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Table 1.

Experimental details and the measured lifetimes of the 3d3(4F)4d levels in V II.

Level Ea (cm−1) Excitation λairb (nm) Detection λairc (nm) τexp (ns) τthd (ns) τthe (ns)
e5P1 72 518 285.98, 286.32 283f 1.95 ± 0.15 2.17 1.91
e5P2 72 674 285.35, 285.68 283f 1.95 ± 0.15 2.39 1.89
e5P3 72 909 284.73, 285.22 280, 283f 1.87 ± 0.15 4.13 1.88

e5F1 72 839 284.68 275 1.90 ± 0.15 2.04 1.79
e5F2 73 027 284.74 261, 275 1.93 ± 0.15 2.00 1.76
e5F3 73 146 284.91 276 1.94 ± 0.15 2.00 1.77
e5F4 73 279 284.37, 285.16 262, 277 1.92 ± 0.10 2.01 1.77
e5F5 73 417 284.60 276 1.87 ± 0.10 2.03 1.78

e5G2 72 878 284.52 261, 278 1.87 ± 0.20 2.04 1.78
e5G3 72 951 284.56 276, 278 1.98 ± 0.15 2.04 1.79
e5G4 73 064 285.24 277, 279 1.80 ± 0.15 2.34 1.79
e5G5 73 223 285.38 277, 280 1.99 ± 0.15 2.05 1.79
e5G6 73 500 284.27 263 1.98 ± 0.10 2.03 1.77

Notes.

(b)

Two-photon excitation starting from 3d34s a5F. Line width 0.01 nm.

(c)

All measurements were made in the second spectral order.

(d)

Semi-empirical superposition-of-configurations calculation by Kurucz (1995).

(e)

Semi-empirical superposition-of-configurations calculation by Kurucz (2013).

(f)

Corrected for scattered laser light.

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