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Table B.11

Calculated thermochemical values of Bromley’s (TiO2)7.

T S° [− G° − H°(Tr)] /T H° − H°(Tr) ΔfH° ΔfG°
K J mol-1 K-1 J mol-1 K-1 kJ mol-1 kJ mol-1 kJ mol-1

0 0.000 Infinite –61.739 –4969.371 –4969.371
100 369.513 898.759 –53.705 –4985.592 –4895.446
200 518.536 670.197 –31.495 –4997.179 –4800.289
298.15 645.627 640.072 0.000 –5002.223 –4702.369
300 647.833 640.081 0.659 –5002.271 –4700.509
400 757.877 654.632 39.025 –5002.993 –4599.720
500 851.828 683.529 81.183 –5001.435 –4499.055
600 932.963 717.214 125.714 –4998.799 –4398.814
700 1003.969 752.025 171.792 –4995.723 –4299.061
800 1066.875 786.410 218.912 –4992.430 –4199.754
900 1123.238 819.711 266.772 –4989.349 –4100.863
1000 1174.221 851.664 315.165 –4987.036 –4002.275
1100 1220.726 882.197 363.960 –4986.009 –3903.862
1200 1263.445 911.320 413.059 –5014.218 –3804.644
1300 1302.939 939.096 462.400 –5010.818 –3703.986
1400 1339.642 965.598 511.930 –5007.992 –3603.559
1500 1373.922 990.912 561.615 –5005.851 –3503.328
1600 1406.068 1015.117 611.426 –5004.494 –3403.218
1700 1436.331 1038.294 661.342 –5004.033 –3303.167
1800 1464.911 1060.515 711.345 –5004.556 –3203.083
1900 1491.984 1081.847 761.421 –5006.196 –3102.974
2000 1517.703 1102.356 811.560 –5111.835 –2999.553
2100 1542.192 1122.094 861.755 –5121.211 –2893.707
2200 1565.565 1141.118 911.996 –5130.693 –2787.432
2300 1587.916 1159.472 962.277 –5140.290 –2680.695
2400 1609.331 1177.199 1012.595 –5150.012 –2573.536
2500 1629.885 1194.341 1062.947 –5159.853 –2466.002
2600 1649.644 1210.932 1113.325 –5169.815 –2358.031
2700 1668.665 1227.007 1163.726 –5179.893 –2249.708
2800 1687.004 1242.594 1214.152 –5190.102 –2140.998
2900 1704.705 1257.722 1264.596 –5200.425 –2031.906
3000 1721.814 1272.417 1315.060 –5210.867 –1922.486
3100 1738.366 1286.702 1365.541 –5221.420 –1812.697
3200 1754.397 1300.599 1416.034 –5232.092 –1702.573
3300 1769.939 1314.128 1466.541 –5242.870 –1592.087
3400 1785.022 1327.307 1517.064 –5253.752 –1481.311
3500 1799.669 1340.154 1567.594 –5264.723 –1370.193
3600 1813.907 1352.685 1618.135 –5275.811 –1258.767
3700 1827.757 1364.915 1668.686 –8150.672 –1092.511
3800 1841.241 1376.858 1719.248 –8153.296 –901.696
3900 1854.376 1388.527 1769.815 –8156.391 –710.831

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