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Table G.1

Inferred range of crystallization temperature of COM ices under laboratory conditions (Tcrystal,lab). All the considered lab spectra of the five COM ices are obtained from the LIDA database (Rocha et al. 2022).

pure ices mixed icesa


Species measured Tlab (K)b Tcrystal, lab (K) measured Tlab (K)b Tcrystal, lab (K) fit B1-c (K)c
CH3CHO 15, 30, 70, 90, 110, 120 70–90 15, 30, 70, 90, 110, 120, 140, 160 110–140 alld

C2H5OH 15, 30, 70, 100, 120, 130, 140, 150 100–120 15, 30, 70, 100, 120, 130, 140, 150, 160 100–160 alld

CH3OCH3 15, 30, 70, 90, 100 30e–70 15, 30, 70, 90, 100, 120, 140, 160 100–140 < 100–120

CH3OCHO 15, 30, 50, 80, 100, 120 80–100 15, 30, 50, 80, 100, 120 50–80f < 100

CH3COCH3 15, 30, 70, 90, 110, 120, 130, 140 90–110 15, 30, 70, 90, 100, 110, 120, 140, 160 100–140 < 90

a The mixing constituents are provided in the legends of Figs. 5 and C.1.

b In experiments, temperature is usually sampled at small intervals (e.g., 1 K), but only a small part of the spectra measured at certain temperatures are provided on databases.

c The range of Tlab in which the lab spectra can fit into the B1-c spectrum, as long as there is no anti-correlation.

d The changes in the band profiles around crystallization are small; therefore, it is hard to exclude the crystalline features when compared with observations.

e The lower limit of Tcrystal, lab of pure CH3OCH3 ice is likely higher than 30 K.

f For CH3OCHO, the Tcrystal, lab of mixed ice is lower than that of pure ice. This is likely due to the crystallization or desorption of CO and H2CO, not the crystallization of CH3OCHO itself.

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