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Fig. 5

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Arrhenius plots for the elementary steps associated with TSH2CO${\rm{T}}{{\rm{S}}_{{{\rm{H}}_2}{\rm{C}} - {\rm{O}}}}$ (panel A), TS1 (panel B), TS2 (panel C), and TS6 (panel D). The values of the natural logarithm of the rate constant (ln(k)) are represented in yr–1 and the inverse of the temperatures (1/T) in K–1. RRKM constants, without considering tunneling and considering tunneling, are represented in blue and orange, respectively.

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