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Table B.8
Calculated thermochemical values of Bromley’s (TiO2)5.
| T | S° | [− G° − H°(Tr)] /T | H° − H°(Tr) | ΔfH° | ΔfG° |
| K | J mol-1 K-1 | J mol-1 K-1 | kJ mol-1 | kJ mol-1 | kJ mol-1 |
|
|
|||||
| 0 | 0.000 | Infinite | –44.169 | –3311.595 | –3311.595 |
| 100 | 327.321 | 701.588 | –38.036 | –3322.786 | –3264.734 |
| 200 | 433.260 | 539.830 | –22.251 | –3331.142 | –3203.082 |
| 298.15 | 523.066 | 518.565 | 0.000 | –3334.991 | –3139.266 |
| 300 | 524.619 | 518.569 | 0.465 | –3335.031 | –3138.051 |
| 400 | 602.139 | 528.820 | 27.492 | –3335.924 | –3072.192 |
| 500 | 668.268 | 549.172 | 57.165 | –3335.251 | –3006.317 |
| 600 | 725.382 | 572.892 | 88.511 | –3333.830 | –2940.657 |
| 700 | 775.363 | 597.397 | 120.946 | –3332.109 | –2875.263 |
| 800 | 819.661 | 621.607 | 154.127 | –3330.233 | –2810.122 |
| 900 | 859.352 | 645.053 | 187.831 | –3328.515 | –2745.218 |
| 1000 | 895.264 | 667.553 | 221.918 | –3327.343 | –2680.477 |
| 1100 | 928.023 | 689.052 | 256.291 | –3327.090 | –2615.812 |
| 1200 | 958.119 | 709.560 | 290.882 | –3347.719 | –2550.528 |
| 1300 | 985.946 | 729.121 | 325.646 | –3345.770 | –2484.176 |
| 1400 | 1011.808 | 747.784 | 360.547 | –3344.229 | –2417.951 |
| 1500 | 1035.961 | 765.613 | 395.555 | –3343.181 | –2351.832 |
| 1600 | 1058.615 | 782.662 | 430.655 | –3342.690 | –2285.770 |
| 1700 | 1079.831 | 798.879 | 465.832 | –3342.839 | –2219.531 |
| 1800 | 1100.080 | 814.638 | 501.069 | –3343.692 | –2153.613 |
| 1900 | 1119.162 | 829.666 | 536.361 | –3345.340 | –2087.468 |
| 2000 | 1137.286 | 844.112 | 571.697 | –3421.273 | –2018.926 |
| 2100 | 1154.547 | 858.018 | 607.073 | –3428.447 | –1948.635 |
| 2200 | 1171.018 | 871.419 | 642.481 | –3435.700 | –1878.008 |
| 2300 | 1186.771 | 884.349 | 677.920 | –3443.031 | –1807.033 |
| 2400 | 1201.859 | 896.838 | 713.369 | –3450.467 | –1735.735 |
| 2500 | 1216.352 | 908.915 | 748.871 | –3457.960 | –1664.152 |
| 2600 | 1230.275 | 920.604 | 784.371 | –3465.560 | –1592.233 |
| 2700 | 1243.686 | 931.929 | 819.904 | –3473.227 | –1520.048 |
| 2800 | 1256.611 | 942.911 | 855.446 | –3480.995 | –1447.568 |
| 2900 | 1269.088 | 953.570 | 891.003 | –3488.843 | –1374.794 |
| 3000 | 1281.146 | 963.923 | 926.570 | –3496.780 | –1301.773 |
| 3100 | 1292.813 | 973.989 | 962.151 | –3504.795 | –1228.474 |
| 3200 | 1304.113 | 983.780 | 997.742 | –3512.893 | –1154.918 |
| 3300 | 1315.068 | 993.313 | 1033.344 | –3521.067 | –1081.090 |
| 3400 | 1325.699 | 1002.599 | 1068.954 | –3529.317 | –1007.040 |
| 3500 | 1336.023 | 1011.651 | 1104.571 | –3537.629 | –932.730 |
| 3600 | 1346.059 | 1020.481 | 1140.197 | –3546.024 | –858.190 |
| 3700 | 1355.822 | 1029.099 | 1175.830 | –5599.971 | –744.469 |
| 3800 | 1365.327 | 1037.515 | 1211.469 | –5602.322 | –613.195 |
| 3900 | 1374.585 | 1045.737 | 1247.112 | –5605.009 | –481.871 |
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