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Fig. 1

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Snapshots of the potential energy surface stationary points for the formation of (a) CH3CN and (b) CH3NC on the (H2O)14 ice cluster, where the CN radical is initially hemibonded to the ice. Distances are in Å. Atoms relevant to the reaction are highlighted using a ball-and-stick representation. The atom colour-code is as follows: red for O, blue for N, grey for C, and white for H.

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