Open Access

Table A.1

Major chemical reactions in the ionosphere of Mars.

Number Reaction Reaction rate
Photoionization
L1 O + hvO+ + e PphO[  cm3 s1 ]$P_{ph}^O\left[ {{\rm{c}}{{\rm{m}}^{ - 3}}{{\rm{s}}^{ - 1}}} \right]$
L2 CO2+hvCO2++e${\rm{C}}{{\rm{O}}_2} + hv \to CO_2^ + + {{\rm{e}}^ - }$ PphCO2[  cm3 s1 ]$P_{ph}^{C{O_2}}\left[ {{\rm{c}}{{\rm{m}}^{ - 3}}{{\rm{s}}^{ - 1}}} \right]$
Chemical reaction (OCO2 Charge exchange)
C1 O++CO2CO+O2+${{\rm{O}}^ + } + {\rm{C}}{{\rm{O}}_2} \to {\rm{CO}} + {\rm{O}}_2^ + $ k1 = 1.1 × 10−9 cm3 s−1
C2 CO2++OCO+O2+${\rm{CO}}_2^ + + {\rm{O}} \to {\rm{CO}} + {\rm{O}}_2^ + $ k2 = 1.6 × 10−10 cm3 s−1
C3 CO2++OCO2+O+${\rm{CO}}_2^ + + {\rm{O}} \to {\rm{C}}{{\rm{O}}_2} + {{\rm{O}}^ + }$ k3 = 0.96 × 10−10 cm−3 s−1
Recombination reaction
R1 O2++eO+O${\rm{O}}_2^ + + {{\rm{e}}^ - } \to O + O$ α1 = 2.4 × 10−7 (300/Te)0.7 cm3 s−1
R2 CO2++eCO+O${\rm{CO}}_2^ + + {{\rm{e}}^ - } \to {\rm{CO}} + {\rm{O}}$ α2 = 4.2 × 10−7 (300/Te)0.75 cm3 s−1

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