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Table B.1.

Species and transitions detected and used in this work, as well as their spectroscopic parameters.

Species Transition Rest Frequency Eu Aij gu
(MHz) (K) (s−1)
o-H2Sa 11, 0 − 10, 1 168762 27.9 2.65×10−5 9
33, 0 − 32, 1 300505 168.9 1.01×10−4 21
p-H2Sa 22, 0 − 21, 1 216710 84.0 4.83×10−5 5

o- H 2 34 S $ \rm{H}_2^{34}\rm{S} $a 11, 0 − 10, 1 167910 28.0 2.64×10−5 9
CSb 2 − 1 97980 4.9 1.68×10−5 5
3 − 2 146969 14.1 6.07×10−5 7
4 − 3 195954 23.5 1.49×10−4 9
5 − 4 244935 35.3 2.98×10−4 11
6 − 5 293912 49.4 5.23×10−4 13
7 − 6 342883 65.8 8.39×10−4 15

OCSb 7 − 6 85139 16.3 1.71×10−6 15
8 − 7 97301 21.0 2.58×10−6 17
9 − 8 109463 26.3 3.70×10−6 19
11 − 10 133785 38.5 6.82×10−6 23
12 − 11 145946 45.5 8.88×10−6 25
13 − 12 158107 53.1 1.13×10−5 27
14 − 13 170267 61.3 1.42×10−5 29
16 − 15 194586 79.4 2.13×10−5 33
17 − 16 206745 89.3 2.56×10−5 35
18 − 17 218903 99.8 3.04×10−5 37
19 − 18 231060 110.9 3.58×10−5 39
23 − 22 279685 161.1 6.37×10−5 47
24 − 23 291839 175.1 7.25×10−5 49
26 − 25 316146 204.9 9.23×10−5 53
29 − 28 352599 253.9 1.28×10−4 59

o-H2CSa 31, 3 − 21, 2 101477 22.9 1.26×10−5 21
31, 2 − 21, 1 104617 23.2 1.38×10−5 21
41, 3 − 31, 2 139483 29.9 3.57×10−5 27
51, 5 − 41, 4 169113 37.5 6.66×10−5 33
71, 7 − 61, 6 236727 58.6 1.91×10−4 45
81, 7 − 71, 6 278886 73.4 3.17×10−4 51
91, 8 − 81, 7 313716 88.5 4.56×10−4 57
101, 9 − 91, 8 348534 105.2 6.30×10−4 63
111, 11 − 101, 10 371847 120.3 7.70×10−4 69

p-H2CSa 30, 3 − 20, 2 103040 9.9 1.48×10−5 7
40, 4 − 30, 3 137371 16.5 3.64×10−5 9
60, 6 − 50, 5 205987 34.6 1.27×10−4 13
72, 5 − 62, 4 240548 98.9 1.88×10−4 15

CCSc 76 − 65 86181 23.3 2.82×10−5 13
78 − 67 93870 19.9 3.80×10−5 17
87 − 76 99866 28.1 4.46×10−5 15
88 − 77 103640 31.1 5.05×10−5 17
89 − 78 106347 25 5.56×10−5 19
98 − 87 113410 33.6 6.63×10−5 17
1010 − 99 129548 42.9 1.00×10−4 21
1011 − 910 131551 37.0 1.06×10−4 23
1110 − 109 140180 46.4 1.27×10−4 21
1112 − 1011 144244 43.9 1.41×10−4 25
1213 − 1112 156981 51.5 1.82×10−4 27
1312 − 1211 166662 61.8 2.16×10−4 25
1313 − 1212 168406 65.3 2.24×10−4 27
1314 − 1213 169753 59.6 2.31×10−4 29

CCSc 1514 − 1413 192961 79.7 3.38×10−4 29
1516 − 1415 195961 77.8 3.53×10−4 33
1616 − 1515 207260 93.3 4.21×10−4 33
1718 − 1617 221071 98.4 5.14×10−4 37
1817 − 1716 232201 111.2 5.94×10−4 35
1818 − 1717 233159 115.0 6.02×10−4 37
1819 − 1718 233938 109.6 6.10×10−4 39
1918 − 1817 245244 123.0 7.01×10−4 37
2120 − 2019 271292 148.4 9.52×10−4 41
2122 − 2021 272592 147.0 9.69×10−4 45
2424 − 2323 310837 195.2 1.44×10−3 49
2625 − 2524 336258 222.8 1.82×10−3 51
2625 − 2524 336722 226.9 §.83×10−3 53

SOd 22 − 11 86093 19.3 5.25×10−6 5
54 − 44 100029 38.6 1.08×10−6 9
32 − 21 109252 21.1 1.08×10−5 5
33 − 22 129138 25.5 2.25×10−5 7
65 − 55 136634 50.7 1.75×10−6 11
34 − 23 138178 15.9 3.17×10−5 9
43 − 32 158971 28.7 4.23×10−5 7
44 − 33 172181 33.8 5.83×10−5 9
45 − 34 178605 24.4 7.02×10−5 11
55 − 44 215220 44.1 1.19×10−4 11
56 − 45 219949 35.0 1.34×10−4 13
98 − 88 254573 99.7 4.24×10−6 17
76 − 65 296550 64.9 3.23×10−4 13
78 − 67 304077 62.1 3.61×10−4 17
22 − 12 309502 19.3 1.42×10−5 5
33 − 23 339341 25.5 1.45×10−5 7
88 − 77 344310 87.5 5.19×10−4 17

34SOd 22 − 11 84410 19.2 4.95×10−6 5
23 − 12 97715 9.1 1.07×10−5 7
33 − 22 126613 25.3 2.12×10−5 7
45 − 34 175352 24.0 6.65×10−5 11
65 − 54 246663 49.9 1.81×10−4 11
67 − 56 256877 46.7 2.15×10−4 15
78 − 67 298257 61.0 3.41×10−4 17
88 − 77 337582 86.1 4.89×10−4 17

SO2a 31, 3 − 20, 2 104029 7.7 1.01×10−5 7
101, 9 − 100, 10 104239 54.7 1.12×10−5 21
102, 8 − 102, 8 129514 60.9 2.50×10−5 21
121, 11 − 120, 12 131014 76.4 1.86×10−5 25
142, 12 − 141, 13 132744 108.1 2.93×10−5 29
62, 4 − 61, 5 140306 29.2 2.53×10−5 13
32, 2 − 31, 3 158199 15.3 2.53×10−5 7
22, 0 − 11, 1 192651 12.6 6.56×10−5 5
243, 21 − 242, 22 200287 302.3 9.87×10−5 49
183, 15 − 182, 16 204246 180.6 9.27×10−5 37
112, 10 − 111, 11 205300 70.2 5.32×10−5 23
32, 2 − 21, 1 208700 15.3 9.72×10−5 7
283, 25 − 282, 26 234187 403.0 1.45×10−4 57
52, 4 − 41, 3 241615 23.6 8.46×10−5 11
152, 14 − 151, 15 248057 119.3 8.06×10−5 31
284, 24 − 283, 25 267719 415.9 2.16×10−4 57
72, 6 − 61, 5 271529 35.5 1.11×10−4 15
181, 17 − 172, 16 288519 163.1 1.57×10−4 37

SO2a 262, 24 − 261, 25 296168 340.6 1.87×10−4 53
43, 1 − 32, 2 332505 31.3 3.29×10−4 9
82, 6 − 71, 7 334673 43.1 1.27×10−4 17
233, 21 − 232, 22 336089 276.0 2.67×10−4 47
191, 19 − 180, 18 346652 168.1 5.22×10−4 39
53, 3 − 42, 2 351257 35.9 3.36×10−4 11
124, 8 − 123, 9 355045 111.0 3.40×10−4 25
134, 10 − 133, 11 357165 123.0 3.51×10−4 27
154, 12 − 153, 13 357241 149.7 3.62×10−4 31
200, 20 − 191, 19 358215 185.3 5.83×10−4 41
194, 16 − 193, 17 359770 214.3 3.85×10−4 39
214, 18 − 213, 19 363159 252.1 4.00×10−4 43
63, 3 − 52, 4 371172 41.4 3.55×10−4 13

The detected species have an integrated intensity above a 3σ level (see Section 3). The spectroscopic parameters are taken from CDMS, except for H2CS and CCS for which the parameters are from JPL.

a

The quantum numbers given are J(Ka, Kb)

b

The quantum numbers given are J

c

The quantum numbers given are N(J)

d

The quantum numbers given are J(K).

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