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Table 1

Root-mean-square (rms) deviations from the global fita of transitions involving vt = 0 torsional energy levels of HCO18OCH3 methyl formate.

Number of parameters 30 (+1fixed)
Number of lines 4430
rms of the 4430 MW vt = 0–0 lines 0.0478 MHz
rms of the 2256 A symmetry lines 0.051 MHz
rms of the 2174 E symmetry lines 0.044 MHz

Sourceb Rangec (GHz) vt, Jmax, Kmaxd Number of linese Uncertaintiesf (MHz) rmsg (MHz)

FTMW-LILLE 1–20 0, 7, 2 30 0.003 0.0024
SMM-LILLEh 150–660 0, 62, 30 4148 0.030–0.050 0.0254
SMM-LILLEh 150–660 0, 25, 6 4 0.100 0.0769
OSLO 7–80 0, 36, 9 248 0.150 0.1729

Notes. 

(a)

Parameter values are given in Table 4. The observed minus calculated residuals are given in the supplementary Table S1.

(b)

Sources of data: FTMW-LILLE, SMM-LILLE and OSLO data comes from present work, see experimental section.

(c)

Range containing the measurements in a given row.

(d)

vt state and maximum J and Ka for each group of measurements.

(e)

Number of MW lines in each uncertainty group.

(f)

One-sigma standard uncertainty in MHz used in the fit.

(g)

Root-mean-square deviation in MHz for each group.

(h)

The SMM-LILLE spectrometer spectral ranges for these measurements are: 150–322 GHz, 400–533 GHz and 583–660 GHz.

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