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Table B.3
Calculated thermochemical values of Jeong’s (TiO2)3.
| T | S° | [− G° − H°(Tr)] /T | H° − H°(Tr) | ΔfH° | ΔfG° |
| K | J mol-1 K-1 | J mol-1 K-1 | kJ mol-1 | kJ mol-1 | kJ mol-1 |
|
|
|||||
| 0 | 0.000 | Infinite | –28.116 | –1698.152 | –1698.152 |
| 100 | 302.773 | 526.126 | –22.792 | –1703.223 | –1679.030 |
| 200 | 369.250 | 430.378 | –12.973 | –1707.887 | –1652.910 |
| 298.15 | 421.656 | 418.028 | 0.000 | –1710.575 | –1625.285 |
| 300 | 422.539 | 418.019 | 0.268 | –1710.610 | –1624.752 |
| 400 | 467.293 | 423.942 | 15.869 | –1711.761 | –1595.926 |
| 500 | 505.445 | 435.685 | 32.989 | –1712.040 | –1566.923 |
| 600 | 538.433 | 449.375 | 51.095 | –1711.890 | –1537.909 |
| 700 | 567.344 | 463.526 | 69.857 | –1711.557 | –1508.938 |
| 800 | 592.985 | 477.510 | 89.065 | –1711.132 | –1480.016 |
| 900 | 615.980 | 491.062 | 108.591 | –1710.797 | –1451.151 |
| 1000 | 636.802 | 504.074 | 128.353 | –1710.784 | –1422.308 |
| 1100 | 655.800 | 516.509 | 148.288 | –1711.321 | –1393.438 |
| 1200 | 673.261 | 528.378 | 168.358 | –1724.383 | –1364.136 |
| 1300 | 689.412 | 539.701 | 188.535 | –1723.895 | –1334.137 |
| 1400 | 704.423 | 550.508 | 208.793 | –1723.653 | –1304.160 |
| 1500 | 718.449 | 560.835 | 229.119 | –1723.702 | –1274.201 |
| 1600 | 731.604 | 570.711 | 249.504 | –1724.084 | –1244.227 |
| 1700 | 743.988 | 580.169 | 269.933 | –1724.850 | –1214.217 |
| 1800 | 755.687 | 589.239 | 290.401 | –1726.036 | –1184.139 |
| 1900 | 766.772 | 597.950 | 310.901 | –1727.700 | –1153.998 |
| 2000 | 777.301 | 606.324 | 331.430 | –1773.933 | –1122.384 |
| 2100 | 787.329 | 614.386 | 351.982 | –1778.910 | –1089.683 |
| 2200 | 796.900 | 622.157 | 372.556 | –1783.933 | –1056.754 |
| 2300 | 806.053 | 629.654 | 393.150 | –1789.001 | –1023.580 |
| 2400 | 814.825 | 636.898 | 413.758 | –1794.124 | –990.189 |
| 2500 | 823.242 | 643.902 | 434.378 | –1799.300 | –956.593 |
| 2600 | 831.336 | 650.683 | 455.015 | –1804.524 | –922.773 |
| 2700 | 839.127 | 657.253 | 475.659 | –1809.800 | –888.765 |
| 2800 | 846.639 | 663.625 | 496.314 | –1815.131 | –854.558 |
| 2900 | 853.890 | 669.808 | 516.979 | –1820.509 | –820.149 |
| 3000 | 860.899 | 675.816 | 537.652 | –1825.938 | –785.567 |
| 3100 | 867.679 | 681.657 | 558.331 | –1831.417 | –750.798 |
| 3200 | 874.247 | 687.339 | 579.017 | –1836.945 | –715.854 |
| 3300 | 880.615 | 692.871 | 599.711 | –1842.515 | –680.723 |
| 3400 | 886.793 | 698.260 | 620.408 | –1848.135 | –645.440 |
| 3500 | 892.795 | 703.514 | 641.113 | –1853.788 | –609.983 |
| 3600 | 898.629 | 708.640 | 661.820 | –1859.493 | –574.368 |
| 3700 | 904.303 | 713.642 | 682.530 | –3092.531 | –515.225 |
| 3800 | 909.828 | 718.527 | 703.248 | –3094.607 | –445.532 |
| 3900 | 915.210 | 723.300 | 723.966 | –3096.887 | –375.795 |
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