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Table B.2

Radial parameters (in cm-1) adopted for the calculations in Xe v.

Configuration Parameter HFR Fitted Ratio Notea

Even parity
5p2 Eav 28 481 29 415
F2(5p,5p) 55 631 50 605 0.910
α 0 –111
ζ 5p 9121 9730 1.067
5p6p Eav 253 537 252 141
ζ 5p 9817 8816 0.898
ζ 6p 2614 2694 1.031
F2(5p,6p) 19 855 17 257 0.869
G0(5p,6p) 4298 3568 0.830
G2(5p,6p) 5684 5510 0.969
5p4f Eav 216 146 210 715
ζ 4f 178 178 1.000 F
ζ 5p 8855 9606 1.085
F2(5p,4f) 48 109 40 305 0.838
G2(5p,4f) 36 992 31 844 0.861
G4(5p,4f) 26 416 20 142 0.762
Odd parity
5s5p3 E av 142 485 142 543
F2(5p,5p) 55 684 47 870 0.860
α 0 100
ζ 5p 9110 9952 1.092
G1(5s,5p) 72 784 55 634 0.764
5p5d E av 184 432 183 499
ζ 5p 9384 10 095 1.076
ζ 5d 608 863 1.418
F2(5p,5d) 43 728 37 678 0.862
G1(5p,5d) 50 314 39 579 0.787
G3(5p,5d) 31 869 25 524 0.801
5p6d E av 307 421 305 556
ζ 5p 9805 9331 0.952
ζ 6d 233 233 1.000 F
F2(5p,6d) 14 535 11 608 0.799
G1(5p,6d) 8677 10 765 1.241
G3(5p,6d) 6311 7518 1.191
5p6s E av 215 033 214 915
ζ 5p 9664 10 297 1.066
G1(5p,6s) 6714 6378 0.950
5p7s E av 317 520 308 416
ζ 5p 9833 10 172 1.034
G1(5p,7s) 2108 2015 0.956
5s5p3–5p5d R1(5p5p;5s5d) 58 429 46 328 0.793
5s5p3–5p6s R1(5p5p;5s6s) –1254 –1129 0.900 F
5p5d–5p6s R2(5p5d;5p6s) –13 325 –12 401 0.931 R
R1(5p5d;5p6s) –5408 –5033 0.931 R

Notes.

(a)

F: Fixed parameter value; R: ratios of these parameters have been fixed in the fitting process.

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