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Table 2

Column densities used in the synthetic spectra.

Column density (molecules cm−2)
(% H2O)
Molecule Dense cloud LYSO MYSO
H2O 9.3×1018 5.0×1018 5.0×1018
CO 2.3×1018 (25.0%) 1.3×1018 (25.0%) 3.5×1017 (7.0%)
CO2 2.4×1018 (26.0%) 1.3×1018 (26.0%) 9.5×1017 (19.0%)
CH3OH 7.4×1017 (8.0%) 3.0×1018 (6.0%) 4.5×1017 (9.0%)
NH3 0 3.5×1017 (7.0%) 3.5×1017 (7.0%)
NH4+${\rm{NH}}_4^ + $ 0 4.0×1017 (8.0%) 5.5×1017 (11.0%)
CH4 0 1.5×1017 (3.0%) 1.0×1017 (2.0%)
OCN 0 2.0×1017 (4.0%) 3.0×1016 (0.6%)
HCOOH 3.7×1017 (4%) 1.0×1017 (2.0%) 2.0×1017 (4.0%)
CH3CHO 0 5.0×1017 (1.0%) 2.7×1017 (5.5%)
H2CO 0 1.0×1017 (2.0%) 2.5×1017 (5.0%)

Detection thresholds of sulphur species (assuming rms level derived from McClure et al. (2023), of 0.003 and 0.005 mJy for NIRSpec and MIRI respectively)

H2S (1 mJy) 4.6×1016 (0.5%) 5.5×1016 (1.1%) 5.0×1016 (1.0%)
H2S (0.10 mJy) 3.5×1017 (3.8%) 4.4×1017 (8.9%) 3.9×1017 (7.9%)
H2S (0.04 mJy) 6.4×1017 (6.9%) 8.7×1017 (17.5%) 7.7×1017 (15.5%)
OCS (1 mJy) 1.8×1015 (0.02%) 2.5×1015 (0.05%) 2.5×1015 (0.05%)
OCS (0.1 mJy) 1.8×1016 (0.2%) 2.2×1016 (0.45%) 2.5×1016 (0.5%)
OCS (0.04 mJy) 3.7×1016 (0.4%) 5.0×1016 (1.0%) 6.0×1016 (1.2%)
CS2 (1 mJy) 5.6×1015 (0.06%) 5.0×1015 (0.1%) 4.0×1015 (0.08%)
CS2 (0.1 mJy) 3.7×1016 (0.4%) 3.0×1016 (0.6%) 2.5×1016 (0.5%)
CS2 (0.04 mJy) 7.4×1017 (0.8%) 5.0×1016 (1.0%) 8.0×1016 (1.6%)
SO2 (1 mJy) 7.4×1015 (0.08%) 7.5×1015 (0.15%) 6.0×1015 (0.12%)
SO2 (0.1 mJy) 4.6×1016 (0.5%) 6.0×1017 (1.2%) 4.0×1017 (0.8%)
SO2 (0.04 mJy) 9.3×1016 (1.0%) 1.0×1017 (2.1%) 8.5×1016 (1.7%)
S8 Undetectable assuming all cosmic S abundance locked in the ices

Notes. Column densities used in each synthetic spectrum, in parenthesis the abundance relative to water. Except for water, all values are extracted from Table 2 in Boogert et al. (2015). The 5σ detection thresholds are listed for each S-carrier at each continuum level for all three environments. These thresholds are computed from the rms value derived from McClure et al. (2023).

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