.064 | 4.6 | 0.071 | 0.102 | −0.574 | 9 | |
z3D3 | 2781.4915 | 35941.328 | 0.033 | 7.8 | 0.009 | 0.026 | −0.859 | 11 | |
z5D2 | 2794.2532 | 35777.189 | 0.065 | 5.3 | 0.067 | 0.107 | −0.561 | 10 | |
z5D3 | 2806.1359 | 35625.697 | 0.012 | 22.4 | 0.018 | 0.028 | −1.302 | 24 | |
Residual | 0.002 | ||||||||
3d3 (4F)4d e5F4 | z5G3 | 2594.3680 | 38533.512 | 0.006 | 14.9 | 0.008 | 0.004 | −1.558 | 16 |
z5G4 | 2607.9594 | 38332.706 | 0.156 | 3.3 | 0.156 | 0.088 | −0.126 | 7 | |
z5G5 | 2624.8423 | 38086.166 | 0.132 | 3.3 | 0.132 | 0.137 | −0.195 | 7 | |
z5F3 | 2749.4562 | 36360.077 | 0.147 | 3.4 | 0.147 | 0.070 | −0.107 | 7 | |
z5F4 | 2767.0633 | 36128.728 | 0.441 | 1.8 | 0.445 | 0.529 | 0.375 | 6 | |
z5F5 | 2782.6108 | 35926.872 | 0.036 | 6.1 | 0.038 | 0.051 | −0.706 | 8 | |
z5D3 | 2795.7014 | 35758.657 | 0.071 | 4.6 | 0.063 | 0.095 | −0.411 | 7 | |
Residual | 0.012 | ||||||||
3d3 (4F)4d e5F5 | z5G5 | 2615.3665 | 38224.149 | 0.178 | 3.2 | 0.174 | 0.095 | 0.030 | 7 |
z5G6 | 2635.3914 | 37933.721 | 0.101 | 3.4 | 0.103 | 0.113 | −0.208 | 7 | |
z5F4 | 2756.5346 | 36266.715 | 0.195 | 3.2 | 0.183 | 0.078 | 0.116 | 7 | |
z5F5 | 2771.9633 | 36064.866 | 0.430 | 2.0 | 0.436 | 0.547 | 0.465 | 6 | |
z5F4 | 2785.7648 | 35886.198 | 0.088 | 3.9 | 0.096 | 0.161 | −0.218 | 7 | |
Residual | 0.007 | ||||||||
3d3 (4F)4d e5G2 | z5G2 | 2611.1949 | 38285.211 | 0.148 | 2.9 | 0.150 | 0.259 | −0.393 | 12 |
z5G3 | 2621.6713 | 38132.230 | 0.015 | 11.2 | 0.014 | 0.000 | −1.392 | 16 | |
z3D1 | 2747.2996 | 36388.618 | 0.168 | 3.0 | 0.215 | 0.229 | −0.293 | 12 | |
z5F2 | 2761.2739 | 36204.472 | 0.118 | 3.6 | 0.130 | 0.033 | −0.441 | 12 | |
z5F3 | 2780.1406 | 35958.792 | 0.095 | 4.2 | 0.104 | 0.048 | −0.532 | 12 | |
z5F1 | 2782.8822 | 35923.368 | 0.286 | 2.4 | 0.223 | 0.341 | −0.051 | 11 | |
z5D1 | 2806.7007 | 35618.528 | 0.101 | 4.6 | 0.100 | 0.054 | −0.497 | 12 | |
z5D2 | 2815.3665 | 35508.899 | 0.058 | 8.4 | 0.052 | 0.025 | −0.737 | 14 | |
Residual | 0.011 | ||||||||
3d3(4F)4d e5G3 | z5G3 | 2616.6275 | 38205.729 | 0.168 | 2.8 | 0.180 | 0.243 | −0.215 | 9 |
z5G4 | 2630.4616 | 38004.809 | 0.041 | 4.2 | 0.005 | 0.001 | −0.824 | 9 | |
z5F2 | 2755.6791 | 36277.973 | 0.172 | 2.9 | 0.257 | 0.243 | −0.161 | 9 | |
z5F3 | 2774.4693 | 36032.291 | 0.099 | 3.6 | 0.099 | 0.039 | −0.392 | 9 | |
z3D2 | 2783.8890 | 35910.378 | 0.334 | 2.1 | 0.276 | 0.314 | 0.138 | 8 | |
z5F4 | 2792.3992 | 35800.942 | 0.063 | 5.0 | 0.061 | 0.023 | −0.588 | 10 | |
z5D2 | 2809.5498 | 35582.410 | 0.087 | 4.2 | 0.083 | 0.029 | −0.439 | 9 | |
z5D3 | 2821.5653 | 35430.891 | 0.023 | 14.5 | 0.025 | 0.039 | −1.022 | 17 | |
Residual | 0.014 | ||||||||
3d3 (4F)4d e5G4 | z5G4 | 2622.7132 | 38117.082 | 0.192 | 2.8 | 0.224 | 0.270 | −0.003 | 9 |
z5G5 | 2639.7873 | 37870.556 | 0.006 | 16.5 | 0.006 | 0.000 | −1.471 | 19 | |
z5F3 | 2765.8594 | 36144.452 | 0.253 | 2.6 | 0.387 | 0.349 | 0.162 | 9 | |
z5F4 | 2783.6777 | 35913.104 | 0.132 | 3.2 | 0.135 | 0.039 | −0.116 | 9 | |
z3D3 | 2787.9014 | 35858.697 | 0.298 | 2.4 | 0.117 | 0.269 | 0.239 | 9 | |
z5F5 | 2799.4125 | 35711.255 | 0.028 | 9.5 | 0.033 | 0.016 | −0.778 | 13 | |
z5D3 | 2812.6609 | 35543.053 | 0.075 | 4.3 | 0.073 | 0.039 | −0.354 | 10 | |
z5D4 | 2813.4894 | 35532.588 | 0.009 | 24.1 | 0.018 | 0.011 | −1.290 | 26 | |
Residual | 0.007 | ||||||||
3d3 (4F)4d e5G5 | z5D5 | 2628.7073 | 38030.171 | 0.189 | 4.3 | 0.204 | 0.289 | 0.034 | 9 |
z5G6 | 2648.9375 | 37739.747 | 0.010 | 8.6 | 0.010 | 0.001 | −1.233 | 12 | |
z5F4 | 2771.3590 | 36072.729 | 0.405 | 4.8 | 0.399 | 0.493 | 0.411 | 9 | |
z5F5 | 2786.9538 | 35870.889 | 0.187 | 4.4 | 0.177 | 0.068 | 0.082 | 9 | |
z5D4 | 2800.9054 | 35692.222 | 0.216 | 4.3 | 0.208 | 0.146 | 0.148 | 9 | |
Residual | 0.003 | ||||||||
3d3(4F)4d e5G6 | z5G6 | 2629.6758 | 38016.166 | 0.374 | 4.0 | 0.398 | 0.403 | 0.406 | 7 |
z5F5 | 2765.6408 | 36147.309 | 0.623 | 2.4 | 0.599 | 0.596 | 0.671 | 6 | |
Residual | 0.003 |
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