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Table 3
Rovibrational transition energies for in the X 1Σ+ state of 7LiH.
Transition energy (cm-1) | |||||
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Band | Line | Present | Experimenta | ΔEcpb | ΔEc |
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1−0 | P(28) | 858.1193 | 858.0924 | 0.31 | 2.7E-02 |
P(23) | 953.1177 | 953.0989 | 0.38 | 1.9E-02 | |
P(18) | 1048.2419 | 1048.231 | 0.46 | 1.1E-02 | |
P(13) | 1141.6388 | 1141.6337 | 0.54 | 5.1E-03 | |
P(8) | 1231.0873 | 1231.0857 | 0.63 | 1.6E-03 | |
P(3) | 1314.0901 | 1314.0902 | 0.72 | −1.0E-04 | |
R(2) | 1401.5064 | 1401.5062 | 0.82 | 2.0E-04 | |
R(7) | 1461.2703 | 1461.2695 | 0.88 | 8.0E-04 | |
R(12) | 1506.8725 | 1506.8724 | 0.93 | 1.0E-04 | |
R(17) | 1536.7646 | 1536.7673 | 0.95 | −2.7E-03 | |
R(22) | 1550.0615 | 1550.0721 | 0.94 | −1.1E-02 | |
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2−1 | P(27) | 844.9443 | 844.9214 | 0.33 | 2.3E-02 |
P(22) | 937.6974 | 937.6828 | 0.38 | 1.5E-02 | |
P(17) | 1030.1894 | 1030.1815 | 0.45 | 7.9E-03 | |
P(12) | 1120.5469 | 1120.5438 | 0.53 | 3.1E-03 | |
P(7) | 1206.5402 | 1206.5394 | 0.62 | 8.0E-04 | |
P(2) | 1285.6869 | 1285.6872 | 0.71 | −3.0E-04 | |
R(3) | 1368.0210 | 1368.0208 | 0.80 | 2.0E-04 | |
R(8) | 1423.2838 | 1423.2834 | 0.86 | 4.0E-04 | |
R(13) | 1464.2863 | 1464.2873 | 0.90 | −1.0E-03 | |
R(17) | 1485.8610 | 1485.8639 | 0.92 | −2.9E-03 | |
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3−2 | p(23) | 885.7266 | 885.7132 | 0.39 | 1.3E-02 |
P(18) | 976.0542 | 976.0472 | 0.44 | 7.0E-03 | |
P(12) | 1081.9646 | 1081.9626 | 0.53 | 2.0E-03 | |
P(7) | 1165.6453 | 1165.645 | 0.61 | 3.0E-04 | |
P(2) | 1242.5862 | 1242.5865 | 0.69 | −3.0E-04 | |
R(3) | 1322.4840 | 1322.4835 | 0.78 | 5.0E-04 | |
R(8) | 1375.9434 | 1375.9434 | 0.85 | 0.0E+00 | |
R(13) | 1415.3862 | 1415.3881 | 0.89 | −1.9E-03 | |
R(18) | 1439.4378 | 1439.4452 | 0.92 | −7.4E-03 | |
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4−3 | P(21) | 888.1921 | 888.1827 | 0.42 | 9.4E-03 |
P(16) | 975.7737 | 975.7707 | 0.48 | 3.0E-03 | |
P(11) | 1060.7999 | 1060.7993 | 0.55 | 6.0E-04 | |
P(6) | 1141.0946 | 1141.0945 | 0.63 | 1.0E-04 | |
R(1) | 1253.6893 | 1253.6882 | 0.75 | 1.1E-03 | |
R(6) | 1310.3681 | 1310.3676 | 0.82 | 5.0E-04 | |
R(11) | 1353.9579 | 1353.9574 | 0.88 | 5.0E-04 | |
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5−4 | P(15) | 957.1386 | 957.1371 | 0.51 | 1.5E-03 |
P(10) | 1039.1932 | 1039.1925 | 0.57 | 7.0E-04 | |
P(4) | 1130.6447 | 1130.6442 | 0.66 | 5.0E-04 | |
R(4) | 1244.8800 | 1244.8819 | 0.79 | −1.9E-03 | |
R(5) | 1255.3743 | 1255.3722 | 0.81 | 2.1E-03 | |
R(8) | 1283.7835 | 1283.7859 | 0.85 | −2.4E-03 |
Notes.
(b)
Comparison between Coppola et al. (2011) and Dulick et al. (1998), ΔEcp = Ecp − Eexpt.
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