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Table B.12

Calculated thermochemical values of Bromley’s (TiO2)8.

T S° [− G° − H°(Tr)] /T H° − H°(Tr) ΔfH° ΔfG°
K J mol-1 K-1 J mol-1 K-1 kJ mol-1 kJ mol-1 kJ mol-1

0 0.000 Infinite –70.471 –5781.203 –5781.203
100 385.397 992.932 –61.615 –5800.067 –5693.352
200 556.199 730.611 –36.151 –5813.226 –5580.927
298.15 702.091 696.050 0.000 –5818.836 –5465.481
300 704.623 696.053 0.759 –5818.885 –5463.286
400 830.859 712.748 44.770 –5819.546 –5344.548
500 938.627 745.900 93.126 –5817.589 –5225.994
600 1031.694 784.543 144.206 –5814.390 –5107.963
700 1113.133 824.468 197.057 –5810.683 –4990.516
800 1185.301 863.912 251.113 –5806.714 –4873.611
900 1249.962 902.113 306.018 –5802.986 –4757.210
1000 1308.454 938.768 361.539 –5800.128 –4641.175
1100 1361.811 973.793 417.523 –5798.737 –4525.362
1200 1410.825 1007.202 473.858 –5830.754 –4408.649
1300 1456.140 1039.067 530.472 –5826.644 –4290.310
1400 1498.256 1069.472 587.303 –5823.188 –4172.253
1500 1537.585 1098.511 644.311 –5820.517 –4054.431
1600 1574.473 1126.282 701.465 –5818.738 –3936.768
1700 1609.195 1152.871 758.741 –5817.983 –3819.182
1800 1641.989 1178.365 816.116 –5818.352 –3701.575
1900 1673.057 1202.840 873.577 –5819.994 –3583.954
2000 1702.567 1226.369 931.110 –5940.494 –3462.555
2100 1730.669 1249.016 988.708 –5950.976 –3338.402
2200 1757.488 1270.841 1046.359 –5961.581 –3213.763
2300 1783.137 1291.900 1104.057 –5972.315 –3088.613
2400 1807.709 1312.239 1161.794 –5983.194 –2962.988
2500 1831.294 1331.907 1219.571 –5994.209 –2836.945
2600 1853.967 1350.943 1277.379 –6005.361 –2710.410
2700 1875.795 1369.386 1335.216 –6016.643 –2583.482
2800 1896.839 1387.271 1393.080 –6028.076 –2456.124
2900 1917.152 1404.628 1450.967 –6039.637 –2328.332
3000 1936.784 1421.489 1508.875 –6051.337 –2200.176
3100 1955.777 1437.879 1566.798 –6063.165 –2071.608
3200 1974.174 1453.824 1624.743 –6075.124 –1942.663
3300 1992.008 1469.346 1682.701 –6087.207 –1813.310
3400 2009.315 1484.468 1740.675 –6099.409 –1683.635
3500 2026.123 1499.209 1798.659 –6111.713 –1553.574
3600 1986.305 1457.914 1856.656 –6124.147 –1221.008
3700 2058.356 1527.620 1914.667 –9409.465 –1230.110
3800 2073.828 1541.324 1972.685 –9412.231 –1008.987
3900 2088.901 1554.712 2030.714 –9415.530 –787.814

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