Energies and E1, M1, E2, and M2 transition rates for states of the 2s22p4, 2s2p5, and 2p6 configurations in oxygen-like ions between F II and Kr XXIX

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Table 3

Comparison of fully relativistic theoretical energy levels with values derived from observed and semi-empirical (SE) wavelengths.

Level	J	Obs.(NIST)^a	SE(Edlén)^b	Calc.^c	Diff.(1)^c	Diff.(2)^c	Calc.^d	Diff.(1)^d	Diff.(2)^d

		Zn XXIII

2s²2p⁴ ³P	2	0	0	0	0	0	0	0	0
	0	110 340	110 437	110 316	−24	−121	110 445	105	8
	1	179 060	178 973	178 931	−129	−42	179 045	−15	72
2s²2p⁴ ¹D	2	267 120	267 325	267 392	272	67	267 408	288	83
2s²2p⁴ ¹S	0	512 070	512 557	512 589	519	32	512 752	682	195
2s2p⁵ ³P^o	2	1 176 110	1 176 226	1 176 299	189	73	1 177 520	1410	1294
	1	1 282 970	1 282 957	1 283 062	92	105	1 284 376	1406	1419
	0	1 380 580	1 380 576	1 380 638	58	62	1 381 930	1350	1354
2s2p⁵ ¹P^o	1	1 626 230	1 626 251	1 626 838	608	587	1 627 985	1755	1734
2p⁶ ¹S	0	2 697 570	2 697 367	2 698 417	847	1050	2 702 031	4461	4664

		Ge XXV

2s²2p⁴ ³P	2	0	0	0	0	0	0	0	0
	0	127 240	127 793	127 284	44	−509	127 401	161	−392
	1	243 540	243 568	243 506	−34	−62	243 652	112	84
2s²2p⁴ ¹D	2	336 200	336 229	336 244	44	15	336 308	108	79
2s²2p⁴ ¹S	0	646 650	646 933	646 798	148	−135	647 012	362	79
2s2p⁵ ³P^o	2	1 324 130	1 324 308	1 324 243	113	−65	1 325 473	1343	1165
	1	1 457 310	1 457 440	1 457 479	169	39	1 458 828	1518	1388
	0	1 596 720	1 597 034	1 596 934	214	−100	1 598 310	1590	1276
2s2p⁵ ¹P^o	1	1 842 920	1 842 732	1 843 400	480	668	1 844 637	1717	1905
2p⁶ ¹S	0	3 021 850	3 021 332	3 022 627	777	1295	3 026 366	4516	5034

		As XXVI

2s²2p⁴ ³P	2	0	0	0	0	0
	0	137 320	136 385	135 600	−1720	−785
	1	281 330	281 802	281 734	404	−68
2s²2p⁴ ¹D	2	377 300	376 598	376 586	−714	−12
2s²2p⁴ ¹S	0	726 580	726 315	726 071	−509	−244
2s2p⁵ ³P^o	2	1 403 750	1 404 724	1 404 572	822	−152
	1	1 550 530	1 551 663	1 551 701	1171	38
	0	1 716 190	1 717 549	1 717 342	1152	−207
2s2p⁵ ¹P^o	1	1 962 370	1 962 613	1 963 325	955	712
2p⁶ ¹S	0		3 195 915	3 197 391		1476

		Se XXVII

2s²2p⁴ ³P	2	0	0	0	0	0
	0	147 760	144 941	143 818	−3942	−1123
	1	323 690	324 396	324 328	638	−68
2s²2p⁴ ¹D	2	422 380	421 316	421 279	−1101	−37
2s²2p⁴ ¹S	0	814 600	814 628	814 253	−347	−375
2s2p⁵ ³P^o	2	1 488 420	1 489 811	1 489 560	1140	−251
	1	1 649 100	1 650 791	1 650 866	1766	75
	0	1 845 030	1 847 080	1 846 742	1712	−338
2s2p⁵ ¹P^o	1	2 090 120	2 091 234	2 091 988	1868	754
2p⁶ ¹S	0		3 379 728	3 381 432		1704

		Br XXVIII

2s²2p⁴ ³P	2	0	0	0	0	0	0	0	0
	0	218 800	153 478	151 954	−66 846	−1524	152 035	−66 765	−1443
	1	379 800	371 663	371 606	−8 194	−57	371 858	−7942	195
2s²2p⁴ ¹D	2	483 040	470 699	470 643	−12 397	−56	470 804	−12 236	105
2s²2p⁴ ¹S	0	944 150	912 501	911 968	−32 182	−533	912 282	−31 868	−219
2s2p⁵ ³P^o	2		1 579 903	1 579 537		−366	1 580 945		1042
	1		1 755 028	1 755 196		168	1 756 684		1656
	0		1 986 274	1 985 784		−490	1 987 396		1122
2s2p⁵ ¹P^o	1		2 229 358	2 230 149		791	2 231 636		2278
2p⁶ ¹S	0		3 573 416	3 575 415		1999	3 579 486		6070

		Kr XXIX

2s²2p⁴ ³P	2	0	0	0	0	0	0	0	0
	0	160 700	162 011	160 024	−676	−1987	160 088	−612	−1923
	1	423 820	423 933	423 900	80	−33	424 185	365	252
2s²2p⁴ ¹D	2	524 890	525 066	525 009	119	−57	525 210	320	144
2s²2p⁴ ¹S	0		1 020 595	1 019 865		−730	1 020 232		−363
2s2p⁵ ³P^o	2	1 674 650	1 675 351	1 674 831	181	−520	1 676 282	1632	931
	1	1 864 320	1 864 603	1 864 921	601	−318	1 866 459	2139	1856
	0	2 133 800	2 135 798	2 135 128	1328	−670	2 136 839	3039	1041
2s2p⁵ ¹P^o	1	2 377 700	2 377 764	2 378 567	867	803	2 380 149	2449	2385
2p⁶ ¹S	0		3 777 648	3 779 999		2351	3 784 241		6593

Notes. Energy levels (E) and the difference of theoretical energies from observed (Diff.(1)) and SE (Diff.(2)) ones are given (in cm^-1). Primary data source for As XXVI, Se XXVII and Br XXVIII ions at NIST is from Kelly (1987).

Reference.

^(a)

Kramida et al. (2013);

^(b)

Edlén (1983);

^(c)

present calculations;

^(d)

Vilkas et al. (1999).

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