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Table B.7
Calculated thermochemical values of Jeong’s (TiO2)5.
| T | S° | [−G° − H°(Tr)] /T | H° − H°(Tr) | ΔfH° | ΔfG° |
| K | J mol-1 K-1 | J mol-1 K-1 | kJ mol-1 | kJ mol-1 | kJ mol-1 |
|
|
|||||
| 0 | 0.000 | Infinite | –47.010 | –3133.685 | –3133.685 |
| 100 | 385.397 | 765.646 | –38.689 | –3142.690 | –3090.446 |
| 200 | 496.994 | 602.678 | –22.183 | –3150.324 | –3035.010 |
| 298.15 | 586.566 | 581.519 | 0.000 | –3154.241 | –2977.448 |
| 300 | 588.103 | 581.516 | 0.462 | –3154.284 | –2976.349 |
| 400 | 665.170 | 591.713 | 27.329 | –3155.337 | –2916.817 |
| 500 | 731.013 | 611.949 | 56.876 | –3154.790 | –2857.228 |
| 600 | 787.947 | 635.557 | 88.125 | –3153.466 | –2797.832 |
| 700 | 837.816 | 659.964 | 120.487 | –3151.819 | –2738.690 |
| 800 | 882.040 | 684.087 | 153.613 | –3149.998 | –2679.790 |
| 900 | 921.682 | 707.462 | 187.272 | –3148.324 | –2621.124 |
| 1000 | 957.554 | 729.897 | 221.322 | –3147.189 | –2562.613 |
| 1100 | 990.284 | 751.339 | 255.666 | –3146.965 | –2504.173 |
| 1200 | 1020.361 | 771.802 | 290.233 | –3167.618 | –2445.117 |
| 1300 | 1048.166 | 791.318 | 324.974 | –3165.692 | –2384.985 |
| 1400 | 1074.017 | 809.947 | 359.856 | –3164.170 | –2324.984 |
| 1500 | 1098.159 | 827.743 | 394.849 | –3163.137 | –2265.085 |
| 1600 | 1120.803 | 844.761 | 429.936 | –3162.660 | –2205.240 |
| 1700 | 1142.122 | 861.061 | 465.099 | –3162.821 | –2145.408 |
| 1800 | 1162.256 | 876.689 | 500.326 | –3163.685 | –2085.523 |
| 1900 | 1181.331 | 891.694 | 535.607 | –3165.344 | –2025.593 |
| 2000 | 1199.453 | 906.121 | 570.936 | –3241.285 | –1963.271 |
| 2100 | 1216.709 | 920.008 | 606.304 | –3248.467 | –1899.194 |
| 2200 | 1233.178 | 933.393 | 641.706 | –3255.725 | –1834.784 |
| 2300 | 1248.927 | 946.307 | 677.137 | –3263.064 | –1770.024 |
| 2400 | 1264.018 | 958.782 | 712.597 | –3270.489 | –1704.940 |
| 2500 | 1278.503 | 970.846 | 748.078 | –3278.003 | –1639.572 |
| 2600 | 1292.427 | 982.523 | 783.580 | –3285.601 | –1573.871 |
| 2700 | 1305.832 | 993.836 | 819.101 | –3293.280 | –1507.897 |
| 2800 | 1318.757 | 1004.808 | 854.640 | –3301.051 | –1441.632 |
| 2900 | 1331.232 | 1015.457 | 890.189 | –3308.907 | –1375.075 |
| 3000 | 1343.290 | 1025.801 | 925.756 | –3316.844 | –1308.268 |
| 3100 | 1354.955 | 1035.858 | 961.332 | –3324.864 | –1241.184 |
| 3200 | 1366.253 | 1045.641 | 996.918 | –3332.968 | –1173.840 |
| 3300 | 1377.207 | 1055.166 | 1032.517 | –3341.144 | –1106.227 |
| 3400 | 1387.837 | 1064.444 | 1068.124 | –3349.397 | –1038.389 |
| 3500 | 1398.161 | 1073.490 | 1103.739 | –3357.712 | –970.295 |
| 3600 | 1408.196 | 1082.314 | 1139.362 | –3366.109 | –901.967 |
| 3700 | 1417.959 | 1090.925 | 1174.992 | –5420.059 | –794.461 |
| 3800 | 1427.462 | 1099.335 | 1210.628 | –5422.413 | –669.399 |
| 3900 | 1436.720 | 1107.551 | 1246.270 | –5425.102 | –544.289 |
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