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Table B.6
Calculated thermochemical values of Bromley’s (TiO2)4.
| T | S° | [− G° − H°(Tr)] /T | H° − H°(Tr) | ΔfH° | ΔfG° |
| K | J mol-1 K-1 | J mol-1 K-1 | kJ mol-1 | kJ mol-1 | kJ mol-1 |
|
|
|||||
| 0 | 0.000 | Infinite | –35.788 | –2537.384 | –2537.384 |
| 100 | 308.759 | 607.077 | –30.359 | –2545.814 | –2504.063 |
| 200 | 394.258 | 478.350 | –17.649 | –2552.416 | –2459.498 |
| 298.15 | 465.492 | 461.487 | 0.000 | –2555.647 | –2413.092 |
| 300 | 466.726 | 461.496 | 0.368 | –2555.684 | –2412.209 |
| 400 | 528.034 | 469.604 | 21.742 | –2556.646 | –2364.189 |
| 500 | 580.309 | 485.698 | 45.198 | –2556.389 | –2316.090 |
| 600 | 625.442 | 504.448 | 69.970 | –2555.558 | –2268.102 |
| 700 | 664.942 | 523.821 | 95.602 | –2554.497 | –2220.276 |
| 800 | 699.952 | 542.957 | 121.826 | –2553.318 | –2172.607 |
| 900 | 731.321 | 561.488 | 148.464 | –2552.267 | –2125.085 |
| 1000 | 759.707 | 579.272 | 175.407 | –2551.656 | –2077.659 |
| 1100 | 785.602 | 596.265 | 202.578 | –2551.781 | –2030.260 |
| 1200 | 809.393 | 612.475 | 229.923 | –2568.613 | –1982.337 |
| 1300 | 831.391 | 627.938 | 257.404 | –2567.383 | –1933.533 |
| 1400 | 851.836 | 642.692 | 284.993 | –2566.483 | –1884.806 |
| 1500 | 870.931 | 656.783 | 312.671 | –2565.973 | –1836.137 |
| 1600 | 888.838 | 670.259 | 340.420 | –2565.912 | –1787.490 |
| 1700 | 905.699 | 683.164 | 368.229 | –2566.363 | –1738.834 |
| 1800 | 921.622 | 695.536 | 396.088 | –2567.375 | –1690.116 |
| 1900 | 936.706 | 707.415 | 423.989 | –2569.026 | –1641.344 |
| 2000 | 951.036 | 718.835 | 451.925 | –2630.107 | –1590.643 |
| 2100 | 964.682 | 729.827 | 479.894 | –2636.177 | –1538.521 |
| 2200 | 977.706 | 740.421 | 507.890 | –2642.310 | –1486.118 |
| 2300 | 990.160 | 750.642 | 535.909 | –2648.506 | –1433.417 |
| 2400 | 1002.094 | 760.515 | 563.949 | –2654.774 | –1380.446 |
| 2500 | 1013.548 | 770.062 | 592.006 | –2661.114 | –1327.234 |
| 2600 | 1024.559 | 779.303 | 620.080 | –2667.519 | –1273.739 |
| 2700 | 1035.159 | 788.255 | 648.168 | –2673.992 | –1220.017 |
| 2800 | 1045.379 | 796.937 | 676.271 | –2680.537 | –1166.048 |
| 2900 | 1055.244 | 805.364 | 704.382 | –2687.149 | –1111.836 |
| 3000 | 1064.777 | 813.549 | 732.504 | –2693.832 | –1057.408 |
| 3100 | 1074.003 | 821.506 | 760.639 | –2700.573 | –1002.749 |
| 3200 | 1082.937 | 829.247 | 788.779 | –2707.385 | –947.875 |
| 3300 | 1091.599 | 836.783 | 816.927 | –2714.257 | –892.773 |
| 3400 | 1100.004 | 844.124 | 845.083 | –2721.189 | –837.480 |
| 3500 | 1108.167 | 851.281 | 873.244 | –2728.172 | –781.972 |
| 3600 | 1116.103 | 858.262 | 901.413 | –2735.219 | –726.270 |
| 3700 | 1123.822 | 865.075 | 929.587 | –4378.709 | –639.216 |
| 3800 | 1131.337 | 871.728 | 957.764 | –4380.924 | –538.108 |
| 3900 | 1138.657 | 878.228 | 985.946 | –4383.406 | –436.952 |
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