Accurate transition and hyperfine data in Ag I from the multiconfiguration Dirac–Hartree–Fock and relativistic coupled-cluster methods

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Table A.3

Weighted oscillator strengths gf in length gauge from FSMRCC and MCDHF/RCI calculations.

Transition	FSMRCC	MCDHF/RCI	unc.	FMP
6s_1/2→5p_1/2	0.308	0.308	A+	0.332
6s_1/2→5p_3/2	0.652	0.651	A+	0.684

7s_1/2→5p_1/2	0.0321	0.0322	AA	0.0298
7s_1/2→5p_3/2	0.0608	0.0619	AA	0.0552
7s_1/2→6p_1/2	0.587	0.582	A+	0.644
7s_1/2→6p_3/2	1.222	1.206	AA	1.308

8s_1/2→5p_1/2	0.0108	0.0107	A+	0.00960
8s_1/2→5p_3/2	0.0205	0.0203	A	0.0176
8s_1/2→6p_1/2	0.0465	0.0489	B	0.0466
8s_1/2→6p_3/2	0.08706	0.0903	B+	0.0848
8s_1/2→7p_1/2	0.869	0.876	B+	0.934
8s_1/2→7p_3/2	1.799	1.794	B+	1.896

5p_1/2→5s_1/2	0.484	0.445	C+	0.558

5p_3/2→5s_1/2	0.993	0.921	C+	1.14
$5 p_{3 / 2} \to 4 d_{5 / 2}^{- 1}$ $Mathematical equation: $5{p_{3/2}} \to 4d_{5/2}^{ - 1}$$	–	0.000314	E	–

6p_1/2→5s_1/2	0.00259	0.00101	E*	0.0222
$6 p_{1 / 2} \to 4 d_{3 / 2}^{- 1}$ $Mathematical equation: $6{p_{1/2}} \to 4d_{3/2}^{ - 1}$$	–	0.000624	E	–
6p_1/2→6s_1/2	0.905	0.902	A+	0.786

6p_3/2→5s_1/2	0.0118	0.0582	E*	0.0530
$6 p_{3 / 2} \to 4 d_{5 / 2}^{- 1}$ $Mathematical equation: $6{p_{3/2}} \to 4d_{5/2}^{ - 1}$$	–	0.00281	E	–
$6 p_{3 / 2} \to 4 d_{3 / 2}^{- 1}$ $Mathematical equation: $6{p_{3/2}} \to 4d_{3/2}^{ - 1}$$	–	0.000147	E	–
6p_3/2→6s_1/2	1.822	1.819	A+	1.584

7p_1/2→5s_1/2	0.000168	0.0000177	E*	0.00568
$7 p_{1 / 2} \to 4 d_{3 / 2}^{- 1}$ $Mathematical equation: $7{p_{1/2}} \to 4d_{3/2}^{ - 1}$$	–	0.000551	E	–
7p_1/2→6s_1/2	0.0239	0.0215	B+	0.0308
7p_1/2→5d_3/2	0.0552	0.0568	A	–
7p_1/2→7s_1/2	1.1966	1.202	AA	1.086

7p_3/2→5s_1/2	0.00124	0.00158	E*	0.0140
$7 p_{3 / 2} \to 4 d_{5 / 2}^{- 1}$ $Mathematical equation: $7{p_{3/2}} \to 4d_{5/2}^{ - 1}$$	–	0.00196	E	–
$7 p_{3 / 2} \to 4 d_{3 / 2}^{- 1}$ $Mathematical equation: $7{p_{3/2}} \to 4d_{3/2}^{ - 1}$$	–	0.000127	E	–
7p_3/2→6s_1/2	0.0633	0.0575	B+	0.0734
7p_3/2→5d_3/2	0.00840	0.00880	A	–
7p_3/2→5d_5/2	0.0808	0.0814	B+	–
7p_3/2→7s_1/2	2.3906	2.409	AA	2.180

$4 d_{3 / 2}^{- 1} \to 5 p_{1 / 2}$ $Mathematical equation: $4d_{3/2}^{ - 1} \to 5{p_{1/2}}$$	–	0.00353	E	–
$4 d_{3 / 2}^{- 1} \to 5 p_{3 / 2}$ $Mathematical equation: $4d_{3/2}^{ - 1} \to 5{p_{3/2}}$$	–	0.000563	E	–

5d_3/2→5p_1/2	1.133	1.095	B+	1.194
5d_3/2→5p_3/2	0.239	0.233	B+	0.248
5d_3/2→6p_1/2	0.186	0.198	B+	0.182
5d_3/2→6p_3/2	0.0201	0.0201	B	0.0197

5d_5/2→5p_3/2	2.155	2.086	B+	2.232
5d_5/2→6p_3/2	0.198	0.213	B	–

6d_3/2→5p_1/2	0.241	0.223	B+	0.264
6d_3/2→5p_3/2	0.0471	0.0448	B+	0.0524
6d_3/2→6p_1/2	0.992	0.972	AA	1.016
6d_3/2→6p_3/2	0.219	0.215	AA	0.220
6d_3/2→7p_1/2	0.287	0.278	B+	0.284
6d_3/2→7p_3/2	0.0289	0.0263	C+	0.0286

6d_5/2→5p_3/2	0.417	0.403	B+	0.472
6d_5/2→6p_3/2	1.962	1.917	AA	–
6d_5/2→7p_3/2	0.294	0.267	C+	–

$4 f_{5 / 2} \to 4 d_{3 / 2}^{- 1}$ $Mathematical equation: $4{f_{5/2}} \to 4d_{3/2}^{ - 1}$$	–	0.000341	A+	–
$4 f_{5 / 2} \to 4 d_{5 / 2}^{- 1}$ $Mathematical equation: $4{f_{5/2}} \to 4d_{5/2}^{ - 1}$$	–	0.0000169	B+	–
4f_5/2→5d_3/2	4.015	3.956	AA	4.038
4f_5/2→5d_5/2	0.303	0.284	AA	0.289

$4 f_{7 / 2} \to 4 d_{5 / 2}^{- 1}$ $Mathematical equation: $4{f_{7/2}} \to 4d_{5/2}^{ - 1}$$	–	0.000332	A	–
4f_7/2→5d_5/2	5.782	5.672	AA	5.797

Notes. Uncertainty estimates for MCDHF/RCI based on the QQE approach. Here, 4d⁻¹ denotes the core-excited configuration 4d⁹5s². FMP refers to values reported by Civiš et al. (2010) based on the Fues model potential.

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