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Table B.5
Calculated thermochemical values of Jeong’s (TiO2)4.
| T | S° | [− G° − H°(Tr)] /T | H° − H°(Tr) | ΔfH° | ΔfG° |
| K | J mol-1 K-1 | J mol-1 K-1 | kJ mol-1 | kJ mol-1 | kJ mol-1 |
|
|
|||||
| 0 | 0.000 | Infinite | –37.516 | –2418.065 | –2418.065 |
| 100 | 338.217 | 639.899 | –30.724 | –2425.133 | –2386.327 |
| 200 | 427.169 | 510.600 | –17.572 | –2431.294 | –2344.958 |
| 298.15 | 498.118 | 493.833 | 0.000 | –2434.601 | –2301.774 |
| 300 | 499.344 | 493.841 | 0.365 | –2434.640 | –2300.951 |
| 400 | 560.236 | 501.893 | 21.595 | –2435.747 | –2256.171 |
| 500 | 612.225 | 517.880 | 44.925 | –2435.616 | –2211.275 |
| 600 | 657.180 | 536.525 | 69.599 | –2434.882 | –2166.468 |
| 700 | 696.571 | 555.803 | 95.161 | –2433.892 | –2121.812 |
| 800 | 731.500 | 574.856 | 121.324 | –2432.773 | –2077.301 |
| 900 | 762.818 | 593.316 | 147.918 | –2431.767 | –2032.933 |
| 1000 | 791.160 | 611.036 | 174.822 | –2431.196 | –1988.652 |
| 1100 | 817.027 | 627.976 | 201.961 | –2431.352 | –1944.398 |
| 1200 | 840.797 | 644.140 | 229.280 | –2448.210 | –1899.618 |
| 1300 | 862.774 | 659.559 | 256.737 | –2447.004 | –1853.951 |
| 1400 | 883.203 | 674.274 | 284.307 | –2446.122 | –1808.359 |
| 1500 | 902.286 | 688.334 | 311.967 | –2445.630 | –1762.828 |
| 1600 | 920.187 | 701.782 | 339.703 | –2445.583 | –1717.318 |
| 1700 | 937.038 | 714.659 | 367.499 | –2446.046 | –1671.794 |
| 1800 | 952.954 | 727.008 | 395.345 | –2447.072 | –1626.212 |
| 1900 | 968.034 | 738.866 | 423.236 | –2448.734 | –1580.574 |
| 2000 | 982.360 | 750.265 | 451.166 | –2509.820 | –1533.003 |
| 2100 | 996.001 | 761.239 | 479.125 | –2515.901 | –1484.013 |
| 2200 | 1009.021 | 771.817 | 507.113 | –2522.041 | –1434.742 |
| 2300 | 1021.472 | 782.023 | 535.124 | –2528.245 | –1385.174 |
| 2400 | 1033.403 | 791.882 | 563.157 | –2534.521 | –1335.335 |
| 2500 | 1044.855 | 801.416 | 591.210 | –2540.863 | –1285.252 |
| 2600 | 1055.863 | 810.644 | 619.277 | –2547.277 | –1234.887 |
| 2700 | 1066.462 | 819.586 | 647.362 | –2553.752 | –1184.297 |
| 2800 | 1076.680 | 828.257 | 675.457 | –2560.304 | –1133.458 |
| 2900 | 1086.544 | 836.674 | 703.566 | –2566.920 | –1082.375 |
| 3000 | 1096.076 | 844.849 | 731.685 | –2573.605 | –1031.077 |
| 3100 | 1105.299 | 852.797 | 759.812 | –2580.354 | –979.547 |
| 3200 | 1114.233 | 860.530 | 787.949 | –2587.168 | –927.803 |
| 3300 | 1122.894 | 868.058 | 816.095 | –2594.043 | –875.830 |
| 3400 | 1131.298 | 875.392 | 844.248 | –2600.978 | –823.667 |
| 3500 | 1139.460 | 882.542 | 872.406 | –2607.963 | –771.289 |
| 3600 | 1147.394 | 889.516 | 900.570 | –2615.015 | –718.717 |
| 3700 | 1155.113 | 896.323 | 928.742 | –4258.508 | –634.792 |
| 3800 | 1162.627 | 902.970 | 956.918 | –4260.723 | –536.811 |
| 3900 | 1169.947 | 909.465 | 985.098 | –4263.208 | –438.785 |
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