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Table A.3
Radial parameters (in cm-1) adopted for the calculations in Zr vi.
| Configuration | Parameter | HFR | Fitted | Ratio | Notea |
|
|
|||||
| Odd parity | |||||
| 4p5 | E av | 22 997 | 23 322 | ||
| ζ 4p | 10 007 | 10 580 | 1.057 | ||
| 4p45p | E av | 461 912 | 446 765 | ||
| F2(4p,4p) | 84 088 | 79 559 | 0.946 | ||
| α | 0 | –651 | |||
| ζ 4p | 10 577 | 10 907 | 1.031 | ||
| ζ 5p | 2382 | 2701 | 1.134 | ||
| F2(4p,5p) | 26 052 | 21 472 | 0.824 | ||
| G0(4p,5p) | 5535 | 4696 | 0.848 | ||
| G2(4p,5p) | 7459 | 6664 | 0.893 | ||
| Even parity | |||||
| 4s4p6 | E av | 251 206 | 224 383 | ||
| 4p44d | E av | 289 403 | 291 464 | ||
| F2(4p,4p) | 82 744 | 78 447 | 0.948 | ||
| α | 0 | –450 | |||
| ζ 4p | 10 187 | 10 521 | 1.033 | ||
| ζ 4d | 721 | 854 | 1.184 | ||
| F2(4p,4d) | 69 677 | 62 179 | 0.892 | ||
| G1(4p,4d) | 86 802 | 72 077 | 0.831 | ||
| G3(4p,4d) | 53 829 | 45 721 | 0.849 | ||
| 4p45d | E av | 536 543 | 535 860 | ||
| F2(4p,4p) | 84 140 | 77 928 | 0.926 | ||
| α | 0 | –450 | F | ||
| ζ 4p | 10 569 | 10 891 | 1.030 | ||
| ζ 5d | 217 | 259 | 1.191 | ||
| F2(4p,5d) | 19 555 | 16 945 | 0.867 | ||
| G1(4p,5d) | 10 870 | 8250 | 0.759 | R1 | |
| G3(4p,5d) | 8037 | 6100 | 0.759 | R1 | |
| 4p45s | E av | 386 802 | 387 950 | ||
| F2(4p,4p) | 83 739 | 79 833 | 0.953 | ||
| α | 0 | –665 | |||
| ζ 4p | 10 498 | 10 846 | 1.033 | ||
| G1(4p,5s) | 8725 | 7618 | 0.873 | ||
| 4p46s | E av | 564 837 | 564 005 | ||
| F2(4p,4p) | 84 213 | 81 311 | 0.965 | ||
| α | 0 | –332 | |||
| ζ 4p | 10 600 | 11 164 | 1.053 | ||
| G1(4p,6s) | 2787 | 2372 | 0.851 | ||
| 4s4p6–4p44d | R1(4p4p;4s4d) | 96 078 | 72 916 | 0.759 | R2 |
| 4s4p6–4p45d | R1(4p4p;4s5d) | 32 299 | 24 513 | 0.759 | R2 |
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