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Table B.1
Calculated thermochemical values of TiO2.
| T | S° | [− G° − H°(Tr)] /T | H° − H°(Tr) | ΔfH° | ΔfG° |
| K | J mol-1 K-1 | J mol-1 K-1 | kJ mol-1 | kJ mol-1 | kJ mol-1 |
|
|
|||||
| 0 | 0.000 | Infinite | –10.951 | –233.980 | –233.980 |
| 100 | 216.499 | 290.042 | –7.606 | –234.100 | –237.593 |
| 200 | 241.559 | 259.146 | –3.967 | –235.289 | –240.659 |
| 298.15 | 257.636 | 255.419 | 0.000 | –236.542 | –243.021 |
| 300 | 257.903 | 255.423 | 0.079 | –236.564 | –243.062 |
| 400 | 270.656 | 257.122 | 4.521 | –237.706 | –245.051 |
| 500 | 281.296 | 260.447 | 9.294 | –238.733 | –246.767 |
| 600 | 290.446 | 264.291 | 14.317 | –239.695 | –248.283 |
| 700 | 298.456 | 268.248 | 19.515 | –240.640 | –249.639 |
| 800 | 305.569 | 272.154 | 24.842 | –241.574 | –250.861 |
| 900 | 311.956 | 275.932 | 30.267 | –242.546 | –251.964 |
| 1000 | 317.743 | 279.558 | 35.759 | –243.637 | –252.954 |
| 1100 | 323.030 | 283.021 | 41.307 | –244.913 | –253.825 |
| 1200 | 327.894 | 286.329 | 46.897 | –250.368 | –254.454 |
| 1300 | 332.396 | 289.484 | 52.520 | –251.307 | –254.757 |
| 1400 | 336.580 | 292.493 | 58.168 | –252.331 | –254.981 |
| 1500 | 340.492 | 295.369 | 63.839 | –253.452 | –255.133 |
| 1600 | 344.165 | 298.123 | 69.528 | –254.685 | –255.208 |
| 1700 | 347.624 | 300.759 | 75.234 | –256.045 | –255.201 |
| 1800 | 350.891 | 303.287 | 80.949 | –257.547 | –255.106 |
| 1900 | 353.986 | 305.714 | 86.676 | –259.209 | –254.927 |
| 2000 | 356.929 | 308.049 | 92.412 | –275.726 | –254.199 |
| 2100 | 359.731 | 310.298 | 98.154 | –278.494 | –253.057 |
| 2200 | 362.407 | 312.465 | 103.907 | –281.273 | –251.783 |
| 2300 | 364.965 | 314.556 | 109.662 | –284.072 | –250.377 |
| 2400 | 367.418 | 316.577 | 115.425 | –286.886 | –248.851 |
| 2500 | 369.771 | 318.531 | 121.190 | –289.720 | –247.210 |
| 2600 | 372.034 | 320.422 | 126.961 | –292.569 | –245.450 |
| 2700 | 374.213 | 322.256 | 132.735 | –295.435 | –243.586 |
| 2800 | 376.314 | 324.033 | 138.511 | –298.321 | –241.612 |
| 2900 | 378.343 | 325.759 | 144.292 | –301.221 | –239.534 |
| 3000 | 380.303 | 327.436 | 150.074 | –304.141 | –237.360 |
| 3100 | 382.200 | 329.067 | 155.860 | –307.073 | –235.085 |
| 3200 | 384.038 | 330.653 | 161.647 | –310.024 | –232.717 |
| 3300 | 385.819 | 332.197 | 167.436 | –312.990 | –230.252 |
| 3400 | 387.548 | 333.702 | 173.228 | –315.970 | –227.702 |
| 3500 | 389.227 | 335.169 | 179.020 | –318.965 | –225.061 |
| 3600 | 390.859 | 336.600 | 184.814 | –321.974 | –222.336 |
| 3700 | 392.447 | 337.998 | 190.609 | –734.096 | –211.740 |
| 3800 | 393.993 | 339.362 | 196.406 | –735.897 | –197.595 |
| 3900 | 395.499 | 340.695 | 202.205 | –737.763 | –183.406 |
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