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Table 1.
Experimental details and the measured lifetimes of the 3d3(4F)4d levels in V II.
Level | Ea (cm−1) | Excitation λairb (nm) | Detection λairc (nm) | τexp (ns) | τthd (ns) | τthe (ns) |
---|---|---|---|---|---|---|
e5P1 | 72 518 | 285.98, 286.32 | 283f | 1.95 ± 0.15 | 2.17 | 1.91 |
e5P2 | 72 674 | 285.35, 285.68 | 283f | 1.95 ± 0.15 | 2.39 | 1.89 |
e5P3 | 72 909 | 284.73, 285.22 | 280, 283f | 1.87 ± 0.15 | 4.13 | 1.88 |
e5F1 | 72 839 | 284.68 | 275 | 1.90 ± 0.15 | 2.04 | 1.79 |
e5F2 | 73 027 | 284.74 | 261, 275 | 1.93 ± 0.15 | 2.00 | 1.76 |
e5F3 | 73 146 | 284.91 | 276 | 1.94 ± 0.15 | 2.00 | 1.77 |
e5F4 | 73 279 | 284.37, 285.16 | 262, 277 | 1.92 ± 0.10 | 2.01 | 1.77 |
e5F5 | 73 417 | 284.60 | 276 | 1.87 ± 0.10 | 2.03 | 1.78 |
e5G2 | 72 878 | 284.52 | 261, 278 | 1.87 ± 0.20 | 2.04 | 1.78 |
e5G3 | 72 951 | 284.56 | 276, 278 | 1.98 ± 0.15 | 2.04 | 1.79 |
e5G4 | 73 064 | 285.24 | 277, 279 | 1.80 ± 0.15 | 2.34 | 1.79 |
e5G5 | 73 223 | 285.38 | 277, 280 | 1.99 ± 0.15 | 2.05 | 1.79 |
e5G6 | 73 500 | 284.27 | 263 | 1.98 ± 0.10 | 2.03 | 1.77 |
Notes.
(d)
Semi-empirical superposition-of-configurations calculation by Kurucz (1995).
(e)
Semi-empirical superposition-of-configurations calculation by Kurucz (2013).
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