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Table A.8

Comparison between available experimental and calculated energy levels in Zr vii.

Eexp a Ecalc b ΔE J Leading components (in %) in LS couplingc
Even parity
0 2 –2 2 89 4p43P + 9 4p41D
12 557 12 554 3 0 83 4p43P + 14 4p41S
13 549 13 550 –1 1 97 4p43P
27 176 27 176 0 2 88 4p41D + 9 4p43P
56 943 56 943 0 0 84 4p41S + 14 4p43P
480 659 480 829 –170 1 53 4p3(4S)5p 3P + 11 4p3(4S)5p 5P + 8 4p3(2D)5p 3P
483 891 484 629 –738 2 61 4p3(4S)5p 3P + 17 4p3(4S)5p 5P + 7 4p3(2D)5p 3P
485 937 484 685 1252 0 84 4p3(4S)5p 3P + 7 4p3(2P)5p 3P + 6 4p3(2D)5p 3P
492 000 494 297 –2297 1 33 4p3(2D)5p 1P + 30 4p3(2D)5p 3D + 12 4p3(4S)5p 3P
498 029 498 816 –787 2 48 4p3(2D)5p 3F + 27 4p3(2D)5p 3D + 11 4p3(2P)5p 3D
501 798 502 258 –460 3 64 4p3(2D)5p 3F + 14 4p3(2D)5p 3D + 12 4p3(2P)5p 3D
504 480 505 161 –681 3 74 4p3(2D)5p 1F + 17 4p3(2D)5p 3D
504 897 503 622 1275 1 41 4p3(2D)5p 3D + 37 4p3(2D)5p 1P + 12 4p3(2P)5p 3D
506 544 502 353 4191 2 51 4p3(2D)5p 3D + 29 4p3(2D)5p 3F + 7 4p3(2P)5p 1D
507 603 508 524 –921 4 75 4p3(2D)5p 3F + 16 4s4p44d 1G
507 868 507 908 –40 3 64 4p3(2D)5p 3D + 21 4p3(2D)5p 3F + 10 4p3(2D)5p 1F
512 175 513 167 –992 2 57 4p3(2D)5p 3P + 14 4p3(2P)5p 3P + 10 4p3(4S)5p 3P
515 789 515 584 205 0 80 4p3(2D)5p 3P + 11 4p3(2P)5p 1S
522 993 523 937 –944 1 37 4p3(2P)5p 3D + 9 4p3(2P)5p 1P + 8 4s4p44d 3D
524 269 524 312 –43 2 53 4p3(2D)5p 1D + 10 4p3(2D)5p 3P + 6 4s4p44d 3D
527 639 528 353 –714 2 44 4p3(2P)5p 3D + 10 4p3(4S)4f 3F + 7 4s4p44d 1D
530 030 530 023 7 1 61 4p3(2P)5p 3P + 19 4p3(2P)5p 1P
530 591 531 023 –432 0 85 4p3(2P)5p 3P + 6 4p3(4S)5p 3P + 5 4p3(2P)5p 1S
530 672 530 657 15 1 58 4p3(2P)5p 3S + 21 4p3(2D)5p 3P + 6 4p3(2D)5p 1P
534 485 534 639 –154 3 68 4p3(2P)5p 3D + 9 4p3(2D)5p 3F + 8 4p3(2D)5p 1F
537 188 537 174 14 1 22 4s4p44d 3D + 19 4p3(4S)4f 5F + 10 4s4p44d 3D
538 927 537 535 1392 2 63 4p3(2P)5p 1D + 11 4p3(2D)5p 1D + 8 4p3(2D)5p 3F
540 660 542 310 –1650 2 33 4p3(2P)5p 3P + 12 4s4p44d 3P + 9 4s4p44d 3P
542 453 541 036 1417 1 34 4p3(2P)5p 1P + 20 4p3(2P)5p 3P + 10 4p3(2D)5p 3D
556 807 556 867 –60 0 63 4p3(2P)5p 1S + 7 4p3(2D)5p 3P + 5 4s4p44d 3P
Odd parity
192 812 192 785 27 2 86 4s4p53P + 9 4p3(2D)4d 3P
201 981 202 001 –21 1 83 4s4p53P + 9 4p3(2D)4d 3P
208 638 208 552 86 0 85 4s4p53P + 10 4p3(2D)4d 3P
243 704 243 873 –169 1 64 4s4p51P + 27 4p3(2D)4d 1P
262 683 263 032 –349 0 95 4p3(4S)4d 5D
263 119 263 287 –168 1 96 4p3(4S)4d 5D
263 702 263 263 439 2 92 4p3(4S)4d 5D
264 081 263 321 760 3 89 4p3(4S)4d 5D
264 903 264 332 571 4 93 4p3(4S)4d 5D + 5 4p3(2P)4d 3F
275 418 276 399 –981 2 24 4p3(4S)4d 3D + 23 4p3(2D)4d 3D + 23 4p3(2D)4d 3F
280 850 281 217 –367 3 34 4p3(2D)4d 3D + 31 4p3(4S)4d 3D + 12 4p3(2D)4d 3F
282 419 283 129 –710 1 47 4p3(2D)4d 3D + 45 4p3(4S)4d 3D
285 543 285 392 151 2 48 4p3(2D)4d 3F + 23 4p3(2D)4d 3D + 15 4p3(4S)4d 3D
288 053 287 594 459 3 57 4p3(2D)4d 3F + 14 4p3(2D)4d 3D + 12 4p3(2P)4d 3F
289 300 290 371 –1071 0 93 4p3(2D)4d 1S
291 472 290 767 705 4 62 4p3(2D)4d 3F + 16 4p3(2D)4d 3G + 15 4p3(2P)4d 3F
296 679 296 182 497 3 81 4p3(2D)4d 3G + 12 4p3(2D)4d 3F
298 282 298 336 –54 4 67 4p3(2D)4d 3G + 28 4p3(2D)4d 3F
300 720 300 635 85 5 99 4p3(2D)4d 3G
303 437 303 512 –75 4 84 4p3(2D)4d 1G + 7 4p3(2D)4d 3G
311 985 311 104 881 2 53 4p3(2P)4d 1D + 21 4p3(2D)4d 1D + 11 4p3(2P)4d 3F
312 987 313 638 –651 1 51 4p3(2P)4d 3D + 32 4p3(2D)4d 3D + 12 4p3(4S)4d 3D
317 400 319 578 –2178 0 63 4p3(2P)4d 3P + 27 4p3(2D)4d 3P + 6 4p3(2D)4d 1S
320 989 321 259 –270 2 49 4p3(2P)4d 3D + 19 4p3(2D)4d 3D + 12 4p3(4S)4d 3D
322 407 322 588 –181 3 73 4p3(2P)4d 3F + 12 4p3(2D)4d 3F + 8 4p3(2D)4d 3G
323 711 324 292 –581 2 55 4p3(2P)4d 3F + 23 4p3(2D)4d 3F + 6 4p3(2D)4d 3D
323 870 320 328 3542 1 68 4p3(2P)4d 3P + 17 4p3(2D)4d 3P + 6 4p3(2D)4d 3S
324 907 325 653 –746 4 70 4p3(2P)4d 3F + 12 4p3(2D)4d 1G + 8 4p3(2D)4d 3G
328 276 328 706 –430 3 37 4p3(2P)4d 3D + 31 4p3(2D)4d 3D + 11 4p3(2P)4d 1F
330 126 330 701 –575 2 79 4p3(2P)4d 3P + 5 4p3(2P)4d 1D
342 695 340 697 1998 1 83 4p3(2D)4d 3S + 13 4p3(2D)4d 3P
343 828 344 828 –1000 2 82 4p3(2D)4d 3P + 10 4s4p53P
345 215 344 686 529 1 42 4p3(2D)4d 1P + 23 4p3(2D)4d 3P + 20 4s4p51P
346 462 345 598 864 3 51 4p3(2P)4d 1F + 20 4p3(2D)4d 1F + 19 4p3(2P)4d 3D
352 853 353 419 –566 3 42 4p3(4S)4d 3D + 26 4p3(2P)4d 3D + 16 4p3(2D)4d 3D
354 335 354 703 –368 1 35 4p3(2D)4d 3P + 23 4p3(2D)4d 1P + 19 4p3(2P)4d 3P
355 650 355 413 237 0 61 4p3(2D)4d 3P + 24 4p3(2P)4d 3P + 14 4s4p53P
360 177 360 333 –156 2 30 4p3(4S)4d 3D + 27 4p3(2P)4d 3D + 16 4p3(2D)4d 1D
364 897 364 861 36 1 39 4p3(2P)4d 3D + 35 4p3(4S)4d 3D + 15 4p3(2D)4d 3D
371 371 371 578 –207 2 54 4p3(2D)4d 1D + 19 4p3(2P)4d 1D + 11 4p3(2P)4d 3D
380 360 380 849 –489 3 59 4p3(2D)4d 1F + 31 4p3(2P)4d 1F
397 987 397 488 499 1 82 4p3(2P)4d 1P
408 775 408 782 –7 2 91 4p3(4S)5s 5S + 7 4p3(2P)5s 3P
418 375 418 373 2 1 85 4p3(4S)5s 3S + 6 4p3(2P)5s 1P
434 766 434 714 52 2 68 4p3(2D)5s 3D + 15 4p3(2P)5s 3P + 10 4p3(2D)5s 1D
434 815 434 803 12 1 79 4p3(2D)5s 3D + 9 4p3(4S)5s 3S + 6 4p3(2P)5s 1P
439 534 439 566 –32 3 99 4p3(2D)5s 3D
443 204 443 228 –24 2 77 4p3(2D)5s 1D + 19 4p3(2D)5s 3D
456 721 456 722 –1 0 98 4p3(2P)5s 3P
458 043 458 073 –30 1 78 4p3(2P)5s 3P + 18 4p3(2P)5s 1P
466 123 466 108 15 2 73 4p3(2P)5s 3P + 11 4p3(2D)5s 1D + 11 4p3(2D)5s 3D
469 225 469 212 13 1 67 4p3(2P)5s 1P + 14 4p3(2D)5s 3D + 11 4p3(2P)5s 3P

Notes. Energies are given in cm-1.

(b)

This work.

(c)

Only the first three components that are larger than 5% are given.

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