Issue |
A&A
Volume 668, December 2022
|
|
---|---|---|
Article Number | A46 | |
Number of page(s) | 12 | |
Section | Atomic, molecular, and nuclear data | |
DOI | https://doi.org/10.1051/0004-6361/202243248 | |
Published online | 01 December 2022 |
Laboratory spectroscopy of theoretical ices: Predictions for JWST and test for astrochemical models★,★★
1
Max-Planck-Institut für extraterrestrische Physik,
Gießenbachstraße 1,
85748
Garching bei München, Germany
e-mail: bmueller@mpe.mpg.de
2
Research Laboratory for Astrochemistry, Ural Federal University,
620002,
19 Mira street,
Yekaterinburg, Russia
Received:
2
February
2022
Accepted:
12
July
2022
Context. The pre-stellar core L1544 has been the subject of several observations conducted in the past years, complemented by modelling studies focused on its gas and ice-grain chemistry. The chemical composition of the ice mantles reflects the environmental physical changes along the temporal evolution, such as density and temperature. The investigation outcome hints at a layered structure of interstellar ices with abundance of H2O in the inner layers and an increasing concentration of CO near the surface. The morphology of interstellar ice analogues can be investigated experimentally assuming a composition derived from chemical models.
Aims. This research presents a new approach of a three-dimensional fit where observational results are first fitted with a gas-grain chemical model predicting the exact ice composition including infrared (IR) inactive species. Then the laboratory IR spectra are recorded for interstellar ice analogues whose compositions reflect the obtained numerical results, in a layered and in a mixed morphology. These results could then be compared with the results of James Webb Space Telescope (JWST) observations. Special attention is paid to the inclusion of IR inactive species whose presence is predicted in the ice, but is typically omitted in the laboratory obtained data. This stands for N2, one of the main possible constituents of interstellar ice mantles, and O2.
Methods. Ice analogue spectra were recorded at a temperature of 10 K using a Fourier transform infrared spectrometer. In the case of layered ice we deposited a H2O-CO-N2-O2 mixture on top of a H2O-CH3OH-N2 ice, while in the case of mixed ice we examined a H2O-CH3OH-N2-CO composition. The selected species are the four most abundant ice components predicted by the chemical model. Results. Following the changing composition and structure of the ice, we find differences in the absorption bands for most of the examined vibrational modes. The extent of observed changes in the IR band profiles will allow us to analyse the structure of ice mantles in L1544 from future observations by the JWST.
Conclusions. Our spectroscopic measurements of interstellar ice analogues predicted by our well-received gas-grain chemical codes of pre-stellar cores will allow detailed comparison with upcoming JWST observations. This is crucial in order to put stringent constraints on the chemical and physical structure of dust icy mantles just before the formation of stars and protoplanetary disks, and to explain surface chemistry.
Key words: astrochemistry / methods: laboratory: solid state / ISM: molecules / techniques: spectroscopic / infrared: ISM
The raw spectra are only available at the CDS via anonymous ftp to cdsarc.cds.unistra.fr (130.79.128.5) or via https://cdsarc.cds.unistra.fr/viz-bin/cat/J/A+A/668/A46
© B. Müller et al. 2022
Open Access article, published by EDP Sciences, under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/4.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
This article is published in open access under the Subscribe-to-Open model.
Open Access funding provided by Max Planck Society.
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