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Table C.1
Some examples of reactions with pressure-dependent rate constants present in the kinetic model.
| k = ATnexp(− E/RT) | - High pressure limit | |||||
| Reaction considered | A (cm3.molecule-1.s-1.K−n) | n | E/R (K) | |||
| 1. | C2H4+OH(+M)=C2H4OH(+M) | 9.003 × 10-12 | 0.0 | 0.0 | ||
| Low pressure limit: | 3.284 × 10-21 | -3.1 | 0.0 | |||
| 2. | H+CH3(+M)=CH4(+M) | 2.774 × 10-10 | 0.0 | 0.0 | ||
| O2 | Enhanced by | 0.40 | ||||
| CO | Enhanced by | 0.75 | ||||
| CO2 | Enhanced by | 1.50 | ||||
| H2O | Enhanced by | 6.50 | ||||
| CH4 | Enhanced by | 0.009 | ||||
| C2H6 | Enhanced by | 3.00 | ||||
| Ar | Enhanced by | 0.35 | ||||
| N2 | Enhanced by | 0.40 | ||||
| He | Enhanced by | 0.35 | ||||
| Low pressure limit: | 3.885 × 10-24 | -1.8 | 0.0 | |||
| TROE centering | 0.37 | 3315 | 61 | |||
| 3. | NO+OH(+M)=HONO(+M) | 1.827 × 10-10 | -0.3 | 0.0 | ||
| Low pressure limit: | 6.484 × 10-25 | -2.4 | 0.0 | |||
| SRI centering: | 1.0 | 0.0 | 1.00 × 10-18 | 0.81 | 0.0 | |
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