Reactivity in interstellar ice analogs: role of the structural evolution

¹ Laboratoire Univers et Particules de Montpellier, UMR 5299, CNRS et Université de Montpellier, Place Eugène Bataillon, 34095 Montpellier Cedex 05, France
² Max-Planck-Institut für Extraterrestrische Physik, Giessenbachstr. 1, 85748 Garching, Germany
³ Aix-Marseille Université, Physique des Interactions Ioniques et Moléculaires, PIIM UMR CNRS, 7345 Avenue Escadrille Normandie-Niémen, 13397 Marseille Cedex 20, France
email: patrice.theule@univ-amu.fr

Received: 13 November 2017
Accepted: 5 February 2018

Abstract

Context. The synthesis of interstellar complex organic molecules in ice involves several types of reactions between molecules and/or radicals that are usually considered to be diffusion controlled.

Aims. We aim to understand the coupling between diffusion and reactivity in the interstellar ice mantle using a model binary reaction in the diffusion-limited regime.

Methods. We performed isothermal kinetic laboratory experiments on interstellar ice analogs at low temperatures, using the NH₃:CO₂:H₂O model system where reactants NH₃ and CO₂ have a low reaction barrier and are diluted in a water-dominated ice.

Results. We found that in the diffusion-limited regime, the reaction kinetics is not determined by the intrinsic bulk diffusivity of reactants. Instead, reactions are driven by structural changes evolving in amorphous water ice, such as pore collapse and crystallization. Diffusion of reactants in this case likely occurs along the surface of (tiny) cracks generated by the structural changes.

Conclusions. The reactivity driven by the structural changes breaks the conventional picture of reactant molecules/radicals diffusing in a bulk water ice. This phenomenon is expected to lead to a dramatic increase in production rates of interstellar complex organic molecules in star-forming regions.