Table A.1
Sublimation temperature and initial volume mixing ratio of the chemical species included in our model.
Species | Tsub [K] | Initial volume mixing ratio |
---|---|---|
CO | 20 | 0.29 × C/H |
N2 | 20 | 0.5 × N/H |
CH4 | 30 | 0.01 × C/H |
CO2 | 70 | 0.1 × C/H |
C2H2 | 70 | 0.0 |
H2S | 150 | 0.1 × S/H |
H2O | 150 | O/H - (3 × MgSiO3/H + 4 × Mg2SiO4/H + CO/H + 2 × CO2/H + 3 × Fe2O3/H + VO/H + TiO/H + 3×Al2O3 + 8×NaAlSi3O8 + 8×KAlSi3O8) |
Refractory organics | 350 | 0.6 × C/H |
FeS | 704 | 0.9 × S/H |
NaAlSi3O8 | 958 | Na/H |
KAISi3O8 | 1006 | K/H |
Mg2SiO4 | 1354 | Mg/H - (Si/H - 3×K/H - 3×Na/H) |
Fe2O3 | 1357 | 0.5 × (Fe/H - 0.9 × S/H) |
VO | 1423 | V/H |
MgSiO3 | 1500 | Mg/H - 2×(Mg/H - (Si/H - 3×K/H - 3×Na/H)) |
Al2O3 | 1653 | 0.5×(Al/H - (K/H + Na/H)) |
TiO | 2000 | Ti/H |
Volume mixing ratios of each species are based on the works of Madhusudhan et al. (2014), Bitsch & Battistini (2020), and Schneider & Bitsch (2021a,b), and their condensation temperatures are from Lodders (2003). We adapted the standard implementation of chemcomp to follow C2H2 and refractory organics instead of NH3 and C. The sub-limation temperature of C2H2 is taken from Penteado et al. (2017), while the value for refractory species is taken from Nakano et al. (2003) for refractory organics. Moreover, we did not consider the evolution of Fe3O4. Solar elemental abundances (Asplund et al. 2009) are assumed.
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