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Table B.13
Calculated thermochemical values of Bromley’s (TiO2)9.
| T | S° | [− G° − H°(Tr)] /T | H° − H°(Tr) | ΔfH° | ΔfG° |
| K | J mol-1 K-1 | J mol-1 K-1 | kJ mol-1 | kJ mol-1 | kJ mol-1 |
|
|
|||||
| 0 | 0.000 | Infinite | –77.878 | –6578.040 | –6578.040 |
| 100 | 405.981 | 1079.088 | –68.247 | –6599.595 | –6476.782 |
| 200 | 592.208 | 787.536 | –40.433 | –6615.232 | –6347.192 |
| 298.15 | 755.288 | 748.789 | 0.000 | –6621.779 | –6213.950 |
| 300 | 758.139 | 748.796 | 0.853 | –6621.835 | –6211.418 |
| 400 | 900.586 | 767.617 | 50.522 | –6622.422 | –6074.398 |
| 500 | 1022.480 | 805.054 | 105.220 | –6619.925 | –5937.643 |
| 600 | 1127.792 | 848.731 | 163.017 | –6615.992 | –5801.544 |
| 700 | 1219.931 | 893.873 | 222.810 | –6611.486 | –5666.158 |
| 800 | 1301.549 | 938.472 | 283.945 | –6606.700 | –5531.427 |
| 900 | 1374.650 | 981.664 | 346.020 | –6602.199 | –5397.299 |
| 1000 | 1440.767 | 1023.110 | 408.777 | –6598.688 | –5263.621 |
| 1100 | 1501.058 | 1062.709 | 472.039 | –6596.843 | –5130.219 |
| 1200 | 1556.442 | 1100.482 | 535.691 | –6632.586 | –4995.836 |
| 1300 | 1607.630 | 1136.502 | 599.643 | –6627.701 | –4859.639 |
| 1400 | 1655.201 | 1170.870 | 663.837 | –6623.556 | –4723.781 |
| 1500 | 1699.622 | 1203.693 | 728.224 | –6620.296 | –4588.208 |
| 1600 | 1741.279 | 1235.079 | 792.770 | –6618.049 | –4452.828 |
| 1700 | 1780.489 | 1265.129 | 857.446 | –6616.957 | –4317.552 |
| 1800 | 1817.521 | 1293.938 | 922.236 | –6617.130 | –4182.266 |
| 1900 | 1852.598 | 1321.594 | 987.114 | –6618.743 | –4046.975 |
| 2000 | 1885.919 | 1348.181 | 1052.074 | –6754.069 | –3907.450 |
| 2100 | 1917.646 | 1373.770 | 1117.103 | –6765.631 | –3764.836 |
| 2200 | 1947.924 | 1398.428 | 1182.189 | –6777.333 | –3621.687 |
| 2300 | 1976.878 | 1422.219 | 1247.325 | –6789.183 | –3477.971 |
| 2400 | 2004.619 | 1445.198 | 1312.508 | –6801.192 | –3333.733 |
| 2500 | 2031.245 | 1467.417 | 1377.731 | –6813.361 | –3189.036 |
| 2600 | 2056.840 | 1488.921 | 1442.990 | –6825.681 | –3043.790 |
| 2700 | 2081.481 | 1509.756 | 1508.279 | –6838.153 | –2898.117 |
| 2800 | 2105.234 | 1529.958 | 1573.596 | –6850.794 | –2751.961 |
| 2900 | 2128.164 | 1549.564 | 1638.939 | –6863.579 | –2605.329 |
| 3000 | 2150.324 | 1568.609 | 1704.304 | –6876.524 | –2458.293 |
| 3100 | 2171.763 | 1587.121 | 1769.689 | –6889.609 | –2310.802 |
| 3200 | 2192.529 | 1605.131 | 1835.096 | –6902.845 | –2162.894 |
| 3300 | 2212.660 | 1622.663 | 1900.515 | –6916.220 | –2014.534 |
| 3400 | 2232.195 | 1639.743 | 1965.953 | –6929.730 | –1865.818 |
| 3500 | 2232.468 | 1656.391 | 1965.953 | –7008.804 | –1716.677 |
| 3600 | 2269.609 | 1672.630 | 2096.866 | –6957.128 | –1567.153 |
| 3700 | 2287.548 | 1688.478 | 2162.340 | –10652.897 | –1347.146 |
| 3800 | 2305.012 | 1703.953 | 2227.828 | –10655.792 | –1095.574 |
| 3900 | 2322.026 | 1719.074 | 2293.324 | –10659.290 | –843.954 |
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