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Table 2

Root-mean-square (rms) deviations from the global fita of transitions involving vt = 0 torsional energy levels of HC18OOCH3 methyl formate.

Number of parameters 29 (+1fixed)
Number of lines 3258
rms of the 3258 MW vt = 0–0 lines 0.0448 MHz
rms of the 1720 A symmetry lines 0.048 MHz
rms of the 1538 E symmetry lines 0.041 MHz

Sourceb Rangec (GHz) vt, Jmax, Kmaxd Number of linese Uncertaintiesf (MHz) rmsg (MHz)

FTMW-LILLE 1–20 0, 4, 1 11 0.003 0.0040

SMM-LILLEh 150–660 0, 63, 30 2890 0.030–0.050 0.0277

SMM-LILLEh 150–660 0, 52, 29 179 0.100 0.0788

OSLO 7–80 0, 33, 8 137 0.150
OSLO 7–80 3 0.200 0.1343
SMM-LILLEh 150–660 0, 38, 29 38 0.200

Notes. 

(a)

Parameter values are given in Table 5. The observed minus calculated residuals are given in the supplementary Table S2.

(b)

Sources of data: FTMW-LILLE, SMM-LILLE and OSLO data comes from present work, see experimental section.

(c)

Range containing the measurements in a given row.

(d)

vt state and maximum J and Ka for each group of measurements.

(e)

Number of MW lines in each uncertainty group.

(f)

One-sigma standard uncertainty in MHz used in the fit.

(g)

Root-mean-square deviation in MHz for each group.

(h)

The SMM-LILLE spectrometer spectral ranges for these measurements are 150–322 GHz, 400–533 GHz and 583–660 GHz.

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