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Table B.10

Calculated thermochemical values of Bromley’s (TiO2)6.

T S° [− G° − H°(Tr)] /T H° − H°(Tr) ΔfH° ΔfG°
K J mol-1 K-1 J mol-1 K-1 kJ mol-1 kJ mol-1 kJ mol-1

0 0.000 Infinite –53.636 –4180.234 –4180.234
100 346.986 805.262 –46.526 –4193.914 –4119.672
200 477.697 607.766 –27.069 –4203.425 –4041.310
298.15 586.971 581.920 0.000 –4207.676 –3960.669
300 588.865 581.932 0.564 –4207.717 –3959.137
400 682.794 594.355 33.312 –4208.473 –3876.085
500 762.844 619.008 69.232 –4207.354 –3793.095
600 831.946 647.730 107.157 –4205.339 –3710.424
700 892.411 677.396 146.395 –4202.959 –3628.126
800 945.994 706.696 186.531 –4200.389 –3546.176
900 994.002 735.073 227.295 –4198.007 –3464.552
1000 1037.435 762.296 268.523 –4196.277 –3383.155
1100 1077.054 788.310 310.093 –4195.651 –3301.886
1200 1113.455 813.123 351.930 –4220.078 –3219.903
1300 1147.107 836.789 393.972 –4217.414 –3136.665
1400 1178.382 859.369 436.177 –4215.241 –3053.605
1500 1207.595 880.937 478.518 –4213.651 –2970.696
1600 1234.991 901.562 520.967 –4212.734 –2887.875
1700 1260.779 921.309 563.506 –4212.586 –2805.086
1800 1285.137 940.243 606.120 –4213.280 –2722.258
1900 1308.212 958.420 648.800 –4214.927 –2639.394
2000 1330.131 975.894 691.533 –4305.719 –2553.676
2100 1351.003 992.715 734.313 –4313.999 –2465.871
2200 1370.924 1008.924 777.135 –4322.369 –2377.683
2300 1389.976 1024.565 819.993 –4330.834 –2289.092
2400 1408.228 1039.671 862.881 –4339.409 –2200.126
2500 1425.747 1054.278 905.797 –4348.086 –2110.829
2600 1442.589 1068.417 948.737 –4356.866 –2021.148
2700 1458.802 1082.115 991.698 –4365.745 –1931.156
2800 1474.433 1095.398 1034.678 –4374.738 –1840.824
2900 1489.522 1108.290 1077.678 –4383.824 –1750.153
3000 1504.105 1120.814 1120.692 –4393.016 –1659.197
3100 1518.213 1132.987 1163.719 –4402.303 –1567.914
3200 1531.878 1144.829 1206.761 –4411.689 –1476.335
3300 1545.126 1156.359 1249.814 –4421.166 –1384.441
3400 1557.982 1167.591 1292.877 –4430.734 –1292.290
3500 1570.467 1178.539 1335.949 –4440.379 –1199.839
3600 1582.604 1189.219 1379.033 –4450.119 –1107.117
3700 1594.411 1199.641 1422.123 –6914.525 –967.391
3800 1605.904 1209.820 1465.220 –6917.016 –806.608
3900 1617.101 1219.765 1508.326 –6919.906 –645.777

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