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Table B.11
Calculated thermochemical values of Bromley’s (TiO2)7.
| T | S° | [− G° − H°(Tr)] /T | H° − H°(Tr) | ΔfH° | ΔfG° |
| K | J mol-1 K-1 | J mol-1 K-1 | kJ mol-1 | kJ mol-1 | kJ mol-1 |
|
|
|||||
| 0 | 0.000 | Infinite | –61.739 | –4969.371 | –4969.371 |
| 100 | 369.513 | 898.759 | –53.705 | –4985.592 | –4895.446 |
| 200 | 518.536 | 670.197 | –31.495 | –4997.179 | –4800.289 |
| 298.15 | 645.627 | 640.072 | 0.000 | –5002.223 | –4702.369 |
| 300 | 647.833 | 640.081 | 0.659 | –5002.271 | –4700.509 |
| 400 | 757.877 | 654.632 | 39.025 | –5002.993 | –4599.720 |
| 500 | 851.828 | 683.529 | 81.183 | –5001.435 | –4499.055 |
| 600 | 932.963 | 717.214 | 125.714 | –4998.799 | –4398.814 |
| 700 | 1003.969 | 752.025 | 171.792 | –4995.723 | –4299.061 |
| 800 | 1066.875 | 786.410 | 218.912 | –4992.430 | –4199.754 |
| 900 | 1123.238 | 819.711 | 266.772 | –4989.349 | –4100.863 |
| 1000 | 1174.221 | 851.664 | 315.165 | –4987.036 | –4002.275 |
| 1100 | 1220.726 | 882.197 | 363.960 | –4986.009 | –3903.862 |
| 1200 | 1263.445 | 911.320 | 413.059 | –5014.218 | –3804.644 |
| 1300 | 1302.939 | 939.096 | 462.400 | –5010.818 | –3703.986 |
| 1400 | 1339.642 | 965.598 | 511.930 | –5007.992 | –3603.559 |
| 1500 | 1373.922 | 990.912 | 561.615 | –5005.851 | –3503.328 |
| 1600 | 1406.068 | 1015.117 | 611.426 | –5004.494 | –3403.218 |
| 1700 | 1436.331 | 1038.294 | 661.342 | –5004.033 | –3303.167 |
| 1800 | 1464.911 | 1060.515 | 711.345 | –5004.556 | –3203.083 |
| 1900 | 1491.984 | 1081.847 | 761.421 | –5006.196 | –3102.974 |
| 2000 | 1517.703 | 1102.356 | 811.560 | –5111.835 | –2999.553 |
| 2100 | 1542.192 | 1122.094 | 861.755 | –5121.211 | –2893.707 |
| 2200 | 1565.565 | 1141.118 | 911.996 | –5130.693 | –2787.432 |
| 2300 | 1587.916 | 1159.472 | 962.277 | –5140.290 | –2680.695 |
| 2400 | 1609.331 | 1177.199 | 1012.595 | –5150.012 | –2573.536 |
| 2500 | 1629.885 | 1194.341 | 1062.947 | –5159.853 | –2466.002 |
| 2600 | 1649.644 | 1210.932 | 1113.325 | –5169.815 | –2358.031 |
| 2700 | 1668.665 | 1227.007 | 1163.726 | –5179.893 | –2249.708 |
| 2800 | 1687.004 | 1242.594 | 1214.152 | –5190.102 | –2140.998 |
| 2900 | 1704.705 | 1257.722 | 1264.596 | –5200.425 | –2031.906 |
| 3000 | 1721.814 | 1272.417 | 1315.060 | –5210.867 | –1922.486 |
| 3100 | 1738.366 | 1286.702 | 1365.541 | –5221.420 | –1812.697 |
| 3200 | 1754.397 | 1300.599 | 1416.034 | –5232.092 | –1702.573 |
| 3300 | 1769.939 | 1314.128 | 1466.541 | –5242.870 | –1592.087 |
| 3400 | 1785.022 | 1327.307 | 1517.064 | –5253.752 | –1481.311 |
| 3500 | 1799.669 | 1340.154 | 1567.594 | –5264.723 | –1370.193 |
| 3600 | 1813.907 | 1352.685 | 1618.135 | –5275.811 | –1258.767 |
| 3700 | 1827.757 | 1364.915 | 1668.686 | –8150.672 | –1092.511 |
| 3800 | 1841.241 | 1376.858 | 1719.248 | –8153.296 | –901.696 |
| 3900 | 1854.376 | 1388.527 | 1769.815 | –8156.391 | –710.831 |
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