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Table B.14
Calculated thermochemical values of Bromley’s (TiO2)10.
| T | S° | [− G° − H°(Tr)] /T | H° − H°(Tr) | ΔfH° | ΔfG° |
| K | J mol-1 K-1 | J mol-1 K-1 | kJ mol-1 | kJ mol-1 | kJ mol-1 |
|
|
|||||
| 0 | 0.000 | Infinite | –88.498 | –7419.038 | –7419.038 |
| 100 | 423.047 | 1189.738 | –77.702 | –7442.892 | –7303.629 |
| 200 | 638.627 | 858.999 | –45.566 | –7459.036 | –7157.337 |
| 298.15 | 822.513 | 815.436 | 0.000 | –7465.671 | –7007.549 |
| 300 | 825.711 | 815.448 | 0.956 | –7465.725 | –7004.706 |
| 400 | 984.759 | 836.484 | 56.406 | –7466.114 | –6850.842 |
| 500 | 1120.484 | 878.242 | 117.310 | –7463.211 | –6697.318 |
| 600 | 1237.652 | 926.913 | 181.616 | –7458.754 | –6544.541 |
| 700 | 1340.160 | 977.199 | 248.136 | –7453.665 | –6392.577 |
| 800 | 1430.969 | 1026.861 | 316.157 | –7448.253 | –6241.349 |
| 900 | 1512.317 | 1074.952 | 385.232 | –7443.149 | –6090.806 |
| 1000 | 1585.899 | 1121.094 | 455.075 | –7439.135 | –5940.774 |
| 1100 | 1653.010 | 1165.178 | 525.491 | –7436.960 | –5791.062 |
| 1200 | 1714.655 | 1207.225 | 596.343 | –7476.548 | –5640.265 |
| 1300 | 1771.643 | 1247.324 | 667.541 | –7470.979 | –5487.469 |
| 1400 | 1824.606 | 1285.584 | 739.010 | –7466.231 | –5335.061 |
| 1500 | 1874.066 | 1322.125 | 810.699 | –7462.462 | –5182.980 |
| 1600 | 1920.450 | 1357.066 | 882.570 | –7459.811 | –5031.122 |
| 1700 | 1964.108 | 1390.519 | 954.587 | –7458.444 | –4879.388 |
| 1800 | 2005.346 | 1422.593 | 1026.733 | –7458.478 | –4727.655 |
| 1900 | 2044.409 | 1453.384 | 1098.982 | –7460.109 | –4575.926 |
| 2000 | 2081.514 | 1482.983 | 1171.322 | –7610.309 | –4419.497 |
| 2100 | 2116.848 | 1511.472 | 1243.741 | –7622.990 | –4259.646 |
| 2200 | 2150.567 | 1538.926 | 1316.226 | –7635.825 | –4099.208 |
| 2300 | 2182.813 | 1565.415 | 1388.769 | –7648.822 | –3938.147 |
| 2400 | 2213.710 | 1591.000 | 1461.364 | –7661.997 | –3776.516 |
| 2500 | 2243.362 | 1615.738 | 1534.003 | –7675.347 | –3614.378 |
| 2600 | 2271.869 | 1639.683 | 1606.685 | –7688.866 | –3451.643 |
| 2700 | 2299.311 | 1662.879 | 1679.401 | –7702.550 | –3288.431 |
| 2800 | 2325.770 | 1685.374 | 1752.151 | –7716.420 | –3124.699 |
| 2900 | 2351.308 | 1707.206 | 1824.927 | –7730.454 | –2960.440 |
| 3000 | 2375.989 | 1728.412 | 1897.730 | –7744.661 | –2795.737 |
| 3100 | 2399.868 | 1749.026 | 1970.556 | –7759.025 | –2630.535 |
| 3200 | 2422.996 | 1769.079 | 2043.403 | –7773.558 | –2464.874 |
| 3300 | 2445.419 | 1788.602 | 2116.271 | –7788.240 | –2298.719 |
| 3400 | 2467.177 | 1807.619 | 2189.155 | –7803.076 | –2132.170 |
| 3500 | 2488.308 | 1826.158 | 2262.054 | –7818.036 | –1965.155 |
| 3600 | 2508.849 | 1844.241 | 2334.970 | –7833.161 | –1797.722 |
| 3700 | 2528.831 | 1861.888 | 2407.898 | –11939.393 | –1551.978 |
| 3800 | 2548.284 | 1879.122 | 2480.840 | –11942.431 | –1271.170 |
| 3900 | 2567.123 | 1895.851 | 2553.792 | –11946.139 | –989.881 |
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