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Table A.1

Sublimation temperature and initial volume mixing ratio of the chemical species included in our model.

Species Tsub [K] Initial volume mixing ratio
CO 20 0.29 × C/H
N2 20 0.5 × N/H
CH4 30 0.01 × C/H
CO2 70 0.1 × C/H
C2H2 70 0.0
H2S 150 0.1 × S/H
H2O 150 O/H - (3 × MgSiO3/H + 4 × Mg2SiO4/H + CO/H
+ 2 × CO2/H + 3 × Fe2O3/H + VO/H
+ TiO/H + 3×Al2O3 + 8×NaAlSi3O8 + 8×KAlSi3O8)
Refractory organics 350 0.6 × C/H
FeS 704 0.9 × S/H
NaAlSi3O8 958 Na/H
KAISi3O8 1006 K/H
Mg2SiO4 1354 Mg/H - (Si/H - 3×K/H - 3×Na/H)
Fe2O3 1357 0.5 × (Fe/H - 0.9 × S/H)
VO 1423 V/H
MgSiO3 1500 Mg/H - 2×(Mg/H - (Si/H - 3×K/H - 3×Na/H))
Al2O3 1653 0.5×(Al/H - (K/H + Na/H))
TiO 2000 Ti/H

Volume mixing ratios of each species are based on the works of Madhusudhan et al. (2014), Bitsch & Battistini (2020), and Schneider & Bitsch (2021a,b), and their condensation temperatures are from Lodders (2003). We adapted the standard implementation of chemcomp to follow C2H2 and refractory organics instead of NH3 and C. The sub-limation temperature of C2H2 is taken from Penteado et al. (2017), while the value for refractory species is taken from Nakano et al. (2003) for refractory organics. Moreover, we did not consider the evolution of Fe3O4. Solar elemental abundances (Asplund et al. 2009) are assumed.

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