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Table B.3

Comparison between available experimental and calculated energy levels in Xe iv.

E exp a E calc b ΔE J Leading components (in %) in LS couplingc
Odd parity
0.0 3 –3 1.5 81 5p34S + 12 5p32P
13 267.0 13 248 19 1.5 72 5p32D + 13 5p32P + 11 5p34S
17 510.7 17 524 –13 2.5 96 5p32D
28 036.4 28 043 –7 0.5 96 5p32P
35 649.6 35 644 5 1.5 70 5p32P + 20 5p32D + 5 5p34S
180 151.5 180 062 90 2.5 68 5p2(3P)4f 4G + 7 5p2(1S)4f 2F + 7 5p2(3P)4f 4F
182 219.1 182 422 –203 3.5 50 5p2(3P)4f 4G + 14 5p2(3P)4f 4D + 14 5p2(3P)4f 4F
186 109.1 186 093 16 0.5 48 5p2(3P)6p 4D + 19 5p2(3P)6p 2S + 11 5p2(3P)6p 2P
187 532.9 187 312 221 3.5 31 5p2(3P)4f 4G + 27 5p2(1D)4f 2G + 23 5p2(3P)4f 2G
188 251.8 187 942 310 4.5 83 5p2(3P)4f 4G + 9 5p2(3P)4f 4F
188 720.6 188 478 243 2.5 52 5p2(3P)4f 2D + 19 5p2(3P)4f 4G + 11 5p2(3P)4f 4D
189 842.1 189 879 –37 3.5 54 5p2(3P)4f 4D + 18 5p2(3P)4f 2G + 15 5p2(1D)4f 2G
190 792.5 190 927 –135 1.5 38 5p2(3P)6p 4D + 14 5p2(3P)6p 4P + 12 5p2(3P)6p 2D
191 858.2 192 042 –184 1.5 43 5p2(3P)4f 4F + 16 5p2(3P)4f 4D + 14 5p2(3P)4f 2D
191 978.1 192 079 –101 2.5 54 5p2(3P)4f 4D + 18 5p2(3P)4f 2D + 14 5p2(3P)4f 4F
193 860.6 193 915 –54 0.5 47 5p2(3P)6p 2S + 36 5p2(3P)6p 4D + 13 5p2(3P)6p 4P
195 784.6 195 729 56 1.5 43 5p2(3P)4f 4D + 17 5p2(3P)4f 2D + 9 5p2(3P)6p 2D
196 325.2 196 734 –409 3.5 56 5p2(3P)4f 4F + 31 5p2(1D)4f 2F
196 506.1 196 718 –212 2.5 51 5p2(3P)4f 4F + 22 5p2(1D)4f 2F + 16 5p2(3P)4f 4D
196 654.7 196 546 108 0.5 86 5p2(3P)4f 4D + 6 5p2(1D)4f 2P
196 724.9 196 748 –23 1.5 31 5p2(3P)6p 4D + 20 5p2(3P)6p 2D + 17 5p2(3P)4f 4D
198 943.1 199 026 –83 2.5 85 5p2(3P)6p 4D + 6 5p2(1D)6p 2F
199 397.0 199 389 8 1.5 33 5p2(3P)4f 2D + 21 5p2(3P)4f 4F + 17 5p2(3P)6p 4S
200 486.2 200 403 83 2.5 33 5p2(3P)6p 4P + 32 5p2(3P)6p 2D + 18 5p2(1D)6p 2D
200 899.4 200 873 26 0.5 72 5p2(3P)6p 4P + 11 5p2(3P)6p 2S + 10 5p2(3P)6p 2P
201 027.6 200 782 245 1.5 29 5p2(3P)6p 4S + 21 5p2(3P)6p 2D + 16 5p2(3P)4f 2D
202 076.1 202 067 9 4.5 45 5p2(3P)4f 4F + 34 5p2(3P)4f 2G + 11 5p2(1D)4f 2H
202 951.1 203 327 –376 3.5 58 5p2(3P)6p 4D + 24 5p2(1D)6p 2F + 7 5p2(3P)4f 2F
204 140.0 203 905 235 1.5 47 5p2(3P)6p 4P + 20 5p2(3P)6p 4S + 15 5p2(1D)6p 2P
205 205.0 205 427 –222 2.5 46 5p2(1D)4f 2F + 15 5p2(3P)4f 2F + 8 5p2(3P)6p 4P
205 216.7 204 872 345 3.5 25 5p2(3P)4f 2F + 19 5p2(3P)4f 2G + 14 5p2(3P)6p 4D
206 061.2 205 962 99 1.5 52 5p2(3P)6p 2P + 26 5p2(1D)6p 2D + 10 5p2(1D)6p 2P
206 216.2 206 083 133 4.5 40 5p2(1D)4f 2G + 31 5p2(1D)4f 2H + 13 5p2(3P)4f 4F
206 713.1 206 868 –155 3.5 30 5p2(1D)4f 2F + 21 5p2(1D)4f 2G + 14 5p2(3P)4f 4F
207 056.6 207 071 –14 2.5 17 5p2(3P)6p 4P + 16 5p2(1D)4f 2F + 13 5p2(3P)6p 2D
208 621.1 208 870 –249 2.5 43 5p2(3P)4f 2F + 15 5p2(3P)6p 2D + 9 5p2(1S)4f 2F
209 343.7 209 185 158 0.5 68 5p2(3P)6p 2P + 13 5p2(3P)6p 2S + 7 5p2(3P)6p 4D
213 735.6 213 529 207 1.5 76 5p2(1D)4f 2D
215 625.5 215 579 47 2.5 39 5p2(1D)6p 2F + 24 5p2(1D)4f 2D + 16 5p2(3P)6p 2D
216 141.0 216 086 55 1.5 35 5p2(1D)6p 2D + 24 5p2(1D)6p 2P + 7 5p2(3P)6p 4P
216 910.7 216 873 37 2.5 58 5p2(1D)6p 2D + 30 5p2(3P)6p 4P + 6 5p2(1D)6p 2F
217 239.7 217 115 125 3.5 31 5p2(1D)6p 2F + 30 5p2(3P)4f 2F + 14 5p2(3P)6p 4D
219 001.7 219 675 –673 2.5 36 5p2(1D)4f 2D + 17 5p2(3P)6p 2D + 16 5p2(1D)6p 2F
219 717.3 219 565 152 3.5 41 5p2(1D)6p 2F + 30 5p2(3P)4f 2F + 12 5p2(3P)6p 4D
220 081.6 220 085 –4 0.5 82 5p2(1D)6p 2P + 7 5p2(3P)6p 2S
220 789.8 220 565 225 0.5 82 5p2(1D)4f 2P + 5 5p2(3P)4f 4D
224 498.2 224 669 –171 1.5 35 5p2(1D)6p 2P + 26 5p2(3P)6p 2P + 14 5p2(1D)6p 2D
228 975.4 228 900 75 3.5 79 5p2(1S)4f 2F + 8 5p2(1D)4f 2F
232 811.4 232 916 –105 0.5 82 5p2(1S)6p 2P + 6 5p2(3P)6p 2P
235 560.7 235 449 112 1.5 83 5p2(1S)6p 2P
99 663.8 99 384 279 2.5 84 5s5p44P + 9 5p2(3P)5d 4P
106 923.2 106 996 –72 1.5 83 5s5p44P + 10 5p2(3P)5d 4P
109 254.4 109 497 –243 0.5 82 5s5p44P + 10 5p2(3P)5d 4P + 6 5s5p42S
121 928.9 122 134 –205 1.5 56 5s5p42D + 15 5p2(1D)5d 2D + 8 5p2(3P)5d 2P
125 474.7 125 429 46 2.5 69 5s5p42D + 19 5p2(1D)5d 2D + 5 5s5p44P
133 027.4 132 735 292 1.5 28 5p2(3P)5d 2P + 24 5p2(3P)5d 4F + 15 5s5p42D
134 980.6 135 211 –230 1.5 56 5p2(3P)5d 4F + 22 5p2(3P)5d 2P + 13 5s5p42P
136 495.9 136 607 –111 2.5 63 5p2(3P)5d 4F + 22 5p2(3P)5d 4D
136 796.3 136 825 –29 0.5 42 5p2(3P)5d 2P + 24 5s5p42P + 13 5s5p42S
141 624.8 141 917 –292 3.5 78 5p2(3P)5d 4F + 16 5p2(3P)5d 4D
141 824.4 141 665 159 2.5 39 5p2(1D)5d 2F + 31 5p2(3P)5d 2F + 18 5p2(3P)5d 4F
145 011.2 144 856 155 3.5 34 5p2(1D)5d 2F + 32 5p2(3P)5d 4D + 17 5p2(3P)5d 2F
145 105.7 145 173 –67 0.5 74 5p2(3P)5d 4D + 13 5s5p42S
145 991.1 146 341 –350 4.5 81 5p2(3P)5d 4F + 16 5p2(1D)5d 2G
146 206.5 146 263 –57 1.5 78 5p2(3P)5d 4D + 8 5p2(3P)5d 4F
148 685.0 148 601 84 2.5 54 5p2(3P)5d 4D + 12 5p2(3P)5d 4F + 12 5p2(3P)5d 2F
150 737.3 150 659 78 0.5 41 5s5p42S + 22 5p2(3P)5d 2P + 14 5p2(1D)5d 2S
155 863.9 155 893 –29 3.5 42 5p2(3P)5d 4D + 20 5p2(3P)5d 2F + 18 5p2(1D)5d 2G
157 205.0 157 289 –84 0.5 69 5p2(3P)6s 4P + 18 5p2(3P)6s 2P + 10 5p2(1S)6s 2S
159 642.8 159 380 263 2.5 71 5p2(3P)5d 4P + 9 5p2(3P)5d 4D + 6 5s5p44P
160 665.1 160 696 –31 3.5 66 5p2(1D)5d 2G + 23 5p2(1D)5d 2F + 7 5p2(3P)5d 4D
161 434.7 161 471 –36 1.5 59 5p2(3P)5d 4P + 15 5p2(1D)5d 2P + 7 5s5p44P
162 866.5 162 752 115 0.5 63 5p2(3P)5d 4P + 13 5p2(1D)5d 2P + 7 5s5p44P
163 463.1 163 608 –145 4.5 81 5p2(1D)5d 2G + 16 5p2(3P)5d 4F
163 596.7 163 137 459 1.5 32 5s5p42P + 30 5p2(3P)5d 2D + 16 5p2(1S)5d 2D
165 280.0 165 268 12 1.5 18 5p2(1D)5d 2P + 17 5s5p42P + 17 5p2(3P)5d 2D
165 995.3 166 060 –65 1.5 80 5p2(3P)6s 4P + 7 5p2(3P)6s 2P
167 206.4 167 606 –399 0.5 65 5p2(3P)6s 2P + 23 5p2(3P)6s 4P
169 001.5 168 667 335 2.5 54 5p2(3P)5d 2D + 15 5p2(3P)5d 2F + 11 5p2(1D)5d 2F
170 490.3 170 444 47 2.5 61 5p2(3P)6s 4P + 29 5p2(1D)6s 2D
172 892.2 172 288 604 0.5 49 5p2(1D)5d 2P + 24 5s5p42P + 11 5p2(3P)5d 4P
173 221.8 172 467 755 1.5 54 5p2(3P)6s 2P + 33 5p2(1D)6s 2D
176 041.9 175 731 311 2.5 27 5p2(1D)5d 2F + 20 5p2(3P)5d 2F + 16 5p2(1D)5d 2D
176 122.2 176 020 102 1.5 55 5p2(1D)5d 2D + 14 5s5p42D + 12 5p2(1D)5d 2P
177 923.3 177 771 153 3.5 57 5p2(3P)5d 2F + 30 5p2(1D)5d 2F + 6 5p2(1D)5d 2G
177 951.1 178 819 –868 0.5 26 5p2(1D)5d 2P + 24 5p2(1D)5d 2S + 19 5s5p42P
179 000.5 178 344 657 2.5 35 5p2(1D)5d 2D + 29 5p2(1S)5d 2D + 10 5p2(3P)5d 2D
182 571.0 184 149 –1578 1.5 33 5p2(1D)6s 2D + 21 5p2(1D)5d 2P + 13 5p2(3P)5d 2P
186 048.6 185 632 417 2.5 65 5p2(1D)6s 2D + 25 5p2(3P)6s 4P
187 546.9 187 664 –117 1.5 29 5p2(1D)6s 2D + 27 5p2(3P)6s 2P + 18 5p2(1D)5d 2P
188 272.6 188 073 200 0.5 36 5p2(1D)5d 2S + 18 5s5p42S + 18 5s5p42P
190 030.5 190 017 14 2.5 42 5p2(1S)5d 2D + 23 5p2(3P)5d 2D + 12 5p2(3P)5d 2F
190 369.3 190 894 –525 1.5 59 5p2(1S)5d 2D + 32 5p2(3P)5d 2D
202 054.6 202 052 3 0.5 86 5p2(1S)6s 2S + 6 5p2(3P)6s 4P

Notes.Energies are given in cm-1.

(a)

From Saloman (2004).

(b)

This work.

(c)

Only the first three components that are larger than 5% are given.

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